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21.
Snowmobile use in Yellowstone National Park has been shown to impact air quality, with implications for the safety and welfare
of Park staff and other Park resource values. Localized impacts have been documented at several high-use sites in the Park,
but the broader spatial variability of snowmobile emissions and air quality was not understood. Measurements of 87 volatile
organic compounds (VOCs) were made for ambient air sampled across the Park and West Yellowstone, Montana, during 2 days of
the 2002–2003 winter use season, 1 year before the implementation of a new snowmobile policy. The data were compared with
similar data from pristine West Coast sites at similar latitudes. Backward trajectories of local air masses, alkyl nitrate-parent
alkane ratios, and atmospheric soundings were used to identify the VOC sources and assess their impact. Different oversnow
vehicle types used in the Park were sampled to determine their relative influence on air mass pollutant composition. VOCs
were of local origin and demonstrated strong spatiotemporal variability that is primarily influenced by levels of snowmobile
traffic on given road segments at different times of day. High levels of snowmobile traffic in and around West Yellowstone
produced consistently high levels of benzene, toluene, and carbon monoxide. 相似文献
22.
Since 1972, at the University of Hohenheim in Stuttgart, Germany, airborne particulate matter (PM12 and then PM10) was continuously collected on filters and analyzed for environmentally relevant elements by X-ray fluorescence analysis. The resulting long-term time series are suitable for the investigation of trends and of seasonal variation. For the period 1972-2005, monthly and annual concentration mean values of 13 elements (Br, Ca, Cr, Cu, Fe, K, Mn, Ni, Pb, S, Ti, V, and Zn) in the air are presented. Trend curves were fitted and the mean yearly variation of the concentration for these elements was calculated and represented graphically. All trend curves show a diminution of the air pollution during this period, but to different extents. Mean trends in percent per year were calculated for each element both for the entire investigation period and for three data subsets of 10-11 years. Possible explanations are discussed in detail. 相似文献
23.
Modification of the biochemical pathways of plants induced by ozone: what are the varied routes to change? 总被引:2,自引:0,他引:2
Heath RL 《Environmental pollution (Barking, Essex : 1987)》2008,155(3):453-463
When plants are observed under a low dose of ozone, some physiological and metabolic shifts occur. Barring extreme injury such as tissue damage or stomata closure, most of these disruptive changes are likely to have been initiated at the level of gene expression. The belief is oxidative products formed in ozone exposed leaves, e.g. hydrogen peroxide, are responsible for much of the biochemical adjustments. The first line of defense is a range of antioxidants, such as ascorbate and glutathione, but if this defense is overwhelmed, subsequent actions occur, similar to systemic acquired resistance or general wounding. Yet there are seemingly unrelated metabolic responses which are also triggered, such as early senescence. We discuss here the current understanding of gene control and signal transduction/control in order to increase our comprehension of how ozone alters the basic metabolism of plants and how plants counteract or cope with ozone. 相似文献
24.
Singh S Sharma DK Dhar S Kumar A Kumar A 《Environmental monitoring and assessment》2007,130(1-3):301-309
Two measurement campaigns were conducted in two sampling sites, An Thinh and Duy Minh, in northern Vietnam during the months
of November–December 2000 and November 2001–February 2002 in order to investigate the extend of the particulate air pollution
from the Pha Lai coal fired power plant. Fine particle samples were analyzed by Energy Dispersive X-Ray Fluorescence spectrometry
and soot samples were analyzed by reflectometer. The result showed that high concentration of soot and elements mostly coincided
with the air masses originating from the power plant. Sea spray aerosol was found to be the major source of chlorine at both
sites. Ratios of specific elements and principal component analysis (PCA) revealed that coal combustion was the main contributor
to the air pollution at both sites. PCA also indicated that there were other sources responsible for the elements emission,
probably the influence of long distance transport and Asian Brown Cloud. 相似文献
25.
By using a dynamic dilution system, the atmospheric measurement of 11 selected toxics VOCs (ethylene, acetylene, propene, 1-butene, 1,3-butadiene, 1-pentene, 1-hexene, benzene, toluene, ethylbenzene, m+p-xylene) from the list WHO of 1996 and TO-14 method of US EPA by preconcentration by thermal desorption (TD), analysis by gas chromatography (GC), identification and quantification with a flame ionisation detector (FID) was developed and validated in term of metrology, especially the techniques of sampling of these VOCs with adsorbents cartridges "Air Toxics" when used with an "UMEG sampler" equipped in the inlet with a nafion membrane. In particular the influence of climatic conditions (temperature and relative humidity) and the influence of chemical factors like ozone, on the representativity of sampling were studied. Experiments made with various humidities showed that the addition of a nafion membrane in the inlet of the sampling system was required. Without this membrane, losses of compounds were observed for RH >50%. With this membrane, storage for 2 weeks in a refrigerator, as for canisters, did not induce a loss of compounds. No significative decrease of concentrations of the studied VOCs after 14 days storage, which are known to react with ozone, were observed with an ozone concentrations of 55 ppb. One explanation is that nafion membrane, placed in the inlet of the sampler, will neutralize ozone before entering the sampling tubes. This observation is in accordance with literature which states that the sampling of VOCs on Carbotrap cartridges without ozone scrubber induce a loss of compounds. 相似文献
26.
P.-A. Dastous J. Nikiema G. Soreanu L. Bibeau M. Heitz 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):275-285
This study presents the experimental results obtained during long-term operation of two biofilters treating two alcohols:
methanol and ethanol. The biofilters used for this purpose were previously packed with a compost material made from tobacco
processing residues. The alcohols concentrations tested lay between 0.40 and 3.20 g/m3 for methanol, and 0.55 and 5.05 g/m3 for ethanol. The empty bed residence time in each biofilter was 60 s. Biofilter inlet loads of less than 190 and 300 g/m3/h for the methanol and ethanol additions respectively, were thereafter evaluated. In addition, the concentrations of nutrient
nitrogen were also varied, from 0.1 to 2.0 g-N/l and from 0.3 to 11.3 g-N/l for the ethanol and the methanol, respectively.
The results thus obtained have made it possible to select the optimal nitrogen concentrations which, for the cases examined,
turn out to be 0.3 g-N/l and between 2 and 3.8 g-N/l for the ethanol and methanol substrates, respectively. The maximum elimination
capacities obtained in this study were 82 and 150 g/m3/h, respectively for the methanol and ethanol cases. It was therefore concluded that, for a readily biodegradable compound
such as ethanol, the nitrogen requirement is substantially lower than that needed for the methanol degradation, the latter
appearing to be more difficult to degrade biologically under similar operating conditions. The production rate of the co-product
carbon dioxide during methanol and ethanol biofiltration was also investigated. Also, a good correlation was found to exist
between the temperature and the conversion achieved in the biofilter. 相似文献
27.
With China's rapid economic development, environmental problems have become more and more serious. Particulate air pollution is terrible in cities with large and dense population. It may lead to adverse health effects and economic costs. In this study, we calculated the health effects of pollution caused by particulate matter with aerodynamic diameters less than 10mum (PM(10)) in 111 Chinese cities in 2004 according to statistical data and epidemiological exposure-response functions. Using economic burden of disease analysis, an economic assessment of these health risks was also presented. In contrast to many previous studies that have examined individual cities, this study covered most large and medium-sized cities in China, which accounted for more than 70% gross domestic product (GDP) of China in 2004. The total economic cost caused by PM(10) pollution was estimated as approximately US$ 29,178.7 million. Mega cities such as Beijing, Shanghai, and Tianjin contribute relatively more to the total costs. The results will help policy makers in formulating more effective countermeasures and increasing public awareness to enhance environmental protection. 相似文献
28.
29.
东亚春季边界层臭氧的数值模拟研究 总被引:3,自引:2,他引:3
利用嵌套网格空气质量模式系统(NAQPMS)对2004年4月东亚边界层(距地面.km以下)臭氧进行了数值模拟.并评估了东亚边界层光化学反应的活性.结果表明.东亚春季臭氧呈带状分布,其高值.〔φ(O3)>55×10-9.主要集中在30°N~40°N.受东亚季风气候控制.沿蒙古、中国东北以及日本一线有一强臭氧输送通道.输送通量达3×10-.mol/(m2·s).通过计算边界层O3光化学净生成率可知.光化学影响主要集中在高污染源排放地区.其与水平输送对臭氧影响的分布具有负相关性.说明光化学生成的O3可被输送至下风地区,而不仅限于局地. 相似文献
30.
Mohsen Soleimani Nasibeh Amini Babak Sadeghian Dongsheng Wang Liping Fang 《环境科学学报(英文版)》2018,30(10):166-175
The presence of heavy metals(HMs) in particulate matters(PMs) particularly fine particles such as PM_(2.5) poses potential risk to the health of human being. The purpose of this study was to analyze the contents of HMs in PM_(2.5) in the atmospheric monitoring stations in Isfahan city,Iran, in different seasons between March 2014 and March 2015 and their source identification using principle component analysis(PCA). The samples of PM_(2.5) were taken using a high volume sampler in 7 monitoring stations located throughout the city and industrial zones since March 2014 to March 2015. The HMs content of the samples was measured using ICP-MS.The results showed that the concentrations of As, Cd and Ni were in a range of 23–36, 1–12,and 5–76 ng/m~3 at all the stations which exceeded the US-EPA standards. Furthermore,the concentrations of Cr and Cu reached to 153 and 167 ng/m~3 in some stations which were also higher than the standard levels. Depending on the potential sources of HMs, their concentration in PM_(2.5) through the various seasons was different. PCA illustrated that the different potential sources of HMs in the atmosphere, showing that the most important sources of HMs originated from fossil fuel combustion, abrasion of vehicle tires, industrial activities(e.g., iron and steel industries) and dust storms. Management and control of air pollution of industrial plants and vehicles are suggested for decreasing the risk of the HMs in the region. 相似文献