气水比回流比及冲击负荷对BAF的影响

研究气水比、回流比及冲击负荷对BAF前置反硝化工艺的影响。研究结果表明BAF前置反硝化工艺最佳气水比为 3∶1 ,最佳回流比为 2 0 0 %。该工艺具有较强的抗冲击负荷能力 ,COD的最佳去除负荷可达 7.70 4kg/ (m3·d) ,NH3-N的最大去除负荷为 1 .2 85kg/ (m3·d) ;水力负荷对COD的去除影响较小 ,对NH3-N、TN的去除影响较大 ,宜将水力负荷控制在 2 .39m/h以下     

The U.S. Flood Control Program at 75: Environmental Issues1

Black, Peter E., 2012. The U.S. Flood Control Program at 75: Environmental Issues. Journal of the American Water Resources Association (JAWRA) 48(2): 244‐255. DOI: 10.1111/j.1752‐1688.2011.00609.x Abstract: Recent, recurring, and increased magnitude floods adversely challenge long‐held and erroneous concepts of flood control. This article focuses on the environmental issues with comprehensively reviewed essentials of the United States (U.S.) riverine Flood Control Program, including news reports, scientific articles, books, and landmark treatises. For the past three‐quarters of a century, U.S. floods have continued (and will continue) to occur, causing increasing property damage with growing fiscal loss. Reasons include inattention to fundamental principles of physics, hydrology, and ecology. There are also important challenges involving environmental policy, economics, and common sense. Measures afforded by the existing program encourage and enable investment in floodplains while violating a variety of natural principles that make the situation worse. This detailed review includes the questionable (actually untrue) justification in the document‐setting policy for the 1936 Omnibus Flood Control Act. The well‐documented evidence is overwhelming. An alternative approach is presented that would enable and celebrate natural floods, managing their ecological and hydrological values, and not attempting to control them.     

Differences in Dissolved Organic Carbon and Nitrogen Responses to Storm‐Event and Ground‐Water Conditions in a Forested,Glaciated Watershed in Western New York1

Abstract: Differences in the storm‐event responses of dissolved organic carbon (DOC) and nitrogen (DON) in streamflow and ground water were evaluated for a glaciated forested watershed in western New York. Eight to ten storm events with varying rainfall amounts, intensities, and antecedent moisture conditions were studied for three catchments (1.6, 3.4, and 696 ha) over a three‐year period (2003‐2005). Concentrations of DOC in streamflow exiting the catchments were significantly higher for storm events following a dry period, whereas no similar response was observed for DON. Highest DON concentrations in streamflow were typically associated with storm events following wet antecedent moisture conditions. In addition to antecedent moisture conditions, DOC concentrations were also positively correlated with precipitation amounts, while DON did not reveal a consistent pattern. Streamwater and ground‐water concentrations of DOC during storm events were also strongly correlated with riparian ground‐water depths but a similar relationship was not observed for DON. Ground‐water DON concentrations were also more variable than DOC. We hypothesized that the differences in DOC and DON responses stemmed from the differences in catchment sources of these solutes. This study suggests that while DOC and DON are intrinsically linked as components of dissolved organic matter, their dynamics and exports from watersheds may be regulated by a different set of mechanisms and factors. Identifying these differences is critical for developing more reliable and robust models for transport of dissolved organic matter.     

Investigation of surfactant-enhanced mass removal and flux reduction in 3D correlated permeability fields using magnetic resonance imaging

Magnetic resonance imaging (MRI) was used to visualize the NAPL source zone architecture before and after surfactant-enhanced NAPL dissolution in three-dimensional (3D) heterogeneously packed flowcells characterized by different longitudinal correlation lengths: 2.1 cm (aquifer 1) and 1.1 cm (aquifer 2). Surfactant flowpaths were determined by imaging the breakthrough of a paramagnetic tracer (MnCl(2)) analyzed by the method of moments. In both experimental aquifers, preferential flow occurred in high permeability materials with low NAPL saturations, and NAPL was preferentially removed from the top of the aquifers with low saturation. Alternate flushing with water and two surfactant pulses (5-6 pore volumes each) resulted in approximately 63% of NAPL mass removal from both aquifers. However, overall reduction in mass flux (Mass Flux 1) exiting the flowcell was lower in aquifer 2 (68%) than in aquifer 1 (81%), and local effluent concentrations were found to increase by as high as 120 times at local sampling ports from aquifer 2 after surfactant flushing. 3D MRI images of NAPL revealed that NAPL migrated downward and created additional NAPL source zones in previously uncontaminated areas at the bottom of the aquifers. The additional NAPL source zones were created in the direction transverse to flow in aquifer 2, which explains the higher mass flux relative to aquifer 1. Analysis using a total trapping number indicates that mobilization of NAPL trapped in the two coarsest sand fractions is possible when saturation is below 0.5 and 0.4, respectively. Results from this study highlight the potential impacts of porous media heterogeneity and NAPL source zone architecture on advanced in-situ flushing technologies.     

Soil heterogeneity effects on acid flushing of lead-contaminated soil

A compact model for evaluation of acid flushing of heavy-metal-contaminated soil in a small-scale on-site treatment plant is proposed. The model assumes that the soil was re-packed in a container after excavation resulting in a soil structure with heterogeneous and random physical and chemical properties. To evaluate the effects of heterogeneity on the efficiency of contaminant removal by acid flushing, a numerical analysis of lead transport in the heterogeneous soil medium was performed. The model examines cation exchange and surface complexation reactions involving three cations (Ca, Pb, and H) and one anion (Cl) in both dissolved and exchangeable forms, two Pb surface complexes (SOPbCl and SOPbOH), and one Cl surface complex (SOH₂Cl). The transport of these species during flushing with acid in a synthetically generated two-dimensional heterogeneous soil was simulated in the model. Results indicated that the flushing fluid preferentially followed pathways with large permeability. The heterogeneous cation exchange capacity (CEC) distribution and surface complexation sites had a significant effect on the transport of dissolved species. Because the CEC was set to a relatively low value, Pb was adsorbed mainly as surface complexes (SOPbCl and SOPbOH). Simulation results suggest that blocks of low hydraulic conductivity located in the upper part of the model domain greatly impede solute transport. Ponding conditions did not significantly affect the efficiency of decontamination. The model and its results are useful in the design of small-scale treatment plants for acid flushing.     

颗粒层中非水相液体污染物冲洗排出速度的数值模拟简

在进行污染土壤的冲洗修复时,模型模拟是极具优势的预测净化效果的方法。本研究分别采用5种粒径的球形玻璃微珠模拟实际土壤,实验考察了玻璃微珠颗粒层中水和非水相液体的排出速度,给出了颗粒层中液含率分布函数,以及最大和最小颗粒层孔隙直径的定义,建立了一个描述颗粒层中水和非水相液体排出速度的多孔介质孔隙毛细管束模型。使用构建的模型模拟水和异辛烷在颗粒层中的排出速度,模拟结果与实验数据有很好的一致性,模型预测结果的平均相对误差小于6.4%,特别是对粒径较小颗粒层,预测的准确性更高。模型可作为进一步研究在非水相液体饱和土壤水冲洗修复时,水和非水相液体排出速度和修复效果的基础。     

Effect of reservoir flushing on downstream river water quality

The effect of short-term reservoir flushing on downstream water quality in the Geum River, Korea was studied using field experiments and computer simulations. The reservoir release was increased from 30 to 200 m(3)/s within 6 h for the purpose of this experiment. The flushing discharge decreased the concentrations of soluble nitrogen and phosphorus species considerably, but the experimental results revealed a negative impact on organic forms of nutrients and biochemical oxygen demand (BOD). A dynamic river water quality model was applied to simulate the river hydraulics and water quality variations during the event. The model showed very good performance in predicting the travel time of flushing flow and the variations of dissolved forms of nitrogen and phosphorus constituents. However, it revealed a limited capability in simulating organic forms of nutrients and BOD because it does not consider the re-suspension mechanism of these constituents from sediment during the wave front passage.     

NaCl盐度对活性污泥处理系统的影响

海水冲厕是一项具有重大节水意义的工程。针对所产生的含盐生活污水的处理 ,试验研究NaCl盐度对活性污泥处理系统的综合影响。分别研究不同盐度驯化下活性污泥的生长、有机物降解和去除情况、SBR反应系统内溶解氧随时间的变化以及污泥沉降性等。试验结果表明 ,NaCl盐度影响了微生物的生长 ,降低有机物降解速率和去除率 ,但是却增强了细胞的溶胞作用和微生物的呼吸作用     

冲厕污水生物处理技术研究

主要研究了复合生物技术对冲厕污水有机污染物和NH4+-N的去除效果。结果表明,在进水COD和NH4+-N负荷分别为1.2~1.4 kg COD/(m3.d)和0.10~0.11 kg NH4+-N/(m3.d)时,出水COD和NH4+-N稳定维持在15 mg/L和5 mg/L,达到国家中水回用相关标准,满足了循环冲洗水水质要求,根本上实现了冲厕污水源头治理和资源化。     

Electrokinetic movement of multiple chlorobenzenes in contaminated soils in the presence of β-cyclodextrin

This study investigated the electrokinetic (EK) behavior of multiple chlorobenzenes, including 1,2,3,4-tetrachlorobenzene (TeCB), 1,2,4,5-tetrachlorobenzene (i-TeCB), and 1,2,3-trichlorobenzene (TCB) in contaminated clayed soils. The effect of β-cyclodextrin (β-CD) on the EK removal of the chlorobenzenes was studied. The largest removal was obtained when Na2CO3/NaHCO3 buffer was used as anodic purging solution without β-CD. The removal efficiencies were related to the aqueous solubilities of chlorobenzenes. With the same cumulative electroosmotic flow, greater solubility led to higher removal efficiency. The addition of β-CD inhibited the EK removal efficiency of all chlorobenzenes. The inhibition increased with the increase of β-CD concentration. With the same β-CD concentration, the inhibition increased with the rise of electric potential. It was found that the inclusion compounds between β-CD and chlorobenzenzes were less soluble than chlorobenzenes. The formation of the less soluble inclusion compounds reduced the aqueous solubility of chlorobenzenes and led to the partial immobilization of the chlorobenzenes that desorbed from soil. It was feasible to use the EK technology to remove chlorobenzenes in contaminated soils using water as the anodic flushing solution. The addition of β-CD was not recommended for the EK removal of chlorobenzenes.