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101.
IntroductionMethane (CH4 )isanimportanttraceorganic gaswiththehighestconcentrationintheatmosphere.BecauseCH4 hasstrongabilitytoabsorbinfrared redlightandthenwarmtheatmosphere,itsgreenhouseeffectsarecloselyfollowingthoseofcarbondioxide (CO2 ) .Themainbiogenics… 相似文献
102.
Biological elimination of H2S and NH3 from wastegases by biofilter packed with immobilized heterotrophic bacteria 总被引:10,自引:0,他引:10
Biotreatment of various ratios of H2S and NH3 gas mixtures was studied using the biofilters, packed with co-immobilized cells (Arthrobacter oxydans CH8 for NH3 and Pseudomonas putida CH11 for H2S). Extensive tests to determine removal characteristics, removal efficiency, removal kinetics, and pressure drops of the biofilters were performed. To estimate the largest allowable inlet concentration, a prediction model was also employed. Greater than 95% and 90% removal efficiencies were observed for NH3 and H2S, respectively, irrespective of the ratios of H2S and NH3 gas mixtures. The results showed that H2S removal of the biofilter was significantly affected by high inlet concentrations of H2S and NH3. As high H2S concentration was an inhibitory substrate for the growth of heterotrophic sulfur-oxidizing bacteria, the activity of H2S oxidation was thus inhibited. In the case of high NH3 concentration, the poor H2S removal efficiency might be attributed to the acidification of the biofilter. The phenomenon was caused by acidic metabolite accumulation of NH3. Through kinetic analysis, the presence of NH3 did not hinder the NH3 removal, but a high H2S concentration would result in low removal efficiency. Conversely, H2S of adequate concentrations would favor the removal of incoming NH3. The results also indicated that maximum inlet concentrations (model-estimated) agreed well with the experimental values for space velocities of 50–150 h−1. Hence, the results would be used as the guideline for the design and operation of biofilters. 相似文献
103.
V.?BoudonEmail author J.-P.?Champion T.?Gabard G.?Pierre M.?Lo?te C.?Wenger 《Environmental Chemistry Letters》2003,1(1):86-91
Highly symmetrical molecules such as CH4, CF4 or SF6 are known to be atmospheric pollutants and greenhouse gases. High-resolution spectroscopy in the infrared is particularly
suitable for the monitoring of gas concentration and radiative transfers in the earth's atmosphere. This technique requires
extensive theoretical studies for the modeling of the spectra of such molecules (positions, intensities and shapes of absorption
lines). Here, we have developed powerful tools for the analysis and the simulation of absorption spectra of highly symmetrical
molecules. These tools have been implemented in the spherical top data system (STDS) and highly-spherical top data system
(HTDS) software available at http://www.u-bourgogne.fr/LPUB/shTDS.html. They include a compilation of modeled data obtained
during the last 20 years. An overview of our latest results in this domain will be presented.
Electronic Publication 相似文献
104.
Swati Mookherji Gregory W. McCarty Jonathan T. Angier 《Journal of the American Water Resources Association》2003,39(2):381-387
ABSTRACT: Dissolved gas analysis permits direct detection of ground water denitrification, a technique we used in this study to assess the fate of nitrate in a riparian wetland. Dissolved argon (Ar) and dinitrogen (N2) were measured in transects of nested piezometers installed at different depths within upwelling regions of a riparian wetland. The method uses the Ar content in the water as a natural inert tracer for assessing background content of N2 from the previous air/water equilibrium. Within the wetland under study, anoxic to suboxic ground water became more oxic in piezometers close to the aquifer layer, indicating upwelling of oxic ground water. Assessment of loss of nitrate and Ar in ground water within an upwelling zone indicated that shallow piezometers had significant N2 loss through degassing. Most of the measured nitrate‐nitrogen (NO3?‐N) loss of 205 μM in a piezometer nest could be accounted for by total N2‐N produced (169 μM N), calculated from changes in dissolved N2 and estimated N2 degassed. Degassing due to methane (CH4) production was also detected in some shallow piezometers within nests. This technique for analysis of dissolved gases in ground water can be applied to detect small changes in N gas concentration and aids in assessing the fate of nitrate along a ground water flow path. 相似文献
105.
活性炭纤维吸附含溴甲烷气体的性能 总被引:1,自引:1,他引:0
采用动态吸附法在25℃下,测定了3种活性炭纤维(ACF-1、ACF-2和ACF-3)对含溴甲烷气体的吸附性能和回收效果,并对活性炭纤维的孔结构进行表征.探讨了孔结构、溴甲烷浓度、气体流量、循环使用次数等因素对活性炭纤维吸附溴甲烷性能的影响.结果表明,活性炭纤维比表面积大小及0.4~0.8 nm左右的微孔数量决定了其对溴甲烷吸附性能的优劣;气体中溴甲烷的浓度的提高使活性炭纤维对溴甲烷的穿透和饱和吸附量增加,而气体流量的增加则使活性炭纤维对溴甲烷的穿透和饱和吸附量降低,但两者均使穿透和饱和吸附时间缩短;活性炭纤维多次循环使用后,对溴甲烷的吸附容量明显地降低,循环12次后达到稳定吸附,其稳定吸附值为133.5 mg/g. 相似文献
106.
107.
Weilong Ouyang Yi Zhou Xiaoqi Fei Yarong Bai Haiqiang Wang Zhongbiao Wu 《环境科学学报(英文版)》2022,34(1):175-184
Herein, a series of niobium oxide supported cerium nanotubes(Ce NTs) catalysts with different loading amount of Nb2O5(0–10 wt.%) were prepared and used for selective catalytic reduction of NOxwith NH3(NH3-SCR) in the presence of CH2Cl2. Commercial V2O5-WO3-TiO2 catalyst was also prepared for comparison. The physcial properties and chemical properties of the Nb2O5 lo... 相似文献
108.
109.
《环境科学与技术》2017,(1)
文章利用全球首颗专用温室气体观测卫星"呼吸号"(GOSAT)上的被动红外探测器(TANSO)官方反演的CH_4浓度L4B数据产品研究2009年6月-2012年5月期间中国区域近地面975 hPa和高空400、250 hPa高度CH_4浓度数据通过与中国地区全球大气本底站(瓦里关站)的数据进行比对验证,剔除L4B中的不合理数据,分析其分布的时空变化特征,同时分析了中国区域对流层和瓦里关站CH_4 2009-2012年间的变化情况以及增长率并将瓦里关站与TCCON全球CH_4地面观测站点数据进行分析比较。结果表明:中国区域CH_4分布在垂直方向上随高度增加而逐渐下降,CH_4主要分布在华北地区,且春夏季节较为强烈,中高层CH_4呈增长趋势,而瓦里关站则有下降的趋势。 相似文献
110.
兴安落叶松林是我国北方最大的针叶林,在我国具有重要的碳汇地位,对我国以及全球的气候变化具有重要影响。由于独特的高寒高湿和多年冻土的特殊生态环境,兴安落叶松林土壤中 CH4的吸收与释放的规律与众不同。因此,开展对土壤 CH4动态及其与环境关系的研究,对揭示兴安落叶松林碳汇能力的形成、碳释放动态以及兴安落叶松林对气候变化的作用具有重要的理论和实践意义。作者于2011年5月到9月间在内蒙古根河国家生态站,在不同坡位的4种典型兴安落叶松林群落中布设样地,采用静态箱-红外气体分析仪收集气体并分析CH4通量的变化,同时测定不同深度的土壤温度,测定土壤含水率。借助SAS方差分析、相关性分析等统计方法,对兴安落叶松林土壤CH4通量的季节变化进行研究,同时分析土壤温度及含水率对 CH4通量的影响。结果表明,CH4的季节动态变化规律:坡顶 CH4通量为春季释放,夏季吸收,秋季释放,吸收大于释放,通量的平均值为-68.12μg·m^-2·h^-1;坡上部CH4通量为春夏秋3季均吸收,通量的平均值为-342.49μg·m^-2·h^-1;坡下部CH4通量为春季释放,夏季吸收,秋季释放,释放大于吸收,通量的平均值为67.8μg·m^-2·h^-1;坡脚CH4通量为春夏秋3季均释放,通量的平均值为263μg·m^-2·h^-1。总的来说,在生长季兴安落叶松林土壤甲烷通量吸收大于释放,说明地处寒温带的大兴安岭是CH4的汇。观测期间CH4通量与温度及土壤含水率均有一定的相关性,二者从不同角度影响CH4通量的变化,而随着坡位的变化土壤水热条件也随之改变,这同样是影响CH4通量的一个重要因素。 相似文献