Global warming related carbon dioxide abatement proposals

The relationship between man-made CO2 emission and atmospheric CO2 concentration has been established. The factors that affect CO2 reduction allotment and the impacts on future energy demand and supply were discussed, in order to help energy policy makers both in developed countries and in developing countries for understanding the fundamental constraint on energy sector resulted from global warming related CO2 reduction, and hopefully in finding a common objective starting point to deal with global warming negotiation in energy sector, and to investigate the optimum stabilization goal and process acceptable to all sovereign countries that based on equity and applicability.     

Prenatal diagnosis of GM2-gangliosidosis B1 variant

Prenatal diagnosis in a pregnancy at risk for a juvenile B1 variant of GM₂-gangliosidosis was carried out. The biochemical study of the cultured amniocytes and the affected fetal brain is reported. The results obtained show that the sulphated artificial substrate can be used in the diagnosis of B1 variant, but not the neutral one. The accumulation of GM₂-ganglioside in the fetal brain of the B1 juvenile form and an infantile form of GM₂-gangliosidosis (0 variant) was compared.     

水泥负载TiO2光催化降解染料水溶液的研究

研究了以ＴｉＯ２为催化剂，且将ＴｉＯ２涂布在模拟工业水处理浅池的水泥质池底表面，以直管高压汞灯为光源，对有机染料酸性玫瑰红Ｂ和晒化绿Ｂ进行光催化降解的可行性。结果表明，在实验条件下，本系统对以上染料有显著的光降解作用，浓度为２５ｍｇ／Ｌ的上述二种染料溶液，经３０ｍｉｎ光照，其降解率分别达８８．２％，此外，还探讨了染料浓度，染料体积、染料溶液ＰＨ值等因素对光降解的影响。     

GdFeO3上CO氧化的Redox机理动力学

ＧｄＦｅＯ３用柠檬酸络合制备。用ＸＲＤ测定ＧｄＦｅＯ３为钙钛矿结构。用ＣＯ还原脉冲及用Ｏ２再氧化脉冲证实在ＧｄＦｅＯ３上ＣＯ氧化为Ｒｅｄｏｘ机理。用外循环流动无梯度反应顺研究了ＣＯ氧化稳态动力学。用正交设计法估计动力学方程中的参数。还原催化剂再氧化为控制步骤。     

重庆南山马尾松林衰亡与大气污染关系的讨论

重庆市南郊的南山是一个风景区,有林地约二万七千余亩,主要是马尾松林(Pinusmassoniana Lamb.),自八十年代起明显出现衰亡现象,目前约有85％马尾松植株受到不同程度的伤害,死亡率达35％左右.马尾松出现的症状是针尖坏死,针叶提早脱落,针长变短,树冠稀疏,枝条枯死,径向生长变弱等.     

纳米TiO_2-CS微球光催化降解亚甲基兰的研究

将用化学方法改性后的纳米TiO2与壳聚糖(CS)共混,通过反相悬浮、交联制备了纳米TiO2-CS微球光催化剂,以亚甲基兰为对象,紫外灯为光源,研究了亚甲基兰的初始浓度、光照时间、不同pH值、纳米TiO2的含量、催化剂用量对亚甲基兰光降解率的影响。结果表明:纳米TiO2-CS微球能显著地降解亚甲基兰,且易于回收、能重复使用,为其实际应用提供了有价值的参数。     

工业废气污染状况与脱硫除尘技术

对工业废气污染状况进行分析讨论,综述了工业废气的多种脱硫除尘技术。并指出应选择脱硫除尘效率高,运转可靠,不产生二次污染的方法。     

纳米TiO_2光催化降解酸性红B的实验研究

采用偶联剂法在聚丙烯多面球表面负载化纳米TiO2,在高压汞灯照射下,以酸性红B染料为研究对象,采用光催化氧化法进行降解处理;研究了溶液初始浓度、H2O2和Fe3+投加量、pH以及光照强度等因素对酸性红B染料降解效果的影响。     

天津市环境空气SO2污染现状及分析

天津环境空气SO2的年均浓度始终超过国家二级标准。年均浓度超标主要因为采暖期SO2浓度过高所至，采暖期SO2平均浓度是非采暖期浓度的3倍左右；在2002--2005年的三个采暖期里，SO2污染逐年加重，导致了年均SO2浓度的逐年升高。天津SO2污染与采暖期增多的低烟囱排放、不利的气象条件有关，也与流动源的隐性排放、能源利用效率低下有关。结合天津经济发展速度、每年煤耗增量、现有环境治理手段来做预测，空气SO2浓度要在未来几年内达到国家二级标准仍是不可能的。     

Heterojunctioned CuO/Cu2O catalyst for highly efficient ozone removal

In recent years, near surface ozone pollution, has attracted more and more attention, which necessitates the development of high efficient and low cost catalysts. In this work, CuO/Cu₂O heterojunctioned catalyst is fabricated by heating Cu₂O at high temperature, and is adopted as ozone decomposition catalyst. The results show that after Cu₂O is heated at 180°C conversion of ozone increases from 75.2% to 89.3% at mass space velocity 1,920,000 cm³/(g·hr) in dry air with 1000 ppmV ozone, which indicates that this heterojunction catalyst is one of the most efficient catalysts reported at present. Catalysts are characterized by electron paramagnetic resonance spectroscopy and ultraviolet photoelectron spectroscopy, which confirmed that the heterojunction promotes the electron transfer in the catalytic process and creates more defects and oxygen vacancies in the CuO/Cu₂O interfaces. This procedure of manufacturing heterostructures would also be applicable to other metal oxide catalysts, and it is expected to be more widely applied to the synthesis of high-efficiency heterostructured catalysts in the future.