中国省域能源消费碳排放时空异质性的EOF和GWR分析

利用自然正交函数(EOF)揭示中国各省份能源消费碳排放量变动的时空特征,借助地理加权回归模型(GWR)分析了碳排放量驱动因素的空间分布状况.研究结果表明:中国省域能源消费碳排放量整体处于增长状态,但其增长速度有减缓趋势;EOF第一模态结果显示,碳排放量以四川省为中心向南北方向扩散,低值区集中分布在西北地区和珠三角地区;第二模态结果显示,碳排放量增长速度表现出西南地区和东南沿海地区较快,而中部省份碳排放量增长速度较慢的态势.碳排放量影响因素的重要程度由大到小依次为:总人口变化量、人均GDP变化量、城镇化率变化量、二产比重变化量、贸易开放程度变化量和能源消耗强度变化量,其中,总人口变化量的影响程度最为剧烈,每当总人口变化1%时,碳排放量相应地会变化0.5358%.     

施硅对水稻铁膜砷固定和体内砷转运的影响

水稻铁膜对砷(As)的固定及其体内As的转运深刻影响着糙米中As的累积.施硅(Si)能够抑制水稻对As的累积,然而,施Si如何调控铁膜对As的固定和水稻各部位的As向糙米的转运,相关机制目前尚未十分清楚.以As超标土壤中的水稻铁膜为研究对象,通过开展不同Si处理水平的土壤盆栽试验,研究施Si对水稻根表铁膜固定As和各组织器官中As向糙米转运的影响及作用机制.结果表明,Si2(0.66 g·kg^-1)处理显著提高了水稻根系CAT(1.81倍)、SOD(7.98倍)和POD(1.25倍)酶活性,增加了铁膜中的DCB-Fe含量(44.35%),提高了铁膜的表面粗糙度(108.91%),导致铁膜的DCB-As含量明显升高(88.32%);而且,Si2处理显著增加了水稻根中As的累积率,降低了根和叶对As的转运能力,最终导致糙米中As含量的显著降低(53.12%).施Si增强水稻根表铁膜对As固定的原因可归结于Si促进铁膜的形成和增大铁膜的表面粗糙度,而施Si抑制根和叶中As向糙米的转运则可能与Si竞争水稻体内As的转运蛋白,促进As-巯基络合物形成以及增强As液泡区隔化等...     

不同耕作措施对渭北旱塬土壤碳库管理指数及其构成的影响

以渭北旱塬9 a（2007—2016年）的不同耕作定位试验为对象,研究了在秸秆还田条件下3种连年单一耕作即翻耕（CC）、免耕（NN）、深松（SS）和3种轮耕措施即免耕-深松（NS）、深松-翻耕（SC）、翻耕-免耕（CN）对农田土壤固碳速率（CSE）、碳库管理指数（CPMI）、小麦产量和秸秆还田后表观腐殖化系数的影响。结果表明：以翻耕（CC）作为参照土样,免耕提高了0~10 cm表层土壤的固碳速率、有机碳（SOC）及其易氧化组分（EOC）的含量,并增加了表层（0~10 cm）土壤的碳库管理指数（CPMI）,在>10 cm土层SOC、EOC含量虽有所减少,但提高了有机碳的稳定系数（K_OS）;深松则提高了表层和35~50 cm土层的SOC、EOC含量、CSE及CPMI,并增加了0~10 cm、35~50 cm土层的EOC/SOC值和10~20 cm土层的K_OS;轮耕处理各土层的CSE、SOC和EOC含量均有所增加,且增加了0~10 cm、35~50 cm土层的EOC/SOC值,其中NS和CN轮耕处理各层CPMI都有所增加。深松、免耕和轮耕处理提高了小麦产量和小麦秸秆量,其中NS处理增加幅度最大,分别为14.3%（籽粒）和12.9%（秸秆）;进行9 a小麦秸秆还田,免耕、深松和轮耕措施提高了还田秸秆的表观腐殖化系数,其中NS处理的表观腐殖化系数显著高于翻耕处理。     

Estimation of biomass distribution in Peninsular Malaysia and in the islands of Sumatra, Java and Borneo based on multi-resolution remote sensing land cover analysis

In this study we used high resolution (20 m) land cover maps to derive detailed information on land cover structure within the classes of a regional medium resolution (500 m) land cover map. This enabled improved biomass estimation for the medium resolution land cover classes. Although our results suggested that land cover maps based merely on medium resolution remote sensing data can be used to monitor the extent of forest cover, they also showed that these maps alone are not sufficient to produce reliable regional estimates on above ground biomass in insular Southeast Asia. A quarter of the study area was covered by sub-pixel size (500 m) mosaic of various land cover types containing 14% of biomass. In total, non-forest areas covered over 60% of the study area and included 43% of biomass. In these areas, highly fragmented within class land cover structure was shown to significantly affect biomass estimates. Therefore we conclude that forest/land cover monitoring based merely on medium resolution remote sensing data can no longer be used to sufficiently quantify carbon fluxes connected to land cover changes in insular Southeast Asia, but multi-resolution approaches are needed to perform this task.     

上海地区土壤碳汇功能评估

利用上海市第二次土壤普查资料,2004年-2005年上海耕地地力调查资料,以及2009年实地调查采样、实验分析获得的数据,研究了3个时期上海土壤有机碳的变化特征。结果表明,20多年：来上海土壤有机碳平均含量没有明显变化,土壤有机碳库逐渐减小,从而使得上海城市化过程中土壤成为一种碳源,而不是碳汇。城市郊区以扩大蔬菜、果树、苗木种植为特征的旱地作物种植方式代替水稻田,是城市化影响土地利用类型变化的明显特征,而水稻田土壤有机碳含量高于林地、菜地。种植结构的变化对土壤有机碳含量有重要影响,同时,耕作制度、耕作方式、施肥等农业管理方式也有一定影响。虽然园林绿地得到快速发展,但没有弥补城市化过程导致农田面积减少带来的有机碳损失。     

森林生态系统在碳循环中的作用

描述了森林生态系统的碳循环及其在全球碳循环中的作用，说明了森林生态系统在碳循环中的作用主要取决于森林生态系统的生物量、林产品、植物枯枝落叶和根系碎屑以及森林土壤。最后，阐明了中国森林生态系统碳循环的研究现状和趋势。     

土壤生态系统中黑碳研究的几个关键问题

因人类活动的影响,全球大气C02浓度自1750年以来呈现逐步上升的趋势。农业生产活动与气候变化紧密相关,因土地利用方式的改变以及高度集约化的粮食、食物生产等农业活动都有可能增加CO2等温室气体的排放。如何遏制和减少大气中的CO2浓度是当前的热点问题,黑碳这一物质形式有可能为这一问题的缓解或解决提供新途径。生物质黑碳是生物质材料在低氧或无氧状态下经热裂解而形成的一种富含碳元素的有机连续体,其中碳（C）元素的含量高达70％-80％,并且大多以稳定的芳香环形式而存在。人类生存环境中所形成黑碳的80％以上最终都要归于土壤,且由于其较强的抗分解能力而长期滞留于土壤环境中。利用黑碳的这些特性及其碳封存能力,实施积极而有效的土壤管理措施,有可能增加土壤生态系统中的碳储存,从而为人类社会应对全球气候变化提供新的机遇。在文献资料调研的基础上,描述了土壤中黑碳的来源及其增加土壤碳储存、减缓陆地生态系统碳循环的潜力;阐释了量化土壤中黑碳的重要性以及精确测定土壤黑碳含量的关键所在;揭示了黑碳在土壤环境中的稳定性,探讨了外源黑碳与土壤本体有机碳的相互作用关系,并分析了黑碳对土壤温室气体排放的影响及其不确定性。揭示这些问题有助于客观评价黑碳能否作为一个有效的土壤有机碳库,也益于明确黑碳在全球碳循环以及中国农业减排过程中的作用与地位。     

Electricity-driven ammonia oxidation and acetate production in microbial electrosynthesis systems

• MES was constructed for simultaneous ammonia removal and acetate production. • Energy consumption was different for total nitrogen and ammonia nitrogen removal. • Energy consumption for acetate production was about 0.04 kWh/g. • Nitrate accumulation explained the difference of energy consumption. • Transport of ammonia and acetate across the membrane deteriorated the performance. Microbial electrosynthesis (MES) is an emerging technology for producing chemicals, and coupling MES to anodic waste oxidation can simultaneously increase the competitiveness and allow additional functions to be explored. In this study, MES was used for the simultaneous removal of ammonia from synthetic urine and production of acetate from CO₂. Using graphite anode, 83.2%±5.3% ammonia removal and 28.4%±9.9% total nitrogen removal was achieved, with an energy consumption of 1.32 kWh/g N for total nitrogen removal, 0.45 kWh/g N for ammonia nitrogen removal, and 0.044 kWh/g for acetate production. Using boron-doped diamond (BDD) anode, 70.9%±12.1% ammonia removal and 51.5%±11.8% total nitrogen removal was obtained, with an energy consumption of 0.84 kWh/g N for total nitrogen removal, 0.61 kWh/g N for ammonia nitrogen removal, and 0.043 kWh/g for acetate production. A difference in nitrate accumulation explained the difference of total nitrogen removal efficiencies. Transport of ammonia and acetate across the membrane deteriorated the performance of MES. These results are important for the development of novel electricity-driven technologies for chemical production and pollution removal.     

Experimental and simulation studies on the influence of carbon monoxide on explosion characteristics of methane

In underground coal mining, methane explosions often can cause tremendous disasters. In the meantime, carbon monoxide (CO), generated during the process of coal oxidation, may appear in the air. Therefore, the explosion characteristics of the mixture of CH₄ and CO must be investigated to prevent gas explosion accidents in coal mines. We conducted experiments by using a 20-L nearly spherical gas explosion testing device. The software FLACS was used to simulate the explosion of the mixture of CH₄ and CO at various mixing concentrations, and the simulation results corresponded to experimental results. With the increase of CO concentration, both upper and lower explosive limits of CH₄ decreased. On the whole, the explosion characteristic parameters of CH₄ and the mixture are similar. When CH₄ concentration was below the stoichiometric concentration, the addition of CO could promote the intensity of gas explosion; oppositely, excessive CO would inhibit the gas explosion reaction. The inhibitory effects become more significant as the concentration of CH₄ increases.     

Analysis of factors affecting individual participation in carbon market

China will set up a national carbon emissions trading market by the end of 2017, which is initially open to individual investors from the initial market for business and institutional investors. In this article, the main influencing factors and mechanism of individual participation in carbon trading market are studied by establishing multiple linear regression model. The study found that age, education level, length of account opening time, and risk attitude are the main factors influencing the participation of individual investors. Environmental awareness and environmental impact are less affected; information transparency and transaction risk also have an impact on the degree of individual investor participation; investment experience does not affect the participation of individual investors in the carbon trading market.