Volatile organic compounds at swine facilities: A critical review

Volatile organic compounds (VOCs) are regulated aerial pollutants that have environmental and health concerns. Swine operations produce and emit a complex mixture of VOCs with a wide range of molecular weights and a variety of physicochemical properties. Significant progress has been made in this area since the first experiment on VOCs at a swine facility in the early 1960s. A total of 47 research institutions in 15 North American, European, and Asian countries contributed to an increasing number of scientific publications. Nearly half of the research papers were published by U.S. institutions.Investigated major VOC sources included air inside swine barns, in headspaces of manure storages and composts, in open atmosphere above swine wastewater, and surrounding swine farms. They also included liquid swine manure and wastewater, and dusts inside and outside swine barns. Most of the sample analyses have been focusing on identification of VOC compounds and their relationship with odors. More than 500 VOCs have been identified. About 60% and 10% of the studies contributed to the quantification of VOC concentrations and emissions, respectively. The largest numbers of VOC compounds with reported concentrations in a single experimental study were 82 in air, 36 in manure, and 34 in dust samples.The relatively abundant VOC compounds that were quantified in at least two independent studies included acetic acid, butanoic acid (butyric acid), dimethyl disulfide, dimethyl sulfide, iso-valeric, p-cresol, propionic acid, skatole, trimethyl amine, and valeric acid in air. They included acetic acid, p-cresol, iso-butyric acid, butyric acid, indole, phenol, propionic acid, iso-valeric acid, and skatole in manure. In dust samples, they were acetic acid, propionic acid, butyric acid, valeric acid, p-cresol, hexanal, and decanal. Swine facility VOCs were preferentially bound to smaller-size dusts.Identification and quantification of VOCs were restricted by using instruments based on gas Chromatography (GC) and liquid chromatography (LC) with different detectors most of which require time-consuming procedures to obtain results. Various methodologies and technologies in sampling, sample preparation, and sample analysis have been used. Only four publications reported using GC based analyzers and PTR-MS (proton-transfer-reaction mass spectrometry) that allowed continuous VOC measurement. Because of this, the majority of experimental studies were only performed on limited numbers of air, manure, or dust samples. Many aerial VOCs had concentrations that were too low to be identified by the GC peaks.Although VOCs emitted from swine facilities have environmental concerns, only a few studies investigated VOC emission rates, which ranged from 3.0 to 176.5 mg d⁻¹ kg⁻¹ pig at swine finishing barns and from 2.3 to 45.2 g d⁻¹ m⁻² at manure storages. Similar to the other pollutants, spatial and temporal variations of aerial VOC concentrations and emissions existed and were significantly affected by manure management systems, barn structural designs, and ventilation rates.Scientific research in this area has been mainly driven by odor nuisance, instead of environment or health concerns. Compared with other aerial pollutants in animal agriculture, the current scientific knowledge about VOCs at swine facilities is still very limited and far from sufficient to develop reliable emission factors.     

纳米TiO 2 -碳纳米管复合膜修饰电极伏安法测定水中α -萘酚和β -萘酚

摘要：制备了一种新型的纳米TiO2-碳纳米管复合膜修饰电极,在pH值为5.57的NaAc-HAc缓冲溶液中,研究了α-萘酚和β-萘酚在该修饰电极上的电化学行为,据此建立了纳米TiO2-碳纳米管复合膜修饰电极伏安法测定水中α-萘酚和β-萘酚的方法。优化了试验条件,α-萘酚和β-萘酚分别在8.3×10^-7mol／L—1.0×10^-5mol／L和7.8×10^-7mol／L—1.0×10^-5mol／L范围内,浓度与氧化峰电流呈良好的线性关系,开路富集3min,检出限分别为3.5××10^-7mol／L和2.3×10^-7mol／L,模拟水样测定的回收率为97.6％—101％。     

热解吸-气相色谱法测定空气中二硫化碳

研究并建立了利用TenaxGC管富集、热解吸仪脱附,经HP-5石英毛细管柱分离,气相色谱（具FID）测定空气,9--硫化碳的方法。研究结果为：当采集30L气体时,本方法检出限可达0．03mg／m3,监测浓度范围为0．03—14mg／m3,方法精密度为8．7％;样品在密闭、低温环境中可保存2d。该方法可以满足环境监测要求。     

Developing Alternative Forest Management Planning Strategies Incorporating Timber, Water and Carbon Values: An Examination of their Interactions

Currently, the integration of carbon and water values of forest ecosystems into forest management planning models has become increasingly important in sustainable forest management. This study focuses on developing a multiple-use forest management planning model to examine the interactions of timber and water production as well as net carbon sequestration in a forest ecosystem. Each forest value is functionally linked to stand structure and quantified economically. A number of forest management planning strategies varying in the amount of water, carbon, and timber targets and flows as constraints are developed and implemented in a linear programming (LP) environment. The outputs of each strategy are evaluated with a number of performance indicators such as standing timber volume, ending forest inventory, area harvested, and net present value (NPV) of water, timber, and carbon over time. Results showed that the cycling time of forest stands for renewal has important implications for timber, water, and carbon values. The management strategies indicated that net carbon sequestration can be attained at a significant cost in terms of foregone timber harvest and financial returns. The standing timber volumes and ending forest inventories were among the most important factors determining whether the forest constitutes a net carbon sink or source. Finally, the interactions among the forest values were generally found to be complementary, yet sometimes contradictory (i.e., negatively affecting each other), depending on the assumed relationship between forest values and stand structure.     

Environmental stewardship—What does it mean?

Human activities have impacted the environment since the first toolmakers learned to make fire. As the human population has grown and changed, so has our impact on the environment. Currently the world's population is estimated at 6–7 billion, and that number of people, along with the billions of domesticated animals, and their activities, are large enough to have major global and regional impacts. Climate change, declining fish populations in the oceans, and ever decreasing ranges for “wild” ecosystems are the most obvious impacts. Other impacts may be surprising to many people, especially those impacts that are regional and not raised to the level of international concern.This paper will take a very high level look at a number of global, regional and local human interactions with the environment, and how mitigating those impacts requires a very broad and multi-disciplinary response. Examples will focus on water, carbon and energy, all of which are needed for life, as we know it, to exist. Stewardship will be shown to involve determination and monitoring of many key indicators and environmental processes, followed by the tough decisions on how to steward those processes to maintain a healthy environment for all the planet's inhabitants. Stewardship is not easy, and there are few cases where solutions can be neatly divided into good or bad, positive or negative.     

Analysis of energy use in a sample of Chinese villages

This paper summarises the methodology and results of work involved in the investigation of energy demand in six Chinese villages included in the SUCCESS Project. The procedures used to collect data associated with local energy demand are explained and the approach to data analysis is explained. Results are provided in terms for delivered energy consumption, as an indicator of energy demand; primary energy consumption, as an indicator of energy resource depletion; and carbon dioxide emissions, as an indicator of global climate change. Similarities and differences between results for this sample of villages are considered. The important causes of differences in results are investigated.     

碳捕集与封存技术适用风险预防原则的理论建构与路径完善

以碳捕集与封存为典型的新兴技术在应对气候变化上的降碳功能显著,但该技术颇具不确定性。“决策于未知”成为政府规制技术风险的真实写照,如何在鼓励碳捕集与封存技术发展,助力“双碳”目标实现的同时,应对随之而来的风险挑战与安全诉求,既是国家必须肩负的义务,也是回应公众期待的内在要求。应运而生的风险预防原则作为应对气候变化的重要举措,为技术风险规制提供了合法性与正当性基础,对于碳捕获、封存技术发展与碳中和目标实现具有重要现实意义。为此,风险预防原则在技术规制中,应当整体遵循弱风险预防理念,彰显秩序、正义和效率的多元价值诉求,实现科学理性与社会理性的平衡。在此基础上,通过多手段的综合应用,开放的风险决策结构,强化风险管理的动态调试,以预防性环境行政公益诉讼为保障,将风险预防原则融汇于碳捕集与封存技术风险规制中。     

Carbon black-benzo(a)pyrene complex-induced apoptosis and autophagy blockage in rat alveolar macrophages

Abstract

Cooking of foods and the burning of biomass and fossil fuels in stoves are the main sources of cooking fumes, with carbon black and polycyclic aromatic hydrocarbons as main components. The toxicity of carbon black and polycyclic aromatic hydrocarbons has been well studied individually, but the combined toxicity is much less understood. Carbon black can adsorb benzo(a)pyrene to form a complex which displays an altered physical form which in this study has been constructed to simulate particles in the cooking fumes and explore the combined toxic effect on rat alveolar macrophages. The complex-induced cell apoptosis and blocked cell autophagy flux compared with both individually. The mechanism of toxicity may be by intracellular reactive oxygen species generation, impairing the mitochondrial membrane potential and activating apoptosis signaling pathways.     

Green identity,green living? The role of pro-environmental self-identity in determining consistency across diverse pro-environmental behaviours

Policy-makers are interested in cost-effective and socially acceptable ways of encouraging the public to adopt more environmentally-friendly lifestyles. One area which UK policy-makers are focussing on is ‘catalyst behaviour’, the notion that taking-up a new behaviour (such as recycling) may cause people to adopt other pro-environmental behaviours. Yet, evidence for such ‘spill-over’ effects is so far limited, and it is unclear when and how cross-situational motivations (e.g., pro-environmental identity) may predict behaviour and when contextual factors are more important. We report on a postal survey (N = 551) of pro-environmental behaviours amongst the UK public. We assess the influence of pro-environmental self-identify on consistency across a range of behaviours. Pro-environmental values, perceived behavioural control, subjective norm, attitudes, and demographic factors were also measured. Findings show self-identity to be a significant behavioural determinant over and above theory of planned behaviour variables for carbon offsetting behaviour. However, pro-environmental self-identity was only a significant predictor for certain other pro-environmental behaviours; background variables were also important predictors. Limitations of the study, and implications for theory and policy, are discussed.     

N-methylcarbamate pesticides and their phenolic degradation products: hydrolytic decay,sequestration and metal complexation studies

We report on the rates of decomposition of a group of N-methylcarbamate (NMC) pesticides (carbaryl, carbofuran and propoxur) under pre-determined tropical field conditions. Rates of decomposition for three NMCs were determined at pH 7.08 and T?=?20?°C and pH 7.70 and T = 33?°C respectively, as follows: carbaryl (78?days and 69?days); carbofuran (143?days and 83?days) and propoxur (116?days and 79?days). Investigation on methods for removal of NMCs and their phenolic decomposition products shows that activated charcoal outperforms zeolite, alumina, diatomaceous earth, cellulose and montmorillonite clay in the removal of both NMCs and phenols from aqueous solution. Furthermore, metal complexation studies on the NMCs and phenols showed that Fe (III) forms a complex with isopropoxyphenol (IPP) within which the Fe:IPP ratio is 1:3, indicative of the formation of a metal chelate complex with the formula Fe(IPP)₃.