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41.
Thacker NP Nitnaware VC Das SK Devotta S 《Environmental science and pollution research international》2007,14(4):225-226
Samples of effluents, sludge, pulp, final products (paper) and soil were collected from the identified pulp and paper mills
in India. The samples were analysed for 2,3,7,8-tetrachloro-dibenzo-p-dioxin (2,3,7,8-TCDD) and other dioxin congeners and
precursors. Pulp and paper mills using chlorine for the bleaching process showed the presence of 2,3,7,8-TCDD in effluent
samples. In the effluent and pulp samples from mills where chlorine dioxide was used as a bleaching agent, the 2,3,7,8-TCDD
congener ranged from below the detection limit 0.05 to 0.12 ngL−1/ngg−1. The relative standard deviation of reproducibility and the percent recovery of 2,3,7,8-TCDD were 2.07 and 82.4% in pulp
and 2.8 and 92% in effluent, respectively. The 1,3,6,8-TCDD was the only other major dioxin congener found in the treated
and untreated effluent and sludge samples. However, dichlorobenzene, trichlorophenyl, and hexachlorobiphenyl were detected
in all samples. The formation of dioxins can be minimised by replacing chlorine with chlorine dioxide in bleaching processes
in pulp and paper mills. 相似文献
42.
李维安 《中国安全科学学报》2005,15(5):109-112
提出了一个利用碳纤维混凝土与普通混凝土进行复合,实现结构安全监测的技术方法。根据普通混凝土与碳纤维混凝土之间良好的亲和能力,将碳纤维混凝土浇铸在结构承载的薄弱部分,利用碳纤维混凝土的压敏特性,可以对该部分的服役状态进行监测,获得结构的变形情况;另一方面,利用碳纤维混凝土的基本特性,还可以适当改善结构的承载强度。笔者所提出的复合结构既具有普通混凝土结构的基本特征,又赋予了结构的自我监测功能,比较有效地克服了全碳纤维混凝土结构建造所面临的电阻率波动、骨料石子影响和建设成本等几个方面的技术问题。 相似文献
43.
A five-stage sequential leaching procedure was used to fractionate 13 heavy metals (Cd, Cu, Pb, Cr, Zn, Fe, Mn, Al, Ni, Co, As, V, Ba) and sulphur (S) in lime waste from the lime kiln at the causticizing plant of Stora Enso Oyj Veitsiluoto Pulp Mills at Kemi, Northern Finland, into the following fractions: (1) water-soluble fraction (H2O), (2) exchangeable fraction (CH3COOH), (3) easily reduced fraction (HONH3Cl), (4) oxidizable fraction (H2O2 + CH3COONH4), and (5) residual fraction (HF + HNO3 + HCl). Although metals were leachable in all fractions, the highest concentrations for most of the metals were observed in the residual fraction (stage 5). It was also notable that the total heavy metal concentrations in lime waste did not exceed the maximal allowable heavy metal concentrations for soil conditioner agents set by the ministry of the Agricultural and Forestry in Finland. The heavy metals concentrations in lime waste were also lower than the maximal allowable heavy metals concentrations of the European Union Directive 86/278/EEC on the protection of environment, and in particular of the soil, when sewage sludge is used in agriculture. The Ca concentration (420 g kg−1; d.w.) was about 262 times higher than the typical value of 1.6 g kg−1 (d.w.) in arable land in Central Finland. However, the concentration Mg (0.2 g kg−1; d.w.) in lime waste was equal to the Mg concentration in arable land in the Central Finland. The lime waste has strongly alkaline pH (12.8) and a neutralizing value (i.e. liming effect) of 47.9% expressed as Ca equivalents (d.w.). This indicates lime waste to be a potential soil conditioner and improvement as well as a pH buffer. 相似文献
44.
45.
介绍了侧联式球磨机噪声产生原理及其噪声控制方法,选择了制作局部式隔声罩的噪声控制设计和装置结构.在中国铝业中州分公司热电厂球磨机上应用,取得了很好的隔声效果. 相似文献
46.
采用水解酸化 CAST 混凝 复合滤池与水解酸化 接触氧化 混凝 复合滤池2种组合工艺对造纸中段废水与生活污水进行合并处理对照试验.结果表明,两种工艺都是切实可行的,二级出水均可达到<污水综合排放标准>(GB8978-1996)二级标准,深度处理出水可达中水水质要求.其中以水解酸化 CAST 混凝 复合滤池组合工艺效果最好. 相似文献
47.
Lactobacillus plantarum SF5.6 is one of the lactic acid bacteria (LAB) that has the highest ability of molasses melanoidin (MM)
decolorization among the 2114 strains of LAB. The strains were isolated from spoilage, pickle fruit and vegetable, soil and sludge from
the wastewater treatment system by using technical step of enrichment, primary screening and secondary screening. This LAB strain
SF5.6 was identified by 16S rDNA analysis and carbohydrate fermentation (API 50 CH). The top five LAB strains having high MM
decolorization (> 55%), namely TBSF5.8-1, TBSF2.1-1, TBSF2.1, FF4A and SF5.6 were selected to determine the optimal condition.
It was found that the temperature at 30°C under facultative conditions in GPY-MM medium (0.5% glucose, 0.1% peptone, 0.1% yeast
extract, 0.1% sodium acetate, 0.05% MgSO4 and 0.005% MnCl2 in MM solution at pH 6) giving a high microbial growth and MM
decolorization for all five strains. It was noticed that the decolorization of MM by LAB strains might be cell growth associated. L.
plantarum SF5.6 grew rapidly within one day while the other strains took 2–3 days. This L. plantarum SF5.6 could rapidly decolorize
MM to 60.91% without any lag phase, and it also had the ability to remove 34.00% phenolic compounds and 15.88% color from treated
palm oil mill e uent. 相似文献
48.
Chokri Belai Moncef Khadraoui Salma Mseddi Monem Kallel Boubaker Elleuch Jean Francois Fauvarque 《环境科学学报(英文版)》2013,25(1):220-230
Problems related with industrials effluents can be divided in two parts: (1) their toxicity associated to their chemical content which should be removed before discharging the wastewater into the receptor media; (2) and the second part is linked to the difficulties of pollution characterisation and monitoring caused by the complexity of these matrixes. This investigation deals with these two aspects, an electrochemical treatment method of an olive mill wastewater (OMW) under platinized expanded titanium electrodes using a modified Grignard reactor for toxicity removal as well as the exploration of the use of some specific analytical tools to monitor effluent phenolic compounds elimination. The results showed that electrochemical oxidation is able to remove/mitigate the OMW pollution. Indeed, 87% of OMW color was removed and all aromatic compounds were disappeared from the solution by anodic oxidation. Moreover, 55% of the chemical oxygen demand (COD) and the total organic carbon (TOC) were reduced. On the other hand, UV- Visible spectrophotometry, Gaz chromatography/mass spectrometry, cyclic voltammetry and 13 C Nuclear Magnetic Resonance (NMR) showed that the used treatment seems efficaciously to eliminate phenolic compounds from OMW. It was concluded that electrochemical oxidation in a modified Grignard reactor is a promising process for the destruction of all phenolic compounds present in OMW. Among the monitoring analytical tools applied, cyclic voltammetry and 13 C NMR are among the techniques that are introduced for the first time to control the advancement of the OMW treatment and gave a close insight on polyphenols disappearance. 相似文献
49.
造纸工业总排水及漂白废水中AOX监测方法的研究 总被引:4,自引:0,他引:4
运用TOX测定仪对造纸工业废水及漂白废水中AOX(可吸附有机卤素)测定;水样用硝酸调pH<2后,以双根活性炭玻璃填充柱连续吸附;将吸附有机物的活性炭在氧气流中燃烧热解、用微库仑法测定其卤化氢.样品前处理比现行活性炭振荡吸附法样品及试剂用量少、快速、重现性好.方法测定浓度下限为3.73μg/L. 相似文献
50.
M. Hafidi G. Ait Baddi V. Gilard P. Ramos K. Alimi J. C. Revel 《Chemistry and Ecology》2005,21(4):313-324
Elemental analysis, fluorescence spectroscopy and differential scanning calorimetry (DSC) were applied to the study of fulvic acids isolated from different stages during olive mill waste composting. The fulvic extracted acids are characterized by a high nitrogen content and O/C ratio values that may result from the high degree of humification and the synthesis of more condensed humic complexes. This was confirmed by fluorescence spectroscopy in the synchronous-scan mode by the decrease of shoulder intensities at intermediate wavelengths indicating the increase of polycondensation and conjugation of unsaturated structures and the greater uniformity of fluorophores. Fluorescence spectra in the emission, excitation and synchronous modes became simpler with compost maturation. This was confirmed by DSC results which proved the high degree of polycondensation of aromatic nuclei of fulvic acid molecules during olive mill waste composting. 相似文献