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61.
This study was a preliminary step to evaluate the acute toxicity of 1-methyl-3-octylimidazolium chloride ([C8mim]Cl) on loach (Misgurnus anguillicaudatus) by determining the effects on hepatic antioxidant enzyme activities and by the comet assay. The results showed that [C8mim]Cl had acute toxicity at concentrations above 20 mg L?1, inducing oxidative stress and genotoxicity on fish liver cells. In respect to enzyme activities, [C8mim]Cl induced changes in the activities of superoxide dismutase, catalase, and glutathione content the livers of fish exposed at 20–80 mg L?1. [C8mim]Cl at the same exposure level caused a remarkable increase in malondialdehyde level. The comet assay indicated that [C8mim]Cl at 20–80 mg L?1 induced genotoxicity in liver cells. With increased exposure concentration and time, the two comet parameters trailing rate and tail moment were significantly increased, with significant differences (P < 0.05) observed between control group and each treatment group. The present study shows that ionic liquids can be a threat to the health of aquatic organism when accidentally released to aquatic ecosystems. 相似文献
62.
聚合氯化铝与三氯化铁混凝剂在常规水处理中的运用 总被引:3,自引:0,他引:3
通过聚合氯化铅与三氯化铁在常规水处理的生产性实验,从经济成本、水质指标和实际使用存在的问题对其进行分析比较,并比较了两种混凝剂在常规水处理中的优缺点。 相似文献
63.
本实验以玉米秸秆为原料,制备了生物炭和AlCl3改性生物炭,研究了2种生物炭分别调理污泥后的脱水效果,并探讨了污泥脱水性能的改善机理.结果表明,经过2种生物炭调理后,污泥比阻(SRF)、泥饼含水率(MC)、污泥沉降体积指数(SV30)、毛细抽吸时间(CST)均下降,污泥净产率(YN)升高,说明污泥脱水性能得到了改善,且AlCl3改性生物炭对污泥脱水性能的改善效果明显优于生物炭.当AlCl3(溶液浓度3mol/L)改性生物炭的用量为3g/L时,调理后的污泥SRF,MC,SV30,CST分别降低至1.3×1012m/kg,81.9%,78.6%,35s,YN增加至17.8kg/(m2·h).分析原因:一方面,经过生物炭调理后,泥饼中会形成一定的骨架结构,使得污泥中的水和EPS能够更容易地释放;另一方面,经过AlCl3改性后,改性生物炭携带的正电荷(Al3+)能够与污泥颗粒所带的负电荷发生电中和作用,使得污泥颗粒更容易聚集,从而提高污泥的脱水效果. 相似文献
64.
为探明氯化铁(Fe Cl3)絮凝-直接过滤工艺对地下水中砷(As)的去除过程及机制,分别进行了批吸附实验、现场絮凝-直接过滤实验、扩展X射线精细结构光谱(EXAFS)及电荷分布多位络合(CD-MUSIC)模拟.采集的地下水样品As主要为五价[As(Ⅴ)],浓度为40μg·L-1.现场柱实验直接过滤工艺中Fe投加量为1.5 mg·L-1,出水As(Ⅴ)浓度均低于10μg·L-1,92 h内可提供64 984 L安全饮用水.固体废物毒性浸出实验表明泥饼浸出液中As浓度为3.4μg·L-1,远低于美国环保署限定值(5 mg·L-1).EXAFS和CD-MUSIC模拟表明Fe Cl3絮凝去除地下水中As(Ⅴ)存在两种机制:在p H 3~9.5范围内,As(Ⅴ)主要以双齿双核吸附在氢氧化铁上;p H9.5时,As(Ⅴ)主要与Ca2+和Mg2+形成沉淀而去除. 相似文献
65.
E. G. Plotnikova D. O. Rybkina L. N. Anan’ina O. V. Yastrebova V. A. Demakov 《Russian Journal of Ecology》2006,37(4):233-240
Microorganisms capable of degrading monocyclic and polycyclic aromatic hydrocarbons and several chlorinated aromatic compounds were isolated from soils polluted with industrial waste from chemical plants. They were identified as representatives of the genera Pseudomonas, Flavobacterium, Alcaligenes, Rhodococcus, Microbacterium, Cellulomonas, Arthrobacter, and Brevibacterium. Among them, bacteria capable of utilizing xenobiotics in a wide range of ambient temperatures and pH and in the presence of high sodium chloride concentrations were revealed. 相似文献
66.
Polyvinylidene chloride (PVDC; polymer of 1,1-dichloroethylene) was combusted with paper in a well-controlled, small-scale incinerator at an average grate temperature of 700 °C, and then dioxins (PCDDs, PCDFs, and coplanar-PCBs) formed in the exhaust gases were analyzed by gas chromatography/mass spectrometry. PVDC lowered the combustion temperature due to its less flammable character. The amount of total dioxins (PCDDs + PCDFs + coplanar-PCBs) formed in the exhaust gas was 58.0 ng/g of a combustion sample and its toxicity equivalency quantity (TEQ) value was 0.64 ng-TEQ/g. The amount of PCDDs formed in the sample ranged from 2.33 ng/g (Cl8-isomer) to 0.048 ng/g (Cl1-isomer). The lower the number of chloride, the less production of PCDDs. On the other hand, there was no relation between the number of chloride and PCDF formation. The amount of PCDFs formed in the sample ranged from 8.02 ng/g (Cl2-isomer) to 4.46 ng/g (Cl8-isomer). A polyvinylchloride (PVC) sample produced 207 ng/g of total dioxins and a PVDC sample produced 57.4 ng/g of total dioxins when they were combusted under the same conditions. An approximately equal composition of dioxin isomers was formed from PVDC and PVC samples. Paper was found to contribute to PCDF formation when it was combusted with plastics. 相似文献
67.
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69.
The potentially explosive reaction of hydrogen peroxide (H2O2) and copper chloride (CuCl2) was investigated. Pressure tests revealed that the reaction was strongly temperature - dependent and can easily undergo runaway reaction. Nevertheless, there was only a slight pressure increase at the low temperatures studied or when using low concentrations of CuCl2. Under the conditions generating the slight pressure increase, hypochlorite anions (ClO−) are generated and the acidity increases. As the reaction reaches completion, ClO− disappears, and the acidity decreases. Interestingly, the addition of phosphate buffer to maintain the weakly acid conditions led to a runaway reaction, and the use of basic ClO− promoted the exothermic reaction. Based on the results, acidity has a strong impact on the reaction behaviour. 相似文献
70.
Runaway reactions present a potentially serious threat to the chemical process industry and the community; such reactions occur time and time again often with devastating consequences. The main objective of this research is to study the root causes associated with ammonium nitrate (AN) explosions during storage. The research focuses on AN fertilizers and studies the effects of different types of fertilizer compatible additives on AN thermal decomposition. Reactive Systems Screening Tool (RSST) has been used for reactivity evaluation and to better understand the mechanisms that result in explosion hazards. The results obtained from this tool have been reported in terms of parameters such as “onset” temperature, rate of temperature and pressure rise and maximum temperature. The runaway behavior of AN has been studied as a solid and solution in water. The effect of additives such as sodium sulfate (Na2SO4) and potassium chloride (KCl) has also been studied. Multiple tests have been conducted to determine the characteristics of AN decomposition accurately. The results show that the presence of sodium sulfate can increase the “onset” temperature of AN decomposition thus acting as AN thermal decomposition inhibitor, while potassium chloride tends to decrease the “onset” temperature thus acting as AN thermal decomposition promoter. 相似文献