Adsorption thermodynamics and kinetic investigation of aromatic amphoteric compounds onto different polymeric adsorbents

The adsorption behavior of p-aminobenzoic acid and o-aminobenzoic acid onto the different polymeric adsorbents was systematically investigated as a function of the solution concentration and temperature.Experimental results indicated that the equilibrium adsorption data of the four polymeric adsorbents fitted well in the Freundlich isotherm.The adsorption capacity of multi-functional polymeric adsorbent NJ-99 was the highest,which might be attributed to the strong hydrogen-bonding interaction between the amino groups on the resin and the carboxyl group of aminobenzoic acid.The adsorption capacity of o-aminobenzoic acid onto any adsorbent was higher than p-aminobenzoic acid.Thermodynamic studies suggested the exothermic,spontaneous physical adsorption process.Adsorption kinetics results showed that the adsorption followed the pseudo-second-order kinetics model and the intraparticle mass transfer process was the rate-controlling step.     

政府干预农地流转:农户收入及资源配置效率

本文基于江苏省苏北地区灌云县和金湖县的农户调研,采用内生性处理回归模型考察政府干预下土地流转对不同类型农户收入的影响,并从农户土地和劳动力资源配置效率的角度解释农户收入变化的根源。研究结果表明,政府干预下土地流转对不同类型农户收入的影响效应有很大差异,农户土地转入后收入增加了161.2%,转出户收入并未显著增加;从农户资源配置角度考察,发现农户转入土地后农业生产效率显著提高,转出土地后农业生产率降低;农户土地转出后非农工作时间和工作报酬并未显著增加,表明转出户并未提高非农劳动力资源配置效率。同时,本文比较政府主导和农户自发两种类型农地流转对农户收入和资源配置效率的影响差异。结果发现,相对于自发土地流转的农户,政府主导下农户转入更大面积土地,并显著提高了单位面积土地生产效率和家庭收入水平;而政府干预土地转出不利于农户土地和劳动力资源配置效率及收入水平的提高。基于以上分析,本文认为政府干预降低了土地流转交易费用,有利于转入户扩大土地面积,实现规模经济效益,进而增加转入户收入;然而,政府干预下转出户资源配置面临较大约束,配置效率和收入都未能实现最大化。因此,政府在完善农地流转服务政策的同时,应当尊重农户土地流转意愿,使得农户土地流转符合家庭资源配置收入最大化目标。同时,要通过非农就业培训、发展非农经济,吸纳更多劳动力转移到非农业领域,进一步促进农村土地流转和规模经营,优化农村土地和劳动力资源配置效率,持续增加农民收入。     

基于生态足迹的武汉城市圈生态承载力评价和生态补偿研究

在推进新型城镇化和生态建设的背景下,客观定量评价区域生态环境状态,是当前我国生态建设重要而紧迫的任务之一。高密度的人类活动会对自然生态系统产生超负荷的压力,通过生态承载力的分析能够定量测度这种状况,为区域可持续发展提供借鉴意义。基于生态足迹模型,计算了2008年和2013年武汉城市圈各县域单元的生态足迹/承载力,并进行了时空变化分析。研究发现武汉城市圈各县域单元的生态足迹和生态承载力在空间上存在显著的差异性,生态足迹逐年增加,生态承载力的变化相对较小,出现两级分化的现象。根据生态足迹/承载力进行跨区县生态补偿测算,得到2008年和2013年武汉城市圈48个县域的转移支付情况,表明如果运用财政转移支付的手段,整个区域能够达到生态系统供给和需求动态平衡的目标,缓解武汉城市圈的生态压力,实现武汉城市圈的可持续发展。     

农户兼业阶段性分化探析

当前农户兼业的阶段性分化其本质是农户之间兼业进程的不统一,进而导致了严重的农村社会分化问题。本文利用江苏省苏北地区农户调研数据分析了当前农户兼业阶段性分化的现状及其带来的社会后果,利用似不相关双变量Probit模型分析了农户兼业阶段性分化的原因,得出了阻碍农户兼业发展的主要制约因素。结果显示,家庭人力资本稀缺是农户实现兼业生产的主要制约因素,农户无法进行非农工作主要是受到家庭人口规模小、老龄化严重的限制,这一部分农户家庭生活水平低,面临严重的"贫困陷阱"。政府直接干预土地流转使部分农户被动退出了农业生产,形式上实现了农户兼业进程的统一,但损害了农户的土地权益,造成农村土地产权不稳定,降低了农户自发性退农倾向,妨碍了土地市场的进一步发展,因此实质上对农户兼业进程起到了阻碍作用。此外,由于土地承包经营证书对承包经营权权能、地块四至等信息界定不清晰,对农户兼业进程的发展没有刺激作用。综合以上结论可知,土地产权以及农户家庭人力资本是导致当前农户阶段性分化的主要原因。政府不应对农村土地市场进行直接干预,而应通过完善农村社保体系、扶持农户非农就业、加快新一轮土地确权发证工作以促进土地市场与农户兼业进程的发展,在市场机制为主、政府调控为辅的环境下合理实现土地的集中与农业规模经营。     

农地流转背景下地块规模对农户种粮投入影响分析

近年来粮食安全受到国家和社会的广泛关注,农地投入作为粮食生产的重要要素,是保障粮食稳定产出的前提。学者就农地规模对农户种粮投入的影响已进行了较多研究,但受农地流转的影响,土地要素更具多样化,土地规模与农户种粮投入的关系发生变化。随着农地流转在我国的快速发展,探析农地流转影响下土地规模对农户种粮投入影响的变化成为一个亟待研究的问题,对保障国家粮食安全具有重要意义。考虑到地块的异质性,本文基于山东、河南、安徽三个粮食主产省622户农户1 284个地块的粮食生产数据从村庄和农户两个层次控制了生产要素市场价格、地块要素等非主观因素,进行多层模型回归分析。结果表明,农地流转特征及地块特征对农户粮食生产单位面积投入有显著影响。地块规模和转入地占比对农地投入影响为负,转入地占比越大,地权稳定性越低,农户投入积极性受到挫伤越明显,在转入地上的投入减少。随着转入土地面积的增加,农户从事粮食生产的机会成本增大,使其有更强的动力增加种粮投入,地块规模的负向影响程度降低。基于分析结果,本文得出以下3点结论:(1)规模化经营有利于降低单位面积种粮成本;(2)农地流转发生时,地块规模对种粮投入的影响发生改变,成片规模化经营将成为我国粮食生产的必然趋势;(3)提高土地综合条件可以降低投入成本,并提高农户投入积极性。要保障国家粮食安全,需从降低种粮成本、提高农户收益着手,建议鼓励农村土地流转,推动粮食规模化生产,同时也要注重增加财政拨款,建设高标准粮田,强化高标准粮田的农业基础设施建设,完善田间配套工程。     

A real-time simulating non-isothermal mathematical model for the passive feed direct methanol fuel cell

In order to understand the complex transport phenomena in a passive direct methanol fuel cell (DMFC), a theoretical model is essential. The analytical model provides a computationally efficient framework with a clear physical meaning. For this, a non-isothermal, analytical model for the passive DMFC has been developed in this study. The model considers the coupled heat and mass transport along with electrochemical reactions. The model is successfully validated with the experimental data. The model accurately describes the various species transport phenomena including methanol crossover and water crossover, heat transport phenomena, and efficiencies related to the passive DMFC. It suggests that the maximum real efficiency can be achieved by running the cell at low methanol feed concentration and moderate current density. The model also accurately predicts the effect of various operating and geometrical parameters on the cell performance such as methanol feed concentration, surrounding temperature, and polymer electrolyte membrane thickness. The model predictions are in accordance with the findings of the other researchers. The model is rapidly implementable and can be used in real-time simulation and control of the passive DMFC. This comprehensive model can be used for diagnostic purpose as well.     

企业环境寻求、污染密集型生产区际转移与环境监管

在当前强调产业结构调整的政策背景下,产业有序转移必须以有利于或者加强环境保护为基本目标。环境规制差异造成了不同经济地域之间污染密集型生产的比较优势调整,强化了高污染产业进行生产区位选择的动机,以规避来自政府的环境监管。环境治理成本的不同是高污染企业区际转移的重要驱动因素,企业环境寻求策略推动了污染密集型生产由环境规制强度高的地区向环境规制松弛地区的转移。企业污染密集型生产的区际转移受到环境要素产品生产比较优势的明显影响,这些环境要素产品与区际环境规制差异、企业市场内部化战略以及污染密集型产品的生命周期密切关联。借鉴一般均衡分析框架,可以明晰企业环境寻求策略下污染密集型生产转移的内在机制。一方面,环境成本差异决定了非环境友好产品生产转移的意愿,高强度的环境规制使得企业生产的边际环境治理成本和平均环境治理成本提高,污染密集型生产外迁的动力加强,生产效率高的企业对环境规制强度更加敏感。污染密集型生产承接地提高环境规制强度能形成对环境负面影响的有力对冲,遏制环境恶化趋势。另一方面,合理的区际环境政策差异能在产业有序转移中发挥重要作用。合理设定区际环境规制级差与碳信征信系统建设,加强分类监管与行业节能减排,建立拟承接生产项目的效率筛选机制,提高区域市场开放程度、降低产业优惠政策所形成隐性市场保护等环境监管手段是保证欠发达地区通过产业承接实现跨越式发展的关键所在。     

壳聚糖/纳米CdS复合颗粒可见光光催化降解猩红B动力学研究

采用仿生矿化法制备了壳聚糖/纳米CdS复合颗粒光催化剂,并用于可见光光催化降解猩红B染料模拟废水,研究了猩红B初始浓度、pH、催化剂投加量和催化剂重复使用次数等因素对猩红B光催化降解的影响.X射线衍射(XRD)分析表明,壳聚糖能有效负载CdS纳米微晶.采用Langmuir-Hinshelwood模型描述壳聚糖/纳米CdS复合颗粒可见光光催化降解猩红B反应动力学行为,在猩红B初始质量浓度较低(≤20 mg/L)时,光催化降解过程符合假一级动力学方程.降低猩红B初始浓度和溶液pH都可显著增大光催化降解速率常数;催化剂投加量小于0.7 g/L时,光催化降解速率随其增加而增大,但催化剂投加量过大会使光催化降解速率减小;催化剂重复使用第5次时,猩红B光催化降解速率常数仍为第1次使用时的63.4%.     

Arsenic rich iron plaque on macrophyte roots - an ecotoxicological risk?

Arsenic is known to accumulate with iron plaque on macrophyte roots. Three to four years after the Aznalcóllar mine spill (Spain), residual arsenic contamination left in seasonal wetland habitats has been identified in this form by scanning electron microscopy. Total digestion has determined arsenic concentrations in thoroughly washed ‘root + plaque’ material in excess of 1000 mg kg⁻¹, and further analysis using X-ray absorption spectroscopy suggests arsenic exists as both arsenate and arsenite. Certain herbivorous species feed on rhizomes and bulbs of macrophytes in a wide range of global environments, and the ecotoxicological impact of consuming arsenic rich iron plaque associated with such food items remains to be quantified. Here, greylag geese which feed on Scirpus maritimus rhizome and bulb material in areas affected by the Aznalcóllar spill are shown to have elevated levels of arsenic in their feces, which may originate from arsenic rich iron plaque.     

Study of lead phytoavailability for atmospheric industrial micronic and sub-micronic particles in relation with lead speciation

Particles from channelled emissions of a battery recycling facility were size-segregated and investigated to correlate their speciation and morphology with their transfer towards lettuce. Microculture experiments carried out with various calcareous soils spiked with micronic and sub-micronic particles (1650 ± 20 mg Pb kg⁻¹) highlighted a greater transfer in soils mixed with the finest particles. According to XRD and Raman spectroscopy results, the two fractions presented differences in the amount of minor lead compounds like carbonates, but their speciation was quite similar, in decreasing order of abundance: PbS, PbSO₄, PbSO₄·PbO, α-PbO and Pb⁰. Morphology investigations revealed that PM_2.5 (i.e. Particulate Matter 2.5 composed of particles suspended in air with aerodynamic diameters of 2.5 μm or less) contained many Pb nanoballs and nanocrystals which could influence lead availability. The soil-plant transfer of lead was mainly influenced by size and was very well estimated by 0.01 M CaCl₂ extraction.