突发事件连锁反应的实证研究——以2008年初我国南方冰雪灾害为例

从突发事件连锁反应分析,认为2008年初我国南方的冰雪灾害是由自然灾害引发的连锁反应事件。选择了新浪网冰雪灾害报道专题的近4 000篇报道作为数据源,从时间、空间和事件角度揭示了此次冰雪灾害的演化过程,并分析了事件扩散的原因。     

基于隶属函数的高速公路安全距离模型研究

为了改善高速公路防追尾安全距离模型,对模型中的驾驶员反应时间进行研究,分析不同车速时驾驶员反应时间对安全距离的影响。驾驶员反应时间受驾龄、应变能力、性别、心理生理状况、车速等多种因素的影响。基于模糊数学中隶属函数的有关理论,利用Matlab软件,在驾驶员反应时间大小允许的范围内,综合考虑各种主要因素,确定驾驶员反应时间。通过具体实例说明该方法的应用,结果证明,应用模糊数学,可以计算出不同的驾驶员,在不同的车速时的反应时间。     

化学品反应危险性分级方法研究与应用

针对化学品反应危险性的评价,介绍利用最大分解热,反应放热功率,绝热反应参数等方法对化学品反应危险性进行分级的几种方法及各自特点。通过分析整合不同分级方法,提出一种基于实测反应放热参数的分级方法,此方法以初始放热温度和反应热组成指标体系,同时配合燃爆曲线实现对化学品反应危险性的分级,得到的结果对于化学品的安全评价有较强的参考价值。考察了6种有机过氧化物的放热性质,诠释了有机过氧化物的反应危险性,应用所提出的反应危险性分级方法对其进行分级,并对分级方法进行了验证。该方法结合了实验结果和多种分级方法的优点,使化学品反应危险性分级方法具有更强的实用性。     

Secondary materials transfer from Japan to China: destination analysis

China has been the largest importer of secondary materials for recycling from Japan during the past decade. In this study, we analyzed the transfer of major secondary materials (plastic, steel, copper, and aluminum scrap) from Japan to China. We identified specific destinations for secondary materials, and the characteristics of secondary materials transferred to China. The major destination for the transfer of secondary materials to China is Guangdong province and part of the Huadong area (Shanghai, Zhejiang, and Jiangsu). Most scrap metal imported into China is of low quality. The destinations of most high-quality nonferrous scrap, imported as processed goods on consignment or through the transit improvement trade, are the northeast border provinces, especially Xinjiang Uighur province. The coefficients of specialization for Chinese cities were different from those for the provinces. Guangdong shows an average recycling structure for China. The structure gradually changes from south to north.     

具有特定拓扑结构的聚烯烃高分子的合成

具有特定拓扑结构的聚合物合成一直是高分子合成化学领域的一个重要研究内容，设计和合成具有特定拓扑结构的聚烯烃高分子更是进一步发掘聚烯烃这一量大面广的通用高分子材料的性能、开拓其新的应用领域的重要手段。在催化剂和聚合方法的研究取得重要进展的基础上，近年来国际上在合成不同拓扑结构（包括嵌段、接枝、梳型和星型）的聚烯烃高分子研究方面发展也较快，所合成的部分高分子亦显示出独特的功能性。本文首先综述不同拓扑结构聚烯烃高分子合成的研究现状，然后结合近期化学所在此领域的研究进展，提出独特的以苯乙烯封端反应性聚烯烃为模块构建拓扑结构聚烯烃的新思路。     

About stability of the ignition process of small solid particle

The distributed mathematical model of magnesium particle ignition is developed taking into account the heterogeneous chemical reaction and the domain of particle thermal influence on gas. The problem solvability in the stationary case has allowed one to expand classification of regular modes of heating as well as the modes of extinction and ignition of a particle. The limiting size of a gas layer near a particle is found that determines an ignition mode. It is shown that the ignition delay time grows if we take into account the gas layer near the particle. Stability of some heating modes within the framework of finite and infinitesimal perturbations is studied. An opportunity to control the ignition process by high-frequency thermal action on the unstable particle gas states is shown.     

城市级危险废物转移安全监管系统设计研究

通过对我国危险废物运输安全现状的分析,以及危险废物转移运输管理中存在的问题,借鉴国内外先进经验,提出构建低成本城市级危险废物转移监控系统的设想,为城市危险废物管理提供辅助工具。以广州市为例,将自建监控中心与基于商业平台监管危险废物转移的设计方案作对比,发现两者构建技术大致相同,但基于商业平台的监管方案节省系统的建设和运行费用50%以上,其不仅可实现政府部门通过内网进行正常业务管理,还可实现政府和危险废物运输企业通过外网对危险废物运输车辆进行实时安全监控,能有效地提高政企对危险废物运输的两级安全监管效能,为突发污染事件提供查询和应急辅助决策,同时为我国各城市危险废物运输的安全监管提供借鉴意义。     

源液室火灾爆炸危险性分析及风险控制措施

对某企业源液室的危险有害因素进行了分析和辨识,利用火灾爆炸指数法进行了风险评价,针对源液室的现状提出了安全对策,同时建议其进行风险转移,以提高该企业抵抗风险的能力.     

Thermal Solid State Reactions of Potato Starch with α-Hydroxy Acids

The numerous applications of dextrins resulting from the heating of potato starch with α-amino acids prompted me to check the thermal reactions of starch with hydroxy acids and their lactones, such as citric acid, lactic acid, tartaric acid, and coumarine. The course of reactions was observed by means of Simultaneous TG/DSC Thermal Analyser. The thermal reactions were carried out on convectional and microwave heating. The course of reactions under such conditions was compared and properties of resulting dextrins were recognized. The structure and properties of products were obtained from FTIR spectra, water solubility tests, and pH measurements. It was found, that hydroxy acids and/or products of their thermal transformations reacted with starch and/or resulting dextrins producing esters or crosslinking esterification of dextrins took place. The properties of new dextrins were presented in order to check, in further studies, their application for selective flotation of complex metal ores and their suitability as prebiotics.     

转锥式生物质热解装置中热载体加热方案选择与设计

根据转锥式生物质热解装置中对加热设备的要求,先后分别选择和设计了三种不同的加热方案,在实际应用中逐步了解每套加热设备的优缺点,为加热设备的改进和该项技术的应用推广奠定坚实的基础.