选煤脱除氟、砷的研究

研究了采自西南3省、1市17个选煤厂的原煤和洗精煤样品,分析了灰分、氟和砷含量,探讨了选煤脱除氟、砷的机理和影响因素。结果表明,选煤能有效降低煤中氟、砷的含量,应用前景广阔。     

Comparative on Causes and Accumulation of Selenium in the Tree-rings Ambient High-selenium Coal Combustion Area from Yutangba, Hubei, China

Toxic trace elements emitted during coal combustion are the main sources of air pollution. They are released into the atmosphere mainly in the forms of fine ash, smoke and flue, and thus adversely affect plant, animal and human health. Selenium is one of toxic and the most volatile in coal. Large amount of atmospheric emission of selenium, as well as selenium present and scrubber stockpiles in ash may create serious environmental problems. In the paper, on the basis of investigating the abundance and distribution of selenium in plant-rings during recent 20 years, the bioaccumulation of selenium is explained that selenium in plant, which were collected from the village of selenium-rich coal combustion, is much higher than that in plants collected away from the village of selenium-rich coal combustion. The main origins of selenium are selenium-rich coal combustion and high-selenium rock weathered. The selenium recycle by food chain and selenium will accumulate and redistribute in environments.     

Study of Trace Elements and Soot in Aerosols from a Coal-Fired Power Plant in Northern Vietnam

Two measurement campaigns were conducted in two sampling sites, An Thinh and Duy Minh, in northern Vietnam during the months of November–December 2000 and November 2001–February 2002 in order to investigate the extend of the particulate air pollution from the Pha Lai coal fired power plant. Fine particle samples were analyzed by Energy Dispersive X-Ray Fluorescence spectrometry and soot samples were analyzed by reflectometer. The result showed that high concentration of soot and elements mostly coincided with the air masses originating from the power plant. Sea spray aerosol was found to be the major source of chlorine at both sites. Ratios of specific elements and principal component analysis (PCA) revealed that coal combustion was the main contributor to the air pollution at both sites. PCA also indicated that there were other sources responsible for the elements emission, probably the influence of long distance transport and Asian Brown Cloud.     

Application of a “closed-can” technique for measuring radon exhalation from mine samples of Punjab, Pakistan

Using the closed-can technique, radon exhalation rate measurements have been carried out for shale and coal samples collected from various mines located in the Chakwal and Makarwal areas of Pakistan. For the two areas, the measured average values of the exhalation rates from shale are 1.45±0.13 and 0.67±0.25 Bq m⁻² h⁻¹ and for coal are 1.0±0.03 and 0.65±0.32 Bq m⁻² h⁻¹, respectively. These values are much lower than the measured exhalation rates from alum-shale-based Nordic concrete which has values in the 50–200 Bq m⁻² h⁻¹ range. The lower values of the measured exhalation rates from the shale and coal deposits in the Chakwal and Makarwal areas are indicative of their lower uranium contents and mine workers in these areas do not face any abnormal health hazard due to radon since the exhalation rates have been found to be on the low side.     

Sorption of polycyclic aromatic hydrocarbons (PAHs) to carbonaceous materials in a river floodplain soil

We report on sorption isotherm of phenanthrene (Phe) for river floodplain soil associated with carbonaceous materials, with particular attention being devoted to the natural loading of Phe. Our sorption experiments with original soil samples, size, and density sub-fractions showed that the light fraction had the highest sorption capacity comparable to low rank coals. In addition, the light fraction contributed most for the sorption of Phe in total soil samples. K_oc values for all fractions were in the same range, thus indicating that coal and coal-derived particles in all samples are responsible for the enhanced sorption for Phe. Sorption was strongly nonlinear and the combined partitioning and pore-filling model gave a better fit than the Freundlich sorption model. In addition, the spiked PAHs did not show the same behavior as the naturally aged ones, therefore the accessibility of indigenous background organic contaminants was reduced when coal and coal-derived particles are associated with the soils.     

南京市典型森林群落枯枝落叶层的生态功能研究

对南京市5种典型森林群落枯枝落叶层现存量、营养元素氮磷贮存量、持水量以及吸纳重金属等生态功能的研究结果表明,5种典型森林群落枯枝落叶层现存量、对氮的贮存能力以及最大拦蓄量均以麻栎-栓皮栎群落最大;对磷和5种重金属的贮存量以银杏群落最大,麻栎-栓皮栎群落次之;枫香-桂花和三角枫群落的各项生态功能相对较弱。建议在南京市的城市森林规划和建设中,应保护好现存的地带性植物群落———以麻栎-栓皮栎为优势种的落叶阔叶林群落或营建类地带性植物群落,维护林地枯枝落叶层的完整性,将有助于改善城市生态环境。     

模拟煤灰渣垂直潜流人工湿地的除磷性能分析

为确定煤灰渣作为垂直潜流人工湿地基质的可行性,通过静态吸附实验和煤灰渣去除生活污水中的磷素实验,表明煤灰渣对污水中磷素的吸附平衡时间较短,吸附速率较快.当温度降低时,煤灰渣的磷素吸附容量对吸附平衡浓度依赖性和吸附强度随之降低,最大理论吸附容量亦降低 83.10% .在处理0.5 m 3 /(m2·d)的生活污水中,煤灰渣对TP的平均去除率达86.03%,吸附方式包括物理吸附和化学吸附,同时得出煤灰渣最大磷素解析量占最大理论吸附容量的0.73%,在实际人工湿地应用中应注意磷素解析而形成的二次污染.     

中国煤矿灾害现状与减灾对策分析

以大量的数据资料，全面系统地分析了煤矿灾害的现状与致灾特点，提出了煤矿防灾减灾对策。     

Structural equation model of the influence of noise annoyance on miners’ unsafe behavior in coal mines

Miners' unsafe behavior (UB) is the main cause of coal mine accidents. Previous research has suggested that excessive noise in tunnels impacts miners' temperaments and safe production behavior. To explore the influence of noise on UB, four different dimensions of noise annoyance were identified: cognitive, emotional, communication, and physical mechanism annoyance. The coal mine noise annoyance scale, miners' unsafe behavior intention (UBI) scale, and miners’ UB scale were developed according to different dimensions. In the first survey, a total of 200 questionnaires were distributed in the two coal mines, and 193 valid questionnaires were recovered. Exploratory factor analysis was conducted, and invalid items were removed according to the analysis results to form the final scale. Then, 500 final scales were distributed in two Chinese coal mines, and 482 valid questionnaires were collected. Confirmatory factor analysis was conducted by collating the data of the second questionnaire. Based upon the structural equation model (SEM), the SEM of the influence of noise annoyance degree on UB and the path analysis with latent variable path analysis with the latent variables (PA-LVs) mediating model of the effect of UBI on UB were established, and the path coefficients with fitting data of the model were analyzed. The results indicated that the four dimensions of coal mine noise annoyance had a strong positive impact on UB, which was reduced by less noise annoyance. In addition, the Bootstrap method was used to verify the mediating method among the four dimensions of noise annoyance, cognitive annoyance, emotional annoyance, with communication annoyance indirectly affecting UB through UBI. The research results provide theoretical support for reducing the UB of miners and improving coal mine safety levels.     

利用煤矸石制备低环境负荷型水泥的研究

煤矸石是我国排放量最大的工业废渣之一,破坏生态环境,不利于可持续发展。本文分析与研究了煤矸石的综合利用现状,着重探讨了煤矸石在我国水泥工业中的应用,并从材料学、热学和环境学等交叉学科入手研究了利用煤矸石生产低环境负荷型水泥的控制理论与技术及其社会经济效益。