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101.
The role of iron in surface-mediated formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from 2-chlorophenol (2-MCP) was investigated over the temperature range of 200-550 °C under oxidative conditions. In order to compare and contrast with previous work on copper and ferric oxide-mediated pyrolysis of 2-MCP, identical reaction conditions were maintained (50 ppm 2-MCP, model fly-ash particles containing 5% Fe2O3 on silica). Observed products included dibenzo-p-dioxin (DD), 1-monochlorodibenzo-p-dioxin (1-MCDD), dibenzofuran (DF), 4,6-dichlorodibenzofuran (4,6-DCDF), 2,4- and 2,6-dichlorophenol, 2,4,6-trichlorophenol, quinone, catechol, chloro-o-quinone, chlorocatechol and polychlorinated benzenes. Yields of DD and 1-MCDD were 2 and 5 times higher than under pyolysis conditions, respectively. Although 4,6-DCDF was the major PCDD/F product formed with a yield that was 2.5× greater than under pyrolysis, the yield of non-chlorinated DF, which was the dominant PCDD/F product under pyrolysis, decreased by a factor of 3. Furthermore, the ∼2× higher yield of PCDDs under oxidative conditions resulted in a PCDD to PCDF ratio of 0.75 compared to a relatively low ratio of 0.39 previously observed under pyrolytic conditions.  相似文献   
102.
Ragazzi M  Rada EC 《Chemosphere》2012,89(6):694-701
In the sector of municipal solid waste management the debate on the performances of conventional and novel thermo-chemical technologies is still relevant. When a plant must be constructed, decision makers often select a technology prior to analyzing the local environmental impact of the available options, as this type of study is generally developed when the design of the plant has been carried out. Additionally, in the literature there is a lack of comparative analyses of the contributions to local air pollution from different technologies. The present study offers a multi-step approach, based on pollutant emission factors and atmospheric dilution coefficients, for a local comparative analysis. With this approach it is possible to check if some assumptions related to the advantages of the novel thermochemical technologies, in terms of local direct impact on air quality, can be applied to municipal solid waste treatment. The selected processes concern combustion, gasification and pyrolysis, alone or in combination. The pollutants considered are both carcinogenic and non-carcinogenic. A case study is presented concerning the location of a plant in an alpine region and its contribution to the local air pollution. Results show that differences among technologies are less than expected. Performances of each technology are discussed in details.  相似文献   
103.
针对某水厂以超滤为核心的短流程水处理工艺,在通过聚氯乙烯(PVC)超滤膜之前选择不同投加量(5、10、15和20 mg/L)的高效聚合氯化铝(HPAC)对长江下游原水进行混凝处理。通过跨膜压差(TMP)增长趋势、CODMn的去除率以及混凝后的水质,可知HPAC的最优投加量为15 mg/L。在此投加量下,运用体积排阻色谱法分析原水、膜前水、膜后水中各相对分子质量有机物的变化,可以发现混凝去除有机物的效果要优于超滤截留的。继而将HPAC与另外4种常用混凝剂:硫酸铝(分析纯)、氯化铁(化学纯)、聚合氯化铝(PAC)、聚合硫酸铁进行对比,结果表明,在它们各自最优投加量下,HPAC能够更有效地减缓超滤膜TMP的增长率,从而降低膜污染。因此,认为HPAC是与PVC超滤合金膜契合效果最佳的混凝剂。  相似文献   
104.
Imidacloprid (IMI) is a relatively new neuro-active neonicotinoid insecticide and nowadays one of the largest selling insecticides worldwide. In the present study a LC–APCI–MS based method was developed and validated for the quantification of imidacloprid and its main metabolite 6-chloronicotinic acid (6-CINA) in urine and hair specimens. The method was tested in biomonitoring of intentionally exposed animals and subsequently applied for biomonitoring of Cretan urban and rural population.  相似文献   
105.
确定压力容器安全系数原则   总被引:2,自引:0,他引:2  
压力容器安全系数与材料参数紧密相关,确定材料许用应力值时,需要同时考虑材料抗拉强度和屈服强度更为合理;奥氏体不锈钢材料具有非常好的应变强化能力和韧性,为充分发挥奥氏体不锈钢材料优良性能,选取奥氏体不锈钢材料许用应力值时,需要特殊考虑。压力容器安全系数的选取建立在经验基础上,在保障压力容器安全性前提条件下,为节省材料和降低成本,随着理论研究深入和科学实验的进步,压力容器安全系数有所降低,这是科学设计和实用成功经验结合的结果。  相似文献   
106.
煤与瓦斯突出的物理模拟和数值模拟研究   总被引:1,自引:0,他引:1  
利用自行设计的实验装置,通过现场采集具有突出倾向的煤样,分别向实验装置煤样中充入吸附能力较大的CO2和吸附能力较小的N2来模拟不同级别的煤与瓦斯突出现象,物理试验结果表明:瓦斯压力越大,突出强度越大;当瓦斯压力相近时,吸附和解吸能力大的瓦斯突出强度大。通过数值模拟对煤与瓦斯突出进行研究,数值模拟再现了煤矿开采过程中诱发的煤与瓦斯突出全过程,同时验证了煤与瓦斯突出是瓦斯压力、地应力及煤岩体的力学性质综合作用的结果,该验证对进一步深入理解认识煤与瓦斯突出的机理具有重要的理论和实践意义。  相似文献   
107.
Malaysia is in dire need of alternatives to landfilling for solid waste management. Recently, landfills have faced the problems of overfilling, overflowing of leachates leading to pollution of water resources, and uncontrolled dust emissions adversely affecting the local environment. With the rising cost of urbanization coupled with the high rate of waste generation, one possible method of waste treatment that is receiving particular attention by the government is incineration. Incineration of solid waste is rather new in Malaysia, with limited usage in handling small sources of waste generation such as the municipal solid waste (MSW) of resort islands; however, its potential in ameliorating the problems associated with solid waste treatment may make it an attractive alternative to landfill. This article presents the results of test runs conducted to investigate the performance of a locally designed and manufactured rotary kiln incinerator (RKI). The test runs were conducted using MSW collected from the Shah Alam municipality. The combustion efficiency was analyzed by looking at the temperature profiles and chemical species concentrations. To complement the combustion characteristics measurements, predictions of the air flow in the incinerator during the process were also investigated. The overall performance of the RKI suggests that it is suitable for treating MSW.  相似文献   
108.
单甲脒饱和蒸气压的测定和估算   总被引:1,自引:0,他引:1  
用气体的法测单甲脒在15,25,35和45℃时的饱和蒸气分别为0.202,0.5546,1.95,6.29Pa;亨利常数计算值分别为6.30×10^-4,1.67×10^-3,5.68×10^0-3和1.78×10&-2,根据Clausius Clapeyron方程求出单甲脒在常温下气化热为89.2kJ.mol^-1。  相似文献   
109.
近年来,太湖蓝藻水华问题日趋严峻,除藻技术是解决该问题最直接而有效的手段,对现有各类除藻技术进行了比较,并以"加压上浮法"应急除藻技术在苏州阳澄湖局部地区的示范工程为例,介绍了该方法的技术原理、技术实现以及在工程应用中的实际意义,为同行在水源地或特殊功能区除藻技术的应用提供参考。  相似文献   
110.
控制排气放空噪声的消声器之研究与应用   总被引:1,自引:0,他引:1  
排气放空噪声是工业上常遇到的噪声源。本文介绍了根据喷注噪声发射理论研制成的小孔喷注与节流降压相复合的新型消声器,适用于高压气源排放,取得了较好的消声效果。鉴于喷注发射噪声的强度取决于喷注的驻压与喷口直径等参量,对节流降压层的设计与控制小孔喷注层的驻压大小,提出了新的见解,可供设计研究喷注消声器参考使用。  相似文献   
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