改进突变理论在井下排水方案优选中的应用

为了更精确合理地对新桥硫铁矿排水方案进行优选,对利用突变理论的方法进行优化,建立突变理论和熵权法相结合的改进模型。从经济和工程量方面出发,综合考虑了影响排水方案优选的3个层次的12个指标,统计样本数据。运用熵权法分层确定同一上层变量下各指标的客观权重,导入突变理论中,建立综合评价结构模型,消除了主观因素的影响。同时运用突变理论和EM-TOPSIS进行方案优选,通过对比3种方法的优选结果,证明了改进突变理论的可靠性与合理性。     

海上应急保障资源调度的多目标模糊规划模型

针对现有应急资源调度模型无法完全适应海上应急保障环境的问题,建立了基于多目标模糊规划的海上应急资源调度模型.首先,将不确定的航行时间和资源需求量表示为三角模糊数,用时间隶属度函数的全积分对模糊应急开始时间进行确定化表示,用需求量隶属度表示需求点所接收的资源数量满足需求的程度.然后,考虑各需求点和各类资源的重要程度,以系统的时效性、需求满意度、安全性和经济性为优化目标建立多目标规划模型,最后,给出了模型的求解方法,并通过算例分析证明了方法的有效性.     

浅谈企业安全管理

事故的发生离不开人、机、环境这三个方面,然而传统的安全管理方式侧重于物的研究而对人的不安全行为重视程度不够。搞好安全管理,人的因素很重要,人是生产活动的主体,通过事故致因理论,有针对性地提出针对人的行为的安全管理措施,通过激励措施,充分调动企业员工的积极性,利用激励的作用,以提高企业的安全管理水平。     

基于博弈赋权物元和证据理论的无线闭塞中心风险评估*

为客观地对无线闭塞中心进行风险评估,建立基于博弈赋权物元和证据理论的评估模型,根据故障树分析法识别的风险因子构建评估指标体系,采用博弈论思想对直觉模糊层次分析法计算的主观权重和熵权法计算的客观权重进行最优组合,进而确定综合权重。运用物元理论和证据理论确定各指标的风险等级和系统整体风险等级,并通过实例分析对评估模型进行对比验证。结果表明:无线闭塞中心整体风险等级为“可容许的”,与实际情况相符。其中,系统外部通信故障的风险等级为“不期望的”,需要对其相关设备加强风险控制。     

城市环境空间规划管控体系的构建——以广州市为例

通过叙述国内环境空间规划体系发展历程,总结国内在开展城市环境空间管控方面的主要做法和经验,以广州市为研究案例提出在城市尺度建立环境空间规划管控体系的总体架构和技术思路,为城市环境规划和空间规划管理提供参考。     

镉污染对生物有机体的危害及防治对策

镉污染是当今重金属污染中面积最广、危害最大的重金属元素之一，被称为“五毒之首”．由于镉污染毒理机制和生物效应的复杂性，对镉污染的研究一直是当前学术界的热点研究课题。本文对镉的环境行为和对生物有机体毒理机制与危害进行综合研究。并介绍目前镉污染修复的先进技术，并对具有应用前景的镉污染修复技术进行了探讨。     

Effect of substituents in hydroxyl radical-mediated degradation of azo pyridone dyes: Theoretical approaches on the reaction mechanism

Understanding the degradation behavior of azo dyes in photocatalytic wastewater treatment is of fundamental and practical importance for their application in textile-processing and other coloration industries. In this study, quantum chemistry, as density functional theory, was used to elucidate different degradation pathways of azo pyridone dyes in a hydroxyl radical (HO^?)-initiated photocatalytic system. A series of substituted azo pyridone dyes were synthesized by changing the substituent group in the para position of the benzene moiety, ranging from strong electron-donating to strong electron-withdrawing groups. The effect of dye molecular structure on the photocatalytic degradation reaction mechanism was analyzed and quantification of substituent effects on the thermodynamic and kinetics parameters was performed. Potential energy surface analysis revealed the most susceptible reaction site for the HO^? attack. The calculated reaction barriers are found to be strongly affected by the nature of substituent group with a good correlation using Hammett σ_p constants and experimentally determined reaction rates. The stability of pre-reaction complexes and transition state complexes were analyzed applying the distortion-interaction model. The increased stability of the transition state complexes with the distancing from the substituent group has been established.     

The thermal transformation mechanism of chlorinated paraffins: An experimental and density functional theory study

The increasing production and usage of chlorinated paraffins(CPs) correspondently increase the amount of CPs that experience thermal processes. Our previous study revealed that a significant amount of medium-chain chlorinated paraffins(MCCPs), short-chain chlorinated paraffins(SCCPs) as well as aromatic and chlorinated polycyclic aromatic hydrocarbons(Cl-PAHs) were formed synergistically during the thermal decomposition of CP-52(a class of CP products).However, the transformation mechanisms of CP-52 to these compounds are still not very clear.This article presents a mechanistic analysis on the decomposition of CP-52 experimentally and theoretically. It was found that CP-52 initially undergoes dehydrochlorination and carbon chain cleavage and it transformed into chlorinated and unsaturated hydrocarbons. Cyclization and aromatization were the most accessible pathways at low temperatures(200–400°C), both of which produce mostly aromatic hydrocarbons. As the temperature exceeds 400°C, the hydrocarbons could decompose into small molecules, and the subsequent radical-induced reactions become the predominant pathways, leading to the formation of Cl-PAHs. The decomposition of CP-52 was investigated by using density functional theory and calculations demonstrating the feasibility and rationality of PCB and PCN formation from chlorobenzene. The results improve the understanding of the transformation processes from CP-52 to SCCPs and Cl-PAHs as well as provide data for reducing their emissions during thermal-related processes.     

火电厂煤尘污染防治主要措施研究

文章通过对火电项目煤尘产生源的分析,根据北方地区社会、经济、环境现状,提出电厂储煤场及输煤系统煤尘的主要防治措施,从而为北方经济欠发达地区火电厂的煤尘污染防治提供一些参考依据,促进环境质量的改善。     

区域大气污染联防联控的理论与方法分析

区域性、复合型大气污染是中国目前以及今后一段时期内所面临的主要大气污染问题,但我国现行"属地"特征的环境管理制度无法满足区域性、复合型大气污染所需要的合作解决问题的要求,因此亟需建立区域大气污染联防联控机制。本文探讨了区域大气污染联防联控的理论基础,并着重讨论了我国实施区域联防联控的技术与方法,包括联防联控区域划分方法、区域大气环境问题控制技术、区域总量控制目标确定与分配方法及区域大气污染联防联控保障体系等。