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491.
Homogeneous formation of polychlorinated dibenzothiophenes/thianthrenes(PCDT/TAs),sulfurated compounds analogous to polychlorinated dibenzo-p-dioxin/dibenzofurans(PCDD/Fs), has been well-documented to occur via radical–radical coupling reactions from chlorinated thiophenol precursors. However, the current understanding of the formation mechanism of PCDT/TAs is exclusively limited to the inherent point of view that chlorothiophenoxy radicals act as the only required intermediates for PCDT/TAs. This study investigates reaction pathways for the formation of PCDT/TAs involving two new types of radical species, i.e., substituted phenyl radicals and substituted thiophenoxyl diradicals. Taking 2-chlorothiophenol(2-CTP) as a model compound for chlorothiophenols,we found that apart from the mostly discussed chlorothiophenoxy radicals, substituted phenyl radicals and substituted thiophenoxyl diradicals could also be readily formed via the reaction of 2-CTP with H radicals. Furthermore, direct self-and cross-coupling of these radicals can result in the formation of PCDT/TAs, including 1-monochlorothianthrene(1-MCTA), 1,6-dichlorothianthrene(1,6-DCTA), 4,6-dichlorodibenzothiophene(4,6-DCDT)and 1,6-dichlorodibenzothiophene(1,6-DCDT). The pathways proposed in this work are proven to be both thermodynamically and kinetically favorable. Particularly, comparisons were made between the formation mechanisms of sulfurated and oxygenated dioxin systems from an energetic point view, showing that replacing oxygen with sulfur atoms greatly reduces the activation barriers of the rate-controlling steps involved in the PCDT/TA formation processes compared with those involved for PCDD/Fs. The calculated results in this work may improve our understanding of the formation mechanism of PCDT/TAs from chlorothiophenol precursors and should be informative to environmental scientists. 相似文献
492.
基于Agent的仿真建模方法(Agent based modeling and simulation,ABMS)和资源保存理论(conservation of resource theory,COR),构建了多Agent仿真模型,通过确定监管Agent、决策支持Agent、职能配合Agent和矿工Agent及其属性,借助Netlogo仿真平台模拟决策支持力度、职能配合程度以及矿工行为选择对监管Agent工作倦怠的影响,可以输出情感耗竭、人格解体和个人成就3个维度下监管Agent的数量。研究表明:决策支持系数Sc对监管Agent工作倦怠现象影响最大、处理有效性系数Ec影响次之、职能配合系数Fc影响最小,多Agent仿真模型促进了矿山监管Agnet工作倦怠现象的量化分析研究,为矿山安全治理提供了有效的决策依据。 相似文献
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针对安全概念不统一,安全科学与技术发展相对滞后,重特大安全事故频发等问题,通过借鉴量子纠缠理论,提出了安全与危险纠缠理论学说。建立了安全与危险纠缠理论模型,阐述了其纠缠机制,明确了一个系统中的安全与危险在不同时段内存在的方式和状态:通常人们所认知的安全或危险均是系统在过去时段内以“一显一隐”的方式塌缩成确定的状态,而在现在与未来时段,它们分别是以“显性”、“隐性”的方式纠缠为不确定的状态;若该系统的“安全与危险纠缠”状态向安全方向塌缩时,系统则表现为安全,若向危险转化时,则系统表现为事故。同时,分析了“安全与危险纠缠”理论建立的对安全科学及安全生产实际意义与理论价值,及其未来展望和存在问题。 相似文献
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Navigating uneven terrain: The roles of political skill and LMX differentiation in prediction of work relationship quality and work outcomes
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Olga Epitropaki Ilias Kapoutsis B. Parker Ellen Gerald R. Ferris Konstantinos Drivas Anastasia Ntotsi 《组织行为杂志》2016,37(7):1078-1103
Drawing from social/political influence, leader–member exchange (LMX), and social comparison theories, the present two‐study investigation examines three levels of LMX differentiation (i.e., individual‐level, meso‐level, and group‐level LMX differentiation) and further tests a model of the joint effects of political skill and LMX differentiation on LMX, relative LMX, and employee work outcomes. In Study 1, we used data from 231 employees and found support for the interactive effect of political skill and individual perceptions of LMX differentiation on LMX quality. We also found partial support for the moderating role of individual‐level LMX differentiation on the indirect effects of political skill on self‐rated task performance and job satisfaction via LMX. In Study 2, we used data from 185 supervisor–subordinate dyads and examined both meso‐level and group‐level LMX differentiation via a multilevel moderated mediation model. Results supported the moderating role of group‐level LMX differentiation and group mean LMX on the indirect effects of political skill on supervisor‐rated task performance and contextual performance/citizenship behavior as well as job satisfaction via relative LMX. Overall, the results suggest that politically skilled employees reap the benefits of LMX differentiation, as they enjoy higher absolute LMX and relative (i.e., to their peers) LMX quality. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
496.
John E. Mathieu 《组织行为杂志》2016,37(8):1132-1141
Theory is essential to everything that we do as people studying and practicing industrial/organizational psychology and organizational behavior. But, I think that our field has lost its way recently and become enamored by shiny objects and interesting puzzles. Advancing management theory seems to have become an end state in and of itself. We seemed to be far more concerned with the entertainment value of theories than we are with their scientific rigor or real‐world value. Top journals in our field are mandating that all articles must make a theoretical contribution, and theoretical contributions are being gauged primarily in terms of how innovative, counter‐intuitive, surprising, and interesting they may be. I advocate for a more balanced approach, and in particular, for greater use of abductive inference. I argue that if you start with a real‐world challenge and draw from existing theory, and then develop new theory to understand and change things, you are also making a theoretical contribution. Whether or not we are guided by theory is not really at issue—at issue is how well developed are our theories, how accurate are they, and do they help us to improve organizational life for everyone involved? 相似文献
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498.
《土壤污染防治行动计划》是国家系统开展土壤污染预防、保护、管控和治理的重大战略部署。文章从污染物来源和土壤污染判断依据两方面探讨了"土壤污染"的概念;提出了我国的"土壤环境污染控制指导值"包括3套指导值,分别为"土壤环境风险筛选值"、"土壤环境修复指导值"和"土壤环境修复启动值",并分析了3套指导值的目标定位、制订策略和执行策略。 相似文献
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土壤重金属污染评价对于环境保护策略的制定和民众健康的防护具有重要意义。应用熵权、毒性系数和模糊数学构建了熵权模糊法评价模型,并以陕西省彬长煤化工业区为例,对其土壤重金属富集特征和潜在生态风险进行了评估。结果表明,土壤Cd、Co和Pb质量比较高,空间差异明显,建矿时间较长的工业园区土壤重金属潜在生态风险水平较高。熵权评价显示Cd为主要污染因子(权重为0.566)。模糊综合评价显示,研究区55.7%的样点为轻度污染,24.3%的样点为中度污染,无重污染和严重污染隶属样点。研究区污染程度有由轻度污染向中度污染过度的趋势。与传统污染评价指数相比,熵权法和模糊数学模型的联合应用有助于提高风险评价的准确性。 相似文献