岩石中氟的赋存状态研究

使用逐级化学提取方法对岩石中氟的赋存状态进行了研究.结果表明:岩石中氟主要与K和Al呈显著相关,高氟岩石中氟与P呈显著正相关,氟主要以氟磷灰石的形式存在;经逐级提取后残渣中的氟与Ca呈显著负相关关系,碳酸盐岩和磷块岩中的氟主要以水溶态和碳酸盐结合态等易溶形式存在;而硅质岩、黑色页岩、硅质碳板岩和碳质板岩中的氟主要存在于难溶矿物中.     

我国西北部地区森林生物灾害发生趋势分析及可持续控灾策略

针对陕西、甘肃、内蒙古、青海、宁夏和新疆西北6省(区)目前的森林现状,分析了两北部地区森林生物灾害的发生特点:主要是(1)森林病虫鼠害严重,尤其是害鼠种类多、分布范围广,危害严重。(2)钻蛀性害虫发生隐蔽,控制困难。(3)干旱和生物多样性贫乏使食叶害虫的暴发周期缩短。预测未来10年森林生物灾害的发展趋势为:(1)总体发生趋势平稳;(2)病虫种类将明显增加;(3)森林鼠害面积明显增加,危害程度在一定时期内会更加严重;(4)杨树蛀干害虫的危害仍然严重。进而提出了可持续控灾的5点策略。     

无锡-常州地下水中内分泌干扰物的赋存特征和健康风险评价

采用固相萃取-超高效液相色谱串联质谱法(SPE-UPLC-MS/MS)分析了无锡-常州地区地下水中4 类(性激素、孕激素、糖皮质激素和酚类激素)22 种典型内分泌干扰物(EDCs)的赋存特征.结果表明,共有20 种EDCs 被检出,以双酚A(BPA)、雌酮(E1)、雌二醇(E2)和炔雌醇(EE2)为主,检出率均在90％...     

我国部分内陆水域有机锡污染现状初探

首次对我国部分内陆水域由于使用了基锡作为船舶防污产而带来的水污染现状进行了研究，运用气相色谱，表面发射火焰光度检测方法对所采样品进行了测定，在我国多处内陆水域域发现了丁基锡污染。     

ACIDIFICATION AND FISH OCCURRENCE IN THE UPPER CHEAT RWER DRAINAGE,WEST VIRGINIA1

ABSTRACT: The decline of many fish populations within the mid-Appalachian region has been attributed to stream acidification as a result of acid precipitation. Many previous attempts to examine relationships between fish occurrence and acidification have been hindered by a lack of data on water quality and fish distributions. To assess relationships between water quality and bedrock type in the upper Cheat River drainage, we used EPA STORET water quality data (1969–1993) and calculated mean pH and mean alkalinity of streams associated with four bedrock types (Hampshire, Chemung, Mauch Chunk, and Pottsville). We examined the relationship between fish occurrence and bedrock type for 53 headwater streams. We found that acidity in headwater streams associated with Pottsville and Mauch Chunk groups often exceeded biological thresholds for acid-sensitive fish species (pH < 5.5). Streams associated with the Pottsville group typically had fewer cyprinid species and fewer total species than those associated with Mauch Chunk, Chemung, and Hampshire bedrock types. The congruent occurrence of streams with low buffering capacity, streams with pH > 5.5, and streams with low fish species richness indicate that acidification has influenced fish distributions in the upper Cheat River drainage.     

Mapping lightning/human-caused wildfires occurrence under ignition point location uncertainty

Fire managers need to study fire history in terms of occurrence in order to understand and model the spatial distribution of the causes of ignition. Fire atlases are useful open sources of information, recording each single fire event by means of its geographical position. In such cases the fire event is considered as point-based, rather than area-based data, completely losing its surface nature. Thus, an accurate method is needed to estimate continuous density surfaces from ignition points where location is affected by a certain degree of uncertainty. Recently, the fire scientific community has focused its attention on the kernel density interpolation technique in order to convert point-based data into continuous surface or surface-data. The kernel density technique needs a priori setting of smoothing parameters, such as the bandwidth size. Up to now, the bandwidth size was often based on subjective choices still needing expert knowledge, eventually supported by empirical decisions, thus leading to serious uncertainties. Nonetheless, a geostatistical model able to describe the point concentration and consequently the clustering degree is required. This paper tries to solve such issues by implementing the kernel density adaptive mode. Lightning/human-caused fires occurrence was investigated in the region of Aragón's autonomy over 19 years (1983–2001) using 3428 and 4195 ignition points respectively for the two causes of fire origin. An analytical calibration procedure was implemented to select the most reliable density surfaces to reduce under/over-density estimation, overcoming the current drawbacks to define it by visual inspection or personal interpretation. Besides, ignition point location uncertainty was investigated to check the sensitivity of the proposed model. The different concentration degree and the dissimilar spatial pattern of the two datasets, allow testing the proposed calibration methodology under several conditions. After having discovered the slight sensitivity of the model to the exact point position, the obtained density surfaces for the two causes were combined to discover hotspot areas and spatial patterns of the two causes. Evident differences in spatial location of the origin causes were noted and described. The general trend follows the geographical features and the human activity of the study areas. The proposed technique should be promising to support decision-making in wildfire prevention actions, because of the occurrence map can be used as a response variable in fire risk predicting models.     

THE RELATIONSHIP OF WATER QUALITY AND FISH OCCURRENCE TO SOILS AND GEOLOGY IN AN AREA OF HIGH HYDROGEN AND SULFATE ION DEPOSITION1

ABSTRACT: A survey of 61 headwater streams and their watersheds on Pennsylvania's Laurel Hill, an area of high hydrogen ion and sulfate deposition, was conducted in May and June 1983. Trout were absent from 12 or 20 percent of the streams. No fish were present in 10 streams. Thirty-three streams appeared to contain viable trout populations, 10 streams had other interferring cultural impacts and 6 streams had nonviable trout populations. Significant differences in water quality were noted among streams with and without fish. The streams having no fish as a group had significantly lower pH and alkalinity and higher dissolved aluminum than those with fish. Attempts were made to correlate soil type and geology with the presence or absence of trout. Watersheds with a major percentage of very stony land soil classifications always contained no trout or were culturally impacted. On the other hand, watersheds with a major percentage of Upshur (limestone derived) soils always supported trout. Watersheds with more than 30 percent Pocono Group bedrock supported trout in every case but two, while in every case but one, watersheds with more than 30 percent Pottsville Group bedrock did not support trout. Acid runoff episode data indicate severe transient acidification attributable to atmospheric deposition. It appears that a combination of very stony land, 30 percent Pottsville Group bedrock and high deposition of hydrogen ions and sulfate may result in transient acidification and absence of fish populations from headwater streams on Pennsylvania's Laurel Hill.     

Why is the rate of annual road fatalities increasing? A unit record analysis of New Zealand data (2010–2017)

IntroductionRecent increases in road crashes have reversed New Zealand’s formerly declining crash rates to produce annual fatal and serious injury counts that are 49% higher than the lowest rates achieved in 2013. Method: We model twenty-one factors in fatal and serious injury crashes, four years before and after 2013 using logistic regression. Three major factors are significantly different in the period after 2013, when crash rates increased: (1) alcohol as a cause, (2) learner licence holders, and (3) a regional effect for Auckland. Newly defined speed zones are a more common setting for crashes in the period of upturn but there is no coinciding elevated likelihood of ‘speed as a causal factor’. Three factors related to road safety were less common: aged under 25-years old, fatigue, and not wearing a seatbelt. Results: Results are compared to rates of prosecutions for alcohol-related driving offences over this period. It is possible that New Zealand’s successful road safety initiatives of the past have been undermined by reduced levels of enforcement and an unexpected outcome from the graduated driving licence system.     

In-depth approach for identifying crash causation patterns and its implications for pedestrian crash prevention

IntroductionA pedestrian crash occurs due to a series of contributing factors taking effect in an antecedent-consequent order. One specific type of antecedent-consequent order is called a crash causation pattern. Understanding crash causation patterns is important for clarifying the complicated growth of a pedestrian crash, which ultimately helps recommend corresponding countermeasures. However, previous studies lack an in-depth investigation of pedestrian crash cases, and are insufficient to propose a representative picture of causation patterns. Method: In this study, pedestrian crash causation patterns were discerned by using the Driving Reliability and Error Analysis Method (DREAM). One hundred and forty-two pedestrian crashes were investigated, and five pedestrian pre-crash scenarios were extracted. Then, the crash causation patterns in each pre-crash scenario were analyzed; and finally, six distinct patterns were identified. Accordingly, 17 typical situations corresponding to these causation patterns were specified as well. Results: Among these patterns, the pattern related to distracted driving and the pattern related to an unexpected change of pedestrian trajectory contributed to a large portion of the total crashes (i.e., 27% and 24%, respectively). Other patterns also played an important role in inducing a pedestrian crash; these patterns include the pattern related to an obstructed line of sight caused by outside objects (9%), the pattern that involves reduced visibility (13%), and the pattern related to an improper estimation of the gap distance between the vehicle and the pedestrian (10%). The results further demonstrated the inter-heterogeneity of a crash causation pattern, as well as the intra-heterogeneity of pattern features between different pedestrian pre-crash scenarios. Conclusions and practical applications: Essentially, a crash causation pattern might involve different contributing factors by nature or dependent on specific scenarios. Finally, this study proposed suggestions for roadway facility design, roadway safety education and pedestrian crash prevention system development.     

Effects of speed humps on vehicle speed and pedestrian crashes in South Korea

Introduction: Speeding is a crucial risk factor for pedestrian safety because it shortens reaction time while increasing the impact force in collisions. Various types of traffic calming measures to prevent speeding have been devised. A speed hump—a raised bump installed in the pavement—has been widely used for this purpose. Method: To evaluate the effectiveness of speed humps, the speed profiles of vehicles passing speed humps were analyzed along with pedestrian crash records near speed humps. Results: The speed profiles showed that vehicles gradually diminished their speeds starting 30 m ahead of speed humps and, immediately after passing the humps, accelerated to regain their original speeds within a distance of 30 m. This speed reduction effect is substantial on both local and major roads: 18.4% and 24.0% reduction in speeds, respectively. The analysis of pedestrian crash records revealed that, inside the zones of speed reduction effect near speed humps (i.e., ±30 m from speed humps), fewer pedestrian crashes per roadway distance occurred and pedestrian injuries were less severe, compared with events outside the effect zones. This safety improvement was greater on major roads than local roads. Practical Applications: This work finds that the speed reductions that occurred near speed humps were gradual and influential ±30 m from their locations, suggesting that the hump installations should be close enough to the pedestrian crossings. It is noteworthy that, albeit that speed humps are more prevalent on local roads, the benefits of speed reduction effects from speed humps were more pronounced on major roads than on local roads. Therefore, speed humps on major roads can be considered a more effective measure for pedestrian safety.