圆形巷道围岩弹性应力场的复变函数解析

为得出圆形巷道围岩弹性应力分布特征,采用复变函数对圆形巷道围岩弹性应力进行解析,得到了与应力函数解法相同的应力场解析表达式,证明了复变函数解法求解巷道围岩应力场的可行性.对圆形巷道边界应力分布规律及沿水平线的应力分布规律进行了分析,结果表明:1)圆形巷道边界的径向应力和剪应力等于0,环向应力集中系数随侧压系数和位置角度变化而变化,与巷道半径无关;2)沿水平线的圆形巷道围岩剪应力等于0,径向应力和环向应力集中系数随侧压力系数和巷道半径变化而变化;3)沿水平线方向,侧压系数对巷道围岩径向应力的影响大于环向应力影响.还分析了侧压系数对巷道围岩应力的影响规律,讨论了侧压系数等于0、大于0小于1、等于1和大于1等4种情况下的巷道边界环向应力分布情况,得出了巷道边界环向应力的拉压区域及环向应力集中系数最大位置.     

压力对填埋垃圾产甲烷的影响研究

压实作用被认为是影响填埋垃圾降解过程的一个重要因素,实验通过自制的压缩降解模拟填埋反应器装置,研究了阶梯增加式压力21k Pa→42 k Pa→84 k Pa(分别在垃圾填埋后的第75、103和131 d时施加)对填埋垃圾产甲烷这一资源化重要阶段的影响,包括产气特性、渗滤液性质及固体沉降等的变化.21 k Pa和42 k Pa分别恒定了4周,垃圾最后在84 k Pa恒定压力下降解,实验总共持续了170 d.结果表明,在初始21k Pa的压力作用下,由于接种物跟垃圾接触面积的增大,甲烷日产量从第75 d的1.85 L·d-1增加到了第76 d的2.95 L·d-1,产甲烷速率提高了59.82%,42 k Pa和84 k Pa时均有所增加,但增加程度均不明显.压力还使砾石层上部积留了一定水位高度的渗滤液,渗滤液的COD和含氮量在压力作用下都有了暂时的升高.压实作用还令垃圾体产生了较大的沉降,但压力进一步增大并没有使垃圾继续发生较多的沉降.实验结果有助于更好地了解压力对填埋垃圾降解过程的影响.     

扰动和加藻共同作用下太湖沉积物中形态磷变化规律

为了阐明反复扰动下,不同初始浓度藻对沉积物中各形态磷释放的影响.以太湖梅梁湾沉积物和上覆水作为研究材料,探讨了扰动和藻类共同作用下沉积物中各形态磷的变化规律.结果表明,无扰动状态下,NH4Cl-P和Res-P均有所降低,而Fe/Al-P和Ca-P则有所增加.其中,Ca-P随藻类初始浓度增加而增加,分别增加48%、66%、74%.但是,扰动状态下,NH4Cl-P和Res-P也明显降低.Fe/Al-P明显增加,其占总磷的百分比为66.2%(3组试验的平均值)高于不扰动状态(53.4%,3组试验的平均值);此外,Ca-P占总磷的百分比为24.1%(3组扰动试验的平均值)明显低于不扰动状态(33.0%,3组试验的平均值).这暗示了扰动和藻类共同作用下促进了Fe/Al-P的形成,而无扰动下藻类却促进了Ca-P的形成.     

Study of gas-water properties under high temperature and pressure for water-soluble gas reservoirs

The physical properties of gas and water are important in usage of gas reservoirs with water and water-soluble gas reservoirs. According to the Petroleum and Natural Gas Industry Standards SY/T5542-2009 of the People's Republic of China, by applying the crude oil multistage degassing method from the “Test Method for Reservoir fluid Physical Properties” and the formation water high-pressure property testing method described in the “Theory and Application of Reservoir Fluid Phase”, this investigation employed a Ruska 2370–601A phase analyzer to obtain data regarding gas–water ratios, water volume factors, compressibility coefficients, and densities. The results showed curve trends with changes in the temperature and pressure. The gas–water ratio was compared to the gas content of subsurface samples from the X water-soluble gas reservoir, suggesting that these findings might help in the analysis of water-soluble gas reservoirs.     

一种无奇异参数椭圆柱形电磁隐身斗篷的设计基础理论

目的研究无奇异参数的椭圆柱形超材料电磁隐身斗篷的设计方法。方法应用变换光学原理建立空间变换坐标表达式,推导出该斗篷的电磁参数张量,再采用Matlab软件验证所推导张量的无奇异性,最后采用有限元仿真软件验证该斗篷的电磁隐身性能。结果椭圆柱形斗篷具备良好的电磁隐身性能,并且其电磁参数张量的各个分量均无奇异性。结论设计出的空间坐标变换方式能够从理论上实现无奇异参数的超材料电磁隐身斗篷,这种方法也拓展了变换光学原理在超材料隐身装置设计方面的应用。     

液相色谱质谱法测定水体及土壤中的类固醇激素

建立了水体和土壤中类固醇激素的液相色谱质谱分析方法。水样采用固相萃取方法富集,土壤样经加速溶剂萃取后由固相萃取净化和富集。处理好的样品经丹磺酰衍生化后上仪器分析。结果表明,类固醇激素在水体和土壤中的检出限分别为0.01~0.6ng/L和0.01~0.19ng/g,回收率分别为77%~97%和62%~119%,RSD小于6.04%和15.5%。该方法具有较高的准确度和精密度,适用于环境水体及土壤中类固醇激素残留的分析。     

浅析原油罐二次密封在线改造过程中的风险与对策

介绍了外浮顶储罐二次密封的机理,剖析了原油储罐二次密封在线改造过程中潜在的风险,并结合某企业改造案例提出了控制措施,对类似油罐二次密封在线改造具有一定的借鉴意义。     

固相萃取-原子荧光光谱法测定土壤中的砷

采用硝酸-氢氟酸-盐酸体系微波消解土壤并结合On-Guard ⅡH柱去除消解液中重金属,原子荧光光谱法测定土壤中的砷。本方法前处理操作过程简单、省时、省力、酸用量少,砷的加标回收率为94.4％～105.6％,能够满足环境监测分析的要求。     

土地利用变化下的生态系统服务敏感性研究——以克里雅绿洲为例

通过剖析传统的敏感性分析法,提出交叉敏感性概念,评价生态服务价值对土地利用类型转换的响应性。以克里雅绿洲为研究区域,以1991、2002 和2011 年三期遥感影像数据为基本信息源,运用交叉敏感性分析,计算生态系统服务价值对土地利用类型转换的敏感性,确定生态系统日趋敏感的土地利用变化过程,为土地管理对策提供参考依据。研究结果表明:20 a来,克里雅绿洲生态服务价值较敏感的土地利用转换类型相对稳定,主要集中在湿地和水体向荒漠和低覆盖度草地的转换;与1991 和2011 年相比,2002 年的交叉敏感性系数普遍上升,这主要是因为湿地、水体面积的减少加剧了研究区的生态脆弱性,从而表现出更大的敏感性;湿地和水体向耕地转换的交叉敏感性一直处于上升趋势,并不断接近于-1,表明生态服务价值对高强度的人为活动变得越来越敏感,从而警示地方管理部门采取必要措施制止此种转换的持续。     

In-situ surfactant/surfactant-nutrient mix-enhanced bioremediation of NAPL (fuel)-contaminated sandy soil aquifers

SCOPE AND BACKGROUND: Contamination of soils, aquifers and groundwater by nonaqueous phase liquid (NAPL) pollutants constitutes a major environmental issue of concern, worldwide. The residual (biodegradation-resistant) hydrophobic fuel hydrocarbons entrapped in the soil porous matrix, possess a particular bioremediation challenge due to their becoming virtually immobile, nor desorbable, or water dispersible. Consequently, they are not available as substrates to the micro-organism-based biodegradation. MATERIALS AND METHODS: Our research involves the development of economically feasible, surfactant/surfactant-nutrient mix (SSNM)-enhanced bioremediation methodologies for sustainable, in situ bioremediation of fuel-contaminated aquifers. This requires, methodologically, (a) the optimization, via in vitro 'flow' (columns) lab experiments and screening processes, of an effective mixture for the intended SSNM-enhanced bioremediation; and (b) the study of the combined effect of the optimized SSNM on the solubilization/mobilization and biodegradation of NAPL (fuel) in in vitro site/aquifer-simulated bioremediation. RESULTS AND DISCUSSION: The essence of our findings: (1) kerosene's maximum enhanced mobilization - f = 3.6, compared with that of deionized water, was achieved with an SSNM having the composition of linear alkylbenzene sulfonate (LABS): coco-amphodiacetate (containing N): surfactant-nutrient X (containing both N and P) = 0.15: 0.15: 0.05 g/L, respectively; (2) 62-64% of the initial amount of kerosene in the initially saturated soil matrix, 'packed' in a column, has been eluted from it during approximately 30 days, compared with 68% of kerosene biodegradation in 'vessel' settings, in 21 days. CONCLUSIONS: (1) The indigenous microorganisms present in th vadose zones of fuel-contaminated sandy soil aquifers are potentially capable of unassisted removal of approximately 80% of the initially contained fuel (kerosene), during a period of about 42 days; (2) the major effects of the SSNM addition are (a) enhanced mobilization of the bulky NAPL; and (b) enhanced desorbtion/ solubilization/dispersion of the entrapped NAPL which, in turn, facilitate their enhanced biodegradation. RECOMMENDATIONS AND PERSPECTIVE: Our findings suggest that pre-optimized, biodegradable SSNM is essential for surfactants-based bioremediation of NAPL-contaminated aquifers, in order to make this in-situ methodology both technologically and economically feasible.