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661.
Jin Zhang Qiang Yang Xiaofei Song Hui Qiao Junhao Zhang 《International Journal of Green Energy》2017,14(12):1011-1019
Electrospun cellulose acetate (CA) nanofibrous mats incorporated with capric acid was studied to fabricate form-stable phase change materials (PCMs) for storing/retrieving thermal energy. Electrospun CA nanofibrous mats with different porous structures and specific surface areas were firstly prepared through regulating the volume ratio of mixture solvent of acetone/dichloromethane (DCM). Effects of different volume ratio of mixture solvent and mat thickness on the morphological structure, specific surface area, and absorption capacity of CA nanofibrous mats were systematically investigated. The results indicated that CA nanofibrous mats were highly porous on the surface; hence, they were capable of absorbing a large amount of capric acid. The maximum absorption capacity of CA mats via electrospinning with volume ratio of acetone/DCM being 5/5 was ~95.8 wt%, due to its higher specific surface area of ~17.1 m2/g. The specific surface area and capric acid absorption capacity of CA nanofibrous mats increased with the increases of mat thickness. As the thickness of nanofibrous mats increased from 10 to 85 μm, the corresponding specific surface area and capric acid absorption capacity of mats increased respectively from 7.2 to 29.0 m2/g and 92.1 to 98.5%. Morphological structures, as well as the properties of thermal energy storage and thermal insulation of the fabricated form-stable PCMs, were studied by scanning electron microscopy, differential scanning calorimetry, and measurement of freezing times, respectively. The results indicated that the resulting form-stable PCMs could well maintain their phase transition characteristics and demonstrated great thermal energy storage capability and temperature regulation ability. 相似文献
662.
Mert Gürtürk Ahmet Koca Yasin Varol Mehmet Şekerci 《International Journal of Green Energy》2017,14(12):1073-1080
Solar energy is one of the most important renewable energy sources, but it is not available every time and every season. Thus, storing of solar energy is important. One of the popular methods of heat storage is use of phase change materials (PCMs) which have large thermal energy storage capacity. In this study, the heat storage tank in a domestic solar water heating system was chosen as control volume. The experiments were performed in the province of Elaz?g, Turkey, in November when solar radiation was weak due to cloudy sky. The heat storage tank of the system was modified to fill PCM between insulation and hot water part. A few PCMs which are Potassium Fluoride, Lithium Metaborate Dihydrate, Strontium Hydroxide Octahydrate, Barium Hydroxide Octahydrate, Aluminum Ammonium Sulfate, and Sodium Hydrogen Phosphate were analyzed to proper operating conditions using a Differential Scanning Calorimeter (DSC) and the best PCM was obtained with the Aluminum Ammonium Sulfate and Sodium Hydrogen Phosphate mixture. Thus, eutectic PCM was obtained and used in a heat storage tank of the solar water heating system. Energy and exergy analysis of heat storage tank was performed with and without the PCM. Energy and exergy analysis has shown that the heat storage tank with the PCM is more efficient than without the PCM and the maximum exergy efficiency was obtained as 22% with the heat storage tank with the PCM. 相似文献
663.
664.
对蕃茄基因转化的受体系统进行了研究结果表明:在蕃茄离体子叶(或子叶切段)培养中,只加细胞分裂素(Zt或BA)即可使不定芽充分分化,而少量生长素对不定芽的分化反而有抑制作用;在所试验过的多种外植体中,以2/3子叶片处切割子叶所产生的外植体用作转化受体最好;不同蕃茄品种、同一品种的不同外植体及同一外植体的不同培养方式等均对转化频率有一定的影响;通过生长素短期刺激诱导,可解决转基因植物生很困难的问题. 相似文献
665.
666.
农杆菌介导的抗除草剂基因转入两系杂交稻恢复系的研究 总被引:5,自引:0,他引:5
利用农杆菌水稻高效转化系统,成功地将外源BAR基因转入实用性两系要交稻恢复系R187和秀水04,经过除草剂Basta田间涂布试验,其阳性率达到90%以上。对转基因植株同步进行的PCR特异扩增和总DNA Southern检测结果也证实抗Basta的植株中含有BAR基因。讨论了应用转BAR基因的方法提高两系杂交水稻制种纯度的条件。图2表1参3 相似文献
667.
Anaerobic biodegradation of benzene series compounds by mixed cultures
based on optional electronic acceptors 总被引:6,自引:2,他引:4
A series of batch experiments were performed using mixed bacterial consortia to investigate biodegradation performance of benzene, toluene, ethylbenzene and three xylene isomers (BTEX) under nitrate, sulfate and ferric iron reducing conditions. The results showed that toluene, ethylbenzene, m-xylene and o-xylene could be degraded independently by the mixed cultures coupled to nitrate, sulfate and ferric iron reduction. Under ferric iron reducing conditions the biodegradation of benzene and p-xylene could be occurred only in the presence of other alkylbenzenes. Alkylbenzenes can serve as the primary subs'rates to stimulate the transformation of benzene and p-xylene under anaerobic conditions. Benzene and p-xylene are more toxic than toluene and ethylbenzene, under the three terminal electron acceptors conditions, the degradation rates decreased with toluene 〉 ethylbenzene 〉 m-xylene 〉 o-xylene〉 benzene 〉 p- xylene. Nitrate was a more favorable electron acceptor compared to sulfate and ferric iron. The ratio between sulfate consumed and the loss of benzene, toluene, ethylbenzene, o-xylene, m-xylene, p-xylene was 4.44, 4.51, 4.42, 4.32, 4.37 and 4.23, respectively; the ratio between nitrate consumed and the loss of these substrates was 7.53, 6.24, 6.49, 7.28, 7.81, 7.61, respectively; the ratio between the consumption of ferric iron and the loss of toluene, ethylbenzene, o-xylene, m-xylene was 17.99, 18.04, 18.07, 17.97, respectively. 相似文献
668.
Ti/Sb-SnO_2 anodes were prepared by thermal decomposition to examine the influence',of the amount of Sb dopant on the structure and electrocatalytic capability of the electrodes in the oxidation of 4-chlorophenol.The physicochemical properties of the Sb-SnO_2 coating were markedly influenced by different amounts of Sb dopant.The electrodes,which contained 5% Sb dopant in the coating, presented a much more homogenous surface and much smaller mud-cracks,compared with Ti/Sb-SnO_2 electrodes containing 10% or 15% Sb dopant,which exibited larger mud cracks and pores on the surface.However,the main microstructure remained unchanged with the addition of the Sb dopant.No new crystal phase was observed by X-ray diffraction(XRD).The electrochemical oxidation of 4-chlorophenol on the Ti/SnO_2 electrode with 5% Sb dopant was inclined to electrochemical combustion;while for those containing more Sb dopant,intermediate species were accumulated.The electrodes with 5% Sb dopant showed the highest efficiency in the bulk electrolysis of 4-chlorophenol at a current density of 20 mA/cm~2 for 180 min;and the removal rates of 4-chlorophenol and COD were 51.0% and 48.9%,respectively. 相似文献
669.
Permeation of Cu(II) from its aqueous solution through a supported liquid membrane (SLM) containing di(2-ethylhexyl)phosphoric acid (D2EHPA) carrier dissolved in coconut oil has been studied. The effects of Cu(II), pH (in feed), H2SO4 (stripping) and D2EHPA (in membrane) concentrations have been investigated. The stability of the D2EHPA-coconutoil has also been evaluated. High Cu(II) concentration in the feed leads to an increase in flux from 4.1 × 10-9 to 8.9 × 10-9 mol/(m2·s) within the Cu(II) concentration range 7.8×10-4-78.6×10-4 mol/L at pH of 4.0 in the feed and 12.4 × 10-4 mol/L D2EHPA in the membrane phase. Increase in H2SO4 concentration in strip solution leads to an increase in copper ions flux up to 0.25 mol/L H2SO4, providing a maximum flux of 7.4 × 10-9 mol/(m2·s). The optimum conditions for Cu(II) transport are, pH of feed 4.0, 0.25 mol/L H2SO4 in strip phase and 12.4 × 10-4 mol/L D2EHPA (membrane) in 0.5 (m pore size polytetrafluoroethylene (PTFE) membrane. It has been observed that Cu(II) flux across the membrane tends to increase with the concentration of copper ions. Application of the method developed to copper plating bath rinse solutions has been found to be successful in the recovery of Cu(II). rane. It 相似文献
670.