南京市产业结构变化对生态环境影响分析

产业结构变化对生态环境影响深远。本文分析了2001—2016年南京市产业结构演进轨迹和高级度变化,采用Spearman相关分析法定性描述了三产比重对生态环境的影响,利用生态环境影响指数定量分析了产业结构的生态环境效应,并通过产业高级度和生态环境影响指数的相关性分析研究了产业结构升级的生态环境效应。结果表明:(1)研究时段内全市产业结构总体经历了一次转型,产业结构高级度总体呈现逐年上升趋势;(2)第一产业、第二产业产值占比与SO_2排放量、NO_x排放量、SO_2年均浓度均呈正相关关系,第三产业产值占比则与其均呈负相关关系;(3)全市产业结构生态环境影响属于中等,产业转型引起的生态环境效应轨迹与产业结构变动轨迹在变化趋势上存在一致性,且要滞后于产业结构转型。随着产业结构高级度的提高和产业结构升级的加速,南京市生态环境会得到改善。     

From pioneering to organised business: the development of ecological farming in China

ABSTRACT

Small-scale ecological farming and their associated alternative food networks, are increasingly important in China, as a response to poor farm incomes and as a contribution to widespread concerns about environmental degradation and food safety. However, despite the enormous market potential and the notable success of some ventures, this type of farming remains at the margins, with many businesses struggling to develop beyond their start-up phase and consumers struggling to build confidence in the new produce and routes to market. Many of these farms display the classic elements of pioneer businesses, including high reliance on charismatic individuals, insecure land rights, high transaction and monitoring costs and fragile routes to market. Empirically, many of these businesses fail because they cannot grow out of the pioneer phase before the pioneer grows tired of the business. While this is a problem for all small businesses, it is particularly acute in business sectors like ecological farming in China, where there is little evidence of suitable and sustainable developmental models. Using Bernardus Lievegoed's work on organisational development applied to two case study farms, we suggest that there are Western developmental models that are applicable to small-scale ecological farming and that have the potential to offer insights into how this might be achieved with Chinese characteristics. We conclude by arguing that, Chinese ecological farms have to plan explicitly for a form of development that allows them to remain committed to their ideals while moving them away from dependence on charismatic people, family labour and volatile customer bases.     

几种新型光催化水质净化反应器的探讨

综述了几种新型光催化反应器的结构、特征，讨论各反应器的应用情况和处理效果，对其优缺点进行评价。指出光催化技术与其它成熟水处理技术的耦合是光催化工艺进入实际应用的重要途径。     

NAPLs污染物垂向指流迁移分形表征中图像处理的影响研究

染色示踪技术是研究多孔介质中指流形态的主要手段之一,而如何更精确地对所采集的图像数据进行分析,是该研究工作中非常重要的组成部分.分形理论在染色示踪影像的基础上对指流形态进行定量描述,以质量分形维数(D m)表征渗流面积,以界面分形维数(D s)表征渗流驱替边界长度,对于识别和预测指流形态有一定的实际意义.而分形维数的计算基于二值化图像完成,因此明确图像二值化过程对分形维数表征的影响对分形维数的应用有重要意义.本研究以4种非水相流体在二维砂箱中迁移的130幅染色图像为目标影像,详细比较了图像预处理过程中不同饱和度(红色)阈值、不同亮度(灰度)阈值以及图形中"湖"的填充3个因素分别对D m和D s的影响.结果表明,在砂箱实验中,与田间实验相比由于染色污染物与石英砂颜色对比度较大,红色阈值调整对两种分形维数影响相对较小;随着灰度阈值的提高D m平均降低0.02,D s平均增加0.05;图形中"湖"的填充对D m几乎没有影响,而使D s平均降低0.10.研究发现与D s相比,D m在图像处理过程中受各种因素影响较小,建议在进一步研究中以D m为指流形态指示指标以避免图形处理过程中主观因素的影响.     

气相色谱/串联质谱法分析水中痕量酞酸酯

采用C18固相萃取结合气相色谱/三重串联四极杆质谱联用仪建立了地表水中痕量酞酸酯(PAEs)类化合物的分析方法。使用串联质谱特有的多反应监测模式可以很好的去除基质的背景干扰,对列入美国环保局优先控制污染物名单的六种PAEs均实现基线分离,在50～1 000 ng/mL范围内线性良好,6种PAEs的相关系数均大于0.99,加标回收率在89.8%～103.4%之间,方法的精密度较好(RSD<10%)。应用于实际地表水样品中PAEs的分析表明,某市地表水中含有邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯和邻苯二甲酸(2-乙基己基)酯,其中邻苯二甲酸二丁酯含量最高(均值为1.25μg/L),邻苯二甲酸丁基苄基酯和邻苯二甲酸二辛酯均未检出。     

ASBR法处理厨房垃圾的酸化研究

应用2阶段序批式厌氧反应器(ASBR)方法对厨房垃圾进行实验室规模酸化阶段的处理研究,结果表明:水解酸化反应器的最佳工况为:进料含固率8%、水力停留时间(HRT)5d,负荷为16g(TS)/(L·d);水解相产酸效率与HRT、pH值以及进料浓度有关;同时建议水解相的最佳pH值为4～5之间较适宜。     

Determination of haloacetic acids in hospital effuent after chlorination by ion chromatography

The ion chromatography combined solid phase extraction (SPE) method was developed for the analysis of low concentration haloacetic acids (HAAs), a class of disinfection by-products formed from chlorination of hospital wastewater. The monitored HAAs included monochloroacetic acid, monobromoacetic acid, dichloroacetic acid, dibromoacetic acid and trichloroacetic acid. The method employed a sodium hydroxide eluent at a flow rate of 0.8 mlmin, electrolytically generated gradients, and suppressed conductivity detection. To analyze the HAAs in real hospital wastewater samples, C18 pretreatment cartridge was utilized to reduce samples' turbidity. Preconcentration with SPE and matrix elimination with treatment cartridges were investigated and found to be able to obtain acceptable detection limits. Linearity, repeatability and detection limits of the above method were evaluated. The detection limits of monobromoacetic acid and dibromoacetic acid were 2.61 μgL and 1.30 μgL, respectively, and the other three acids are ranging from 0.48 to 0.82 μgL under 25-fold preconcentration. When the above optimization procedure was applied to three hospital wastewater samples with different treatment processes in Tianjin, it was found that the dichloroacetic acid was the major compound, and the growth ratios of the HAAs after disinfection by sodium hypochlorite were 91.28%, 63.61% and 79.50%, respectively.     

黄土高原资源型城市文化娱乐业发展对经济转型的影响

经济转型是资源型城市实现高质量发展的关键。文化娱乐业作为经济增长新引擎,在资源型城市经济转型中起着重要作用。采用黄土高原资源型城市2010—2019年面板数据,在构建综合指数测度资源型城市经济转型成效的基础上,运用空间杜宾模型实证检验文化娱乐业对经济转型的作用。结果表明：文化娱乐业对经济转型的影响呈先抑制后促进的“U”型曲线,在文化娱乐业发展初期,文化娱乐业的过度发展不利于经济转型升级,当文化娱乐业密度跨过拐点（5.104个/万人）后,经济转型成效会随着文化娱乐业的发展而提升;文化娱乐业具有显著的空间溢出效应,可以有效促进邻近城市经济转型,且邻近城市经济转型的提高会带动本市经济转型。研究结果有望为黄土高原资源型城市高质量发展提供科学依据与决策支持。     

高寒干旱区地表水与地下水水化学特征及转换关系：以大通河流域为例

全球气候变暖和区域极端气候会导致高寒干旱山区平原降雨失衡、冰川融化和冻土退化,进而改变区域水文循环.其中,地表水与地下水转化关系是高寒干旱区水文循环气候响应的重要科学问题之一.以祁连山南麓大通河流域为研究区,基于119组基本水化学参数和38组氘氧同位素数据,利用多元统计分析和同位素技术,研究了流域地表水与地下水的水化学特征及其相互转化过程.结果表明,流域地表水以HCO₃-Mg·Ca型水为主,受控于岩石风化作用;地下水以HCO₃-Mg·Ca型和Cl·SO₄-Na型水为主,受岩石风化作用和蒸发浓缩共同控制.上游地下水存在少量钙、镁长石的溶解,中游地下水化学组分主要为碳酸盐岩的风化溶解,下游地下水中各离子组分蒸发富集使地下水溶解性总固体升高.风化溶滤、人为活动、原生沉积环境、阳离子交替吸附及其他因素对研究区地表水和地下水化学组分的贡献率依次为39.1%、 15.0%、 12.6%、 13.8%和19.5%.δD和δ¹⁸O同位素测试结果表明,沿地下水流向大通河河水氘氧同位素含量呈富集到贫化的变化趋势,大通河...