三维花状结构α-FeOOH协同H2O2可见光催化降解双氯芬酸钠

采用油浴回流法,在常压回流反应条件下批量制备出三维花状结构的α-Fe OOH纳米材料,并利用XRD、FT-IR和SEM等仪器对其进行分析表征;以双氯芬酸钠为目标污染物,考察三维花状结构α-Fe OOH纳米材料,在模拟太阳光照射下,催化H2O2降解有机污染物的性能.结果表明,三维花状结构α-Fe OOH由纳米棒自组装形成,纳米棒的长度约400~500 nm,直径约40~60 nm.以模拟可见光为光源,三维花状结构α-Fe OOH与H2O2构成光助异相类Fenton体系,对双氯芬酸钠有良好的光催化降解效果,在90 min内对初始浓度为30 mg·L-1的双氯芬酸钠降解去除率达到99%以上,催化降解反应以羟基自由基氧化反应为主.     

The oil industry along the Atlantic coast of Cameroon: Assessing impacts and possible solutions

While the oil industry along the Atlantic coast of Cameroon has made important contributions to the national economy, this has been accompanied with adverse environmental impacts. There has been significant pollution from oil drilling, refinery waste, oil spillage, gas and flaring. After discussing these impacts, this paper argues that prevailing regulations are inadequate and need overhauling. It proposes that cleaner production requires:

(i)

specific laws to protect dwellers in the neighbourhood of oil refineries, filling stations, service stations and pipelines;     

用松香胺萃取处理含酚废水的研究

用松香胺萃取处理模拟含酚废水。研究了萃取剂组成、油水比、废水酸度对分配系数的影响,萃取温度、萃取时间对脱酚效率的影响,以及反萃剂的浓度、用量和反萃温度对反萃率的影响。     

Prioritizing R&D for the U.S. Department of Energy's Weapons Complex Clean-Up

Prioritizing the U.S. Department of Energy's (DOE's) targeted R&D program supporting weapons-complex clean-up has been problematic. Considering issues common to all R&D evaluation, linking R&D prioritization to clean-up project prioritization, the latter aligned with institutional goals, offers a pragmatic solution. This method is illustrated with results of a clean-up prioritization model of DOE's Oak Ridge National Laboratory site.     

Development of a Model for Simulation of Solute Transport in a Stream–Aquifer System

A model for simulation of solute transport in a dynamic stream–aquifer system is developed by integrating four existing sub-models. Interface packages are created to link the sub-models. The developed model is successfully used to simulate chloride transport in the stream–aquifer system of the Arkansas River and the Equus Beds Aquifer in Kansas and demonstrates that chloride concentration in the aquifer decreases in the vicinity of the simulated channel over time.     

含瓦斯煤岩突出过程数值模拟

含瓦斯煤岩突出是煤炭开采过程中一种复杂的工程诱发灾害。根据煤岩体变形与瓦斯渗流的基本理论 ,考虑煤岩介质材料力学性质的非均匀性特点以及煤岩介质变形破裂过程中透气性的非线性变化特性 ,建立了含瓦斯煤岩突出过程固气耦合作用的RFPA2D Flow模型。利用该模型对石门掘进诱发的含瓦斯煤岩突出进行了初步的数值模拟 ,模拟结果再现了煤岩介质在瓦斯压力、地应力和煤岩力学性质等因素综合作用下由裂纹萌生、扩展、相互作用、贯通直至失稳抛出的突出全过程 ,揭示了采动影响下煤岩介质渐进破坏诱致突变的非线性本质 ,包括含瓦斯煤岩破裂过程中应力场的演化 ,为含瓦斯煤岩突出机理研究提供一套全新的数值试验分析工具。     

上海世博会地下变电站基坑围护结构的动力反应分析

采用三维快速拉格朗日程序FLAC3D,对上海世博会500 kV地下变电站围护结构的动力反应问题进行了深入细致的分析和研究。所建立的模型采用摩尔-库伦本构关系,同时考虑了静力、动力以及地下承压水的影响,并且通过FLAC3D软件的二次开发功能引入统一强度理论,来判别围护结构中钢筋混凝土的应力状态,力求更真实地反映围护结构在动力作用下的响应状态。分析结果表明,圆型围护结构的环向刚度比较大,受力时将大部分侧向荷载转移给其环向拱结构,从而使得基坑和周围土体无论在静力状态还是动力状态下,整体变形均较小;基坑整体在所研究的各种工况下,围护结构都处于安全状态。     

酸性条件下Fe3+氧化SO2的脱硫反应机理

讨论酸性条件下Ｆｅ＾３＋液相氧化ＳＯ２的几何可能反应机理,设计了不同的缓冲和非缓冲Ｆｅ＾３＋溶液脱硫试验。通过对不同反应体系ＳＯ２吸收特性的测量,得出了反应符合半导体或过渡态金属的催化机理,液相氧化反应的速率受Ｆｅ＾３＋的老化进程所控制,从而为低浓度Ｆｅ＾３＋溶液烟气脱硫和解释雾水酸化现象提供了理论基础。     

Equilibrium study and kinetics of Cu removal from water by zeolite prepared from oil shale ash

Engineered zeolite was produced from oil shale ash by reaction with sodium hydroxide in a closed vessel reactor. This adsorbent was used for removal of copper ions from aqueous solution. The maximum adsorption capacity was 504.6 mg Cu²⁺/g zeolite. Kinetic studies showed that the rate of adsorption of copper is increased with increasing the solution pH and temperature, quantity of the zeolite and agitation speed. The kinetic data were fitted to homogeneous micropore model and found that the mass transfer coefficient and diffusivity of the Cu²⁺ are directly affected by the kinetic parameters. The increase in solution concentration will decrease the mass transfer coefficient while diffusivity is increased.