Sorption and desorption of lindane by wood charcoal in fixed‐bed reactor

Abstract

Sorption and desorption of lindane (y‐HCH) by wood charcoal (WC) and wood charcoal treated by 1N HNO₃ (WCT) in fixed‐bed reactor (FBR) were investigated in this study. WCT revealed a better performance than WC, in removing lindane in FBR. The breakthrough of lindane was significantly affected by the size of WCT, flow rate to the FBR, and depth of WCT bed. The removal of lindane in the presence of mixture of other pesticides was considerably reduced. The design parameters for FBR were calculated based on the bed‐depth service time (BDST) approach. Many parameters Viz. depth of sorption zone, velocity of sorption, sorbent use rate, critical bed‐depth, bed efficiency, and service time, were determined for design of the fixed‐bed. Using the material balance principle, the characteristics of the wave‐front were evaluated and found that the wave‐front velocity is approximately equal to the sorption velocity determined from the BDST approach. Desorption studies were performed in dilute organic solvent media and they gave an excellent performance in regeneration process.     

电梯结构噪声分析和控制

文中根据民用电梯的一般结构布局,通过对声传播途径分析,得到电梯噪声扰民是受结构噪声影响的结论。通过对电梯系统和电梯与支架组成系统的力平衡分析,得出电梯结构噪声主要是主机支架设计不合理和安装不当产生的。文章提出了结构噪声防治措施,并对结构噪声扰民的多台电梯实施了工程控制措施,均取得了预期的降噪效果。     

变频器故障波形预处理方法研究

电力电子设备在电力系统中的运用越来越广泛,其故障后对电力系统的运行影响也越来越大,从运行设备中提取波形用于诊断其相关故障的诊断方法的研究正在深入开展。由于现场采集波形的数据往往过于庞杂,不利于切中关键的故障特征,在研究用现场录波进行故障诊断前,首先要研究如何对实际采集的波形数据进行简化的方法。本文通过编制C＋＋程序,对故障录波简化过程进行了研究,并通过故障波形不同简化效果的对比说明了提高数据处理效率与减少波形特征损失的结合点的选取。     

城市环境中加油站燃爆灾害的安全评估探讨

为了准确计算城市环境中加油站的安全距离并进行安全评估,针对城市中一级加油站蒸汽云爆炸灾害效应开展分析,基于TNT当量法和Roberts点源模型,计算距离加油站不同距离上的爆炸波超压和火球热辐射通量。依据相应的伤害准则,系统评估了灾害效应,并与已有试验数据和规范进行对比验证和分析。研究结果表明,城市一级加油站的爆炸安全距离为37 m,热辐射安全距离为52 m。     

大质量熔融铝液遇水爆炸效应评估

为揭示蒸汽爆炸灾害形成机制,建立了大质量熔融铝液遇水自触发爆炸反应模拟装置。根据反应特征和破坏程度,熔融铝液遇水爆炸反应可分为柔和爆炸、剧烈爆炸与猛烈爆炸等3种类型;基于爆炸相似准则,定量化描述了爆炸反应的冲击波破坏效应;热效应则来自冲击波绝热压缩和产物热交换耦合作用;从热力学角度来看,铝液与容器底面夹裹形成过热亚稳态水,可认为是爆炸反应的触发源。     

突出冲击波对防突风门的破坏失效研究*

为了分析煤与瓦斯突出事故中防突风门的安全性,同时降低成本寻求对现有防突风门材料和结构的替代方案,研究不同厚度的Q460钢制防突风门在突出冲击波载荷下的破坏情况。基于能量法得到不同厚度的风门最大挠度数学模型,再根据煤炭行业规定中的对应数据和安全要求,运用LS-DYNA软件对冲击载荷下的风门破坏进行数值模拟,得到Q460钢制防突风门的静力学特征并与能量法结果进行比对。结果表明:长宽分别为1.75 m和1.8 m,厚度为25 mm和30 mm的风门在0.6 MPa的冲击波超压作用下能满足安全要求,能量法计算结果与数值模拟误差在9%以内,基于安全设计余量可以接受;提出挠厚比概念,当挠厚比小于0.84时,风门不会被破坏,在使用Q460钢设计防突风门时,应尽量确保该值小于0.84。     

高压管汇磁致伸缩导波缺陷检测模拟研究

针对高压管汇导波缺陷检测问题,基于磁致伸缩效应,借助COMSOL有限元仿真软件,建立高压管汇直管段的导波缺陷检测模型,探究导波的激励条件及缺陷检测效果,分析不同参数对缺陷附近磁感应强度分布的影响。研究结果表明:在频率为10 kHz的正弦电流信号激励下,可产生沿管道轴向传播的T（0,1）模态导波,并能辨别缺陷处的回波信号。改变缺陷的尺寸参数时,缺陷附近的磁感应强度随着缺陷深度增加呈增大趋势,随轴向宽度增加呈减小趋势,不同形状的缺陷对应的磁感应强度存在一定的差异;改变激励条件,磁感应强度均随激励电流、激励频率的增加呈不断增加趋势。     

Numerical and experimental study on the generation and propagation of negative wave in high-pressure gas pipeline leakage

Negative-wave-based leakage detection and localization technology has been widely used in the pipeline system to diminish leak loss and enhance environmental protection from hazardous leak events. However, the fluid mechanics behind the negative wave method has yet been disclosed. The objective of this paper is to investigate the generation and propagation of negative wave in high-pressure pipeline leakage. A three-dimensional computational fluid dynamic (CFD) study on the negative wave was carried out with large eddy simulation (LES) method. Experimentally validated simulation presented the transient wave generation at the leak onset and the comprehensive wave evolution afterwards. Negative wave was proven to be a kind of rarefaction acoustic waves induced by transient mass loss at the onset of leakage. Diffusion due to the density difference at wave fronts drives the negative wave propagation. Propagation of negative wave can be categorized into three states – semi-spherical wave, wave superposition and plane wave, based on different wave forms. The wave characteristics at different states were elucidated and the attenuation effects were discussed respectively. Finally, a non-dimensional correlation was proposed to predict the negative wave amplitude based on pipeline pressure and leak diameter.     

Inhibiting effects of gas–particle mixtures containing CO2, Mg(OH)2 particles,and NH4H2PO4 particles on methane explosion in a 20-L closed vessel

The main risk factors from methane explosion are the associated shock waves, flames, and harmful gases. Inert gases and inhibiting powders are commonly used to prevent and mitigate the damage caused by an explosion. In this study, three inhibitors (inert gas with 8.0 vol% CO₂, 0.25 g/L Mg(OH)₂ particles, and 0.25 g/L NH₄H₂PO₄ particles) were prepared. Their inhibiting effects on methane explosions with various concentrations of methane were tested in a nearly spherical 20-L explosion vessel. Both single-component inhibitors and gas–particle mixtures can substantially suppress methane explosions with varying degrees of success. However, various inhibitors exhibited distinct reaction mechanisms for methane gas, which indicated that their inhibiting effects for methane explosion varied. To alleviate amplitude, the ranking of single-component inhibitors for both explosion pressure (P_ex) and the rate of explosion pressure rise [(dP/dt)_ex] was as follows: CO₂, NH₄H₂PO₄ particles, and Mg(OH)₂ particles. In order of decreasing amplitude, the ranking of gas‒particle mixtures for both P_ex and (dP/dt)_ex was as follows: CO₂–NH₄H₂PO₄ mixture, CO₂‒Mg(OH)₂ mixture, and pure CO₂. Overall, the optimal suppression effect was observed in the system with the CO₂–NH₄H₂PO₄ mixture, which exhibited an eminent synergistic effect on methane explosions. The amplitudes of P_ex with methane concentrations of 7.0, 9.5, and 11.0 vol% decreased by 37.1%, 42.5%, and 98.6%, respectively, when using the CO₂–NH₄H₂PO₄ mixture. In addition, an antagonistic effect was observed with CO₂‒Mg(OH)₂ mixtures because MgO, which was generated by the thermal decomposition of Mg(OH)₂, can chemically react with water vapor and CO₂ to produce basic magnesium carbonate (xMgCO₃·yMg(OH)₂·zH₂O), thereby reducing the CO₂ concentration in a reaction system. This research revealed the inhibiting effects of gas‒particle mixtures (including CO₂, Mg(OH)₂ particles, and NH₄H₂PO₄ particles) on methane explosions and provided primary experimental data.     

瓦斯积聚量及爆炸距离对风机和防爆门的影响研究*

为揭示瓦斯积聚量及瓦斯爆炸距离对风机和防爆门的影响机制,利用Fluent模拟软件,结合宁煤集团羊场湾矿的实际情况,在构建三维数学物理模型的基础上,开展不同瓦斯积聚量（56.52,113.04,169.56,226.08 m3）和不同爆炸距离（20,30,50,70 m）条件下的模拟研究。研究结果表明:风机和防爆门处超压峰值随瓦斯积聚量增加而增加,均呈线性关系,瓦斯积聚量为56.52 m3时风机处超压峰值为0.260 MPa,小于风机破坏荷载0.306 MPa;考虑安全系数前提下,当瓦斯积聚量超过56.52 m3时防爆门应开启保护风机;在确定瓦斯积聚量为56.52 m3基础上,分析不同爆炸距离对风机和防爆门影响,由模拟结果可知,风机和防爆门处超压峰值随爆炸距离增加而降低,均呈幂函数关系。研究成果可为瓦斯爆炸对风机和防爆门的影响研究提供指导。