Cr12MoV模具钢堆焊工艺及组织研究

研究了Cr12MoV模具钢堆焊工艺,对堆焊接头组织形貌分析和显微硬度测定表明,堆焊层具有高硬度,热影响区中的白亮带为残余奥氏体,它有利于缓解热应力。     

中空夹层钢管再生混凝土柱火灾后力学性能分析

基于ABAQUS建立中空夹层钢管再生混凝土短柱理论模型,进行受火后加载模拟,受火过程采用ISO-834标准升、降温曲线。进而探究柱构件在受火全过程中的温度分布规律和受火后的力学性能。并分析了受火时间、空心率、取代率、名义含钢率、钢管强度和混凝土强度等参数对柱构件剩余承载力的影响。结果表明:受火时间、含钢率、混凝土强度和钢材强度对构件剩余承载力影响较明显,空心率和取代率对构件剩余承载力影响较小;受火45 min和90 min后,空心率取33.90%能较大限度减轻构件自重,且具备良好的抗火性能。     

关于地震设防区建筑结构用钢的几点意见

从地震时结构用钢的换效模式出发，本文系统地提出了用于地震设防区内建筑结构用钢的性能要求。为些测定了现有常用建筑结构钢的抗震性能。并就如何提高工程抗震的可靠性，从合理选材和开发具有高抗震性能的钢材两个方面提出了意见。     

Ageing of chromium(III)-bearing slag and its relation to the atmospheric oxidation of solid chromium(III)-oxide in the presence of calcium oxide

Slag arising in ferrochromium and stainless steel production is known to contain residual levels of trivalent chromium. As the chromium is normally bound in the slag matrix in various silicate or spinel phases, and hence not easily mobilised, utilisation or controlled disposal of such slag is generally considered unproblematic. Experimental test work with a number of slag materials indicates, however, that very gradual oxidation of trivalent to hexavalent chromium does occur when the slag is exposed to atmospheric oxygen, rendering a quantifiable but small portion of chromium in this much more mobile and toxic form. Mechanisms and rates of the oxidation reaction were investigated in a number of long-term studies using both original slag materials and artificial mixes of chromium and calcium oxides. Powders of these materials, some of them rolled into balls, were left to age under different conditions for periods of up to 12 months. In the slag samples, which contained between 1 and 3 wt.% chromium, 1000–10 000 μg Cr(VI) were found per gram of chromium within 6–9 months of exposure to an ambient atmosphere. The rate of the oxidation reaction decreased exponentially, and the reaction could generally be said to have ceased within 12 months. In mixtures of calcium and chromium oxides the oxidation reaction is presumed to occur at the boundaries between chromium oxide and calcium oxide phases through diffusion of oxygen along the grain boundaries and of Cr³⁺ across the boundaries, resulting in the formation of calcium chromate. In the slags, where calcium and chromium oxide can form a solid solution, the oxidation is likely to occur at the exposed surface of grains containing this solution.     

新型内构式稀土磁盘废水处理器的研制与应用

针对轧钢废水中含有磁性铁氧化物 ,为使废水处理回用 ,研制了集预磁、磁吸、固液分离、自动清渣于一体的新型内构式稀土磁盘水处理器 ,并阐明了其应用的方法     

钢渣脱除烧结烟气中二氧化硫的实验研究

通过对钢渣的分析，确定了其作为脱硫剂的可能性。从钢渣在不同操作条件下脱硫的实验研究看，钢渣能有效地脱除烟气中的SO2，在湿润状态、低流速条件下，微细钢渣的脱硫能力较强，钢渣作为脱硫剂使用将具有良好的经济效益和环境效益。     

18CrNi4WA 钢渗碳针阀体开裂失效分析

目的研究18CrNi4WA钢渗碳针阀体开裂失效原因。方法通过化学成分分析、断口扫描分析、金相组织分析、能谱分析等测试手段,对18CrNi4WA钢渗碳针阀体的断裂模式及失效原因进行分析。结果针阀体失效件原始材料符合针阀体制造要求,但渗碳淬火温度过高,未得到最优的渗碳层组织,燃油中存在的硫元素导致喷油孔位置产生严重腐蚀,燃油局部压力的变化导致针阀体表面产生空蚀损伤,裂纹起始于喷油孔圆周面,自裂纹源向外发散呈月牙状,为典型疲劳断裂特征。结论腐蚀与空蚀损伤的协同作用加快裂纹的萌生,使针阀体在热疲劳及机械振动等交变载荷的作用下产生疲劳开裂,使用寿命大为降低。     

基于FAD的铝合金车体焊接缺陷安全性评价方法研究

目的确保高速列车运行安全,采用先进的方法和理论对焊接缺陷进行评定显得非常重要。方法采用断裂力学和有限元相结合的方法,建立车体全比例有限元模型。采用热弹塑性法对焊接残余应力进行有限元数值仿真。基于标准BS 7910提供的焊接缺陷评价方法,对焊接缺陷进行安全性评定。结果对车体带焊缝的有限元模型,依据BS EN12663标准施加车体所承受的载荷,获取焊缝关注点的应力转化所得到一次应力。根据关注点信息建立所在焊缝处的接头模型进行热弹塑性仿真模拟,从而获取该关注点残余应力数值及分布转化所得到二次应力。将焊接缺陷进行裂纹当量化,从而计算得到载荷比与应力强度因子比值,结合许用FAD曲线,对高速列车铝合金车体上焊缝关注点进行安全性评价。结论该方法对车体这种大型复杂焊接结构的安全性进行评价是可行的,并对焊接缺陷是否合于使用提出质量控制的建议。     

Water quality induced corrosion of stainless steel valves during long-term service in a reverse osmosis system

The current study analyzes the contribution of 10 water quality parameters (including pH, turbidity, conductivity, total dissolved solids (TDS), hardness, total organic carbon (TOC), alkalinity, calcium ions, chlorides and sulfates) to corrosion extent of stainless steel valves taken from different locations in a reverse osmosis system of a reclaimed water plant. The valves were in service for 5 years. Raman spectroscopy and X-ray photoelectron spectroscopy analyses are conducted to quantify corrosion products on different valves under various water quality conditions. On that basis, bivariate and multivariate regression analyses between the 10 water quality parameters and the corrosion extent of valve specimens (represented by metal loss percentage (MLP) values) are carried out to check the contribution of those water quality parameters to MLP. The results indicate that the proportions of metal oxides as corrosion products vary according to the corrosion extent of the valves. Although no linear correlation is found, all 10 water quality parameters except for pH show a significant positive correlation with the MLP values of the valve specimens. Moreover, results of multivariate regression suggest that the variation of MLP can be explained by turbidity, TDS, TOC and sulfates. A positive contribution of turbidity, TDS and TOC to MLP is observed, whereas the contribution of sulfates is negative. The results from the current work help to identify the reasons for water quality-induced failure of stainless steel equipment in RO systems.     

Chemical fixation of toxic metals in stainless steel pickling residue by Na2S∙xH2O, FeSO4∙6H2O and phosphoric acid for beneficial uses

The leaching concentrations of different metals in stainless steel pickling residue(SSPR)were determined and the toxic metals were treated using Na_2 S·xH_2 O,FeSO_4·6 H_2 O,and phosphoric acid.A modified European Community Bureau of Reference(BCR) sequential extraction was used to identify the speciation of the concerned metals.Results showed that SSPR contains a large amount of Ca(58.41%),Fe(29.44%),Cr(3.83%),Ni(2.94%),Mn(2.82%) and some of Al,Cu,Mg,Zn.Among them,Cr and Ni were the most toxic metals in SSPR,thus the raw SSPR falls into hazardous waste category due to the leaching amount of Cr.In addition,the leached Cr was identified as Cr6+(MgCr04) in the waste.BCR test revealed that risk assessment code(RAC) of Cr and Ni were 33.29% and 61.7%,indicating they posed "high" and "very high" risk to the environment,respectively.After fixing by Na_2 S·xH_2 O and FeSO_4·6 H_2 O,the leaching concentrations of Cr and Ni were less than 1.5 and 0.5 mg/L,respectively.After fixing by Na_2 S·xH_2 O and FeSO_4·6 H_2 O the tre ated SSPR can be safely reused as roadbed materials,concrete and cement aggregates.This study provides a useful implication in treatment and beneficial reuse of heavy metal-containing hazardous wastes.