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71.
黄河中上游能源化工区大气污染跨界环境影响分析 总被引:1,自引:0,他引:1
对黄河中上游能源化工区近地面和边界层顶气象流场及该区域大气污染长距离输送产生的跨界环境影响趋势特征进行了分析。结果表明,该区域近地面和边界层顶的流场总体上为西北向东南流动,大气污染物长距离输送可能影响的区域主要为华中地区;区域冷空气的活动对其大气污染物的清除起重要作用;通过CALPUFF模型的模拟结果表明,该区域SO2的影响程度和范围明显大于NO2,在区域内部存在污染物浓度较高的区域,但未对区外造成显著跨界环境影响。 相似文献
72.
Investigation of titanium liquid/gas diffusion layers in proton exchange membrane electrolyzer cells
Stuart M. Steen III Jingke Mo Zhenye Kang Gaoqiang Yang 《International Journal of Green Energy》2017,14(2):162-170
In a proton exchange membrane electrolyzer cell (PEMEC), liquid/gas diffusion layer (LGDL) is expected to transport electrons, heat, and reactants/products to and from the catalyst layer with minimum voltage, current, thermal, interfacial, and fluidic losses. In addition, carbon materials, which are typically used in PEM fuel cells (PEMFCs), are unsuitable in PEMECs due to the high ohmic potential and highly oxidative environment of the oxygen electrode. In this study, a set of titanium gas diffusion layers with different thicknesses and porosities are designed and examined coupled with the development of a robust titanium bipolar plate. It has been found that the performance of electrolyzer improves along with a decrease in thickness or porosity of the anode LGDL of titanium woven meshes. The ohmic resistance of anode LGDL and contact resistance between anode LGDL and the anode catalyst play dominant roles in electrolyzer performance, and better performance can be obtained by reducing ohmic resistance. Thin titanium LGDLs with straight-through pores and optimal pore morphologies are recommended for the future developments of low-cost LGDLs with minimum ohmic/transport losses. 相似文献
73.
地冲击荷载作用下双层结构磁流变阻尼器隔震效果的数值模拟 总被引:1,自引:0,他引:1
在抗爆结构中,一般采用单层隔震系统进行隔震,目前单层隔震系统的最大隔震率可以达到90%以上,但在加速度峰值很高的冲击荷载作用下,隔震后的结构响应加速度仍然很大。鉴于这种情况,本文对加入磁流变阻尼器(MRD)的双层隔震系统进行了研究。针对抗爆结构的两种典型荷载,采用改进Bouc-Wen模型和模糊控制方法,利用Matlab Simulink对双层隔震系统进行了数值模拟,计算了不同荷载作用下,不同隔震系统的加速度、位移及结构的振动剂量值(VDV)的响应,并与结构采用单层隔震系统的结果进行了对比。结果表明,与单层隔震系统相比,带有磁流变阻尼器的双层隔震系统没有太多的优越性。 相似文献
74.
Typologically identical (dwarf birch-herb-dwarf shrub-moss) open and closed larch forests growing on the same altitudinal transect have proved to differ in the structural-functional organization of lower vegetation layers. Coverage, general species composition, and species richness of the herb-dwarf shrub layer are higher in the open forest than in the closed forest. Correlations between individual species of vascular plants weaken upon transition from the open to the closed forest. Conversely, the coverage of the lichen-moss layer increases in the closed forest, which contributes to its role as a factor of selection of vascular plant species against the background of the prevailing influence of the tree layer. 相似文献
75.
76.
Joseph Sherma 《Journal of environmental science and health. Part. B》2013,48(4):429-440
Applications of thin layer chromatography and high performance thin layer chromatography for the separation, detection, and qualitative and quantitative determination of pesticides, other agrochemicals, and related compounds are reviewed for the period from July 1, 2004 to November 1, 2006. Analyses are covered for a variety of samples, such as food, crops, biological, environmental, pharmaceuticals, and formulations, and for residues of pesticides of various types, including insecticides, herbicides, and fungicides, belonging to different chemical classes. In addition to references on residue analysis, studies such as pesticide-structure relationships, metabolism, degradation, and lipophilicity are covered, many of which make use of thin layer radiochromatography. 相似文献
77.
78.
罗立昱 《中国环境管理干部学院学报》2012,22(3):39-41,45
臭氧层损耗是重要的全球环境问题之一。最早认识到臭氧层危害的美国率先在国内立法控制相关物质,然而另一大经济体——欧共体,在这一方面却行动迟缓。在保护臭氧层的国际谈判中,美欧之间相互妥协,最终达成了对氟氯烃化合物(CFCs)进行限控的《蒙特利尔议定书》。美欧之间的分歧来自国内化工业巨头的影响,国际经济变动影响外交决策。国际环境问题背后隐藏的经济关系与大国的领导作用是影响国际环境合作的主要因素。 相似文献
79.
The effect of dissolved humic substances (DHS) on the rate of water-gas exchange of two volatile organic compounds was studied under various conditions of agitation intensity, solution pH and ionic strength. Mass-transfer coefficients were determined from the rate of depletion of model compounds from an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution (dynamic system). Under these conditions, the overall transfer rate is controlled by the mass-transfer resistance on the water side of the water-gas interface. The experimental results show that the presence of DHS hinders the transport of the organic molecules from the water into the gas phase under all investigated conditions. Mass-transfer coefficients were significantly reduced even by low, environmentally relevant concentrations of DHS. The retardation effect increased with increasing DHS concentration. The magnitude of the retardation effect on water-gas exchange was compared for Suwannee River fulvic and humic acids, a commercially available leonardite humic acid and two synthetic surfactants. The observed results are in accordance with the concept of hydrodynamic effects. Surface pressure forces due to surface film formation change the hydrodynamic characteristics of water motion at the water-air interface and thus impede surface renewal. 相似文献
80.
本文以天然钠基膨润土为原料,采用水溶液聚合法,在室温条件下,通过改性聚丙烯酰胺对膨润土进行直接插层改性,制备了一种新型聚丙烯酰胺改性膨润土防渗材料。以此防渗材料作为防渗层,选用沈阳大辛填埋场的垃圾渗透液为处理对象,在动态实验下,就其对实际垃圾渗滤液中主要污染物去除的有效性和控制垃圾渗滤液渗透的可行性进行研究。抗渗性能测试结果表明,改性膨润土防渗性能较好,渗透系数为1.0×10^-7cm/s,达到固体废物填埋场的防渗材料国家标准1.0×10^-7cm/s的使用要求。改性膨润土防渗层对COD、氨氮、重金属离子去除效果较好,吸附作用较强,COD和氨氮最大去除率分别达到81%和91%,TFe、Zn^2+和TCr的最大去除率分别达到71%、58%和73%。实验结果验证了本研究所制备的改性膨润土防渗材料具有优良的抗渗、截污性能。 相似文献