广州城区夏季大气颗粒物数浓度谱分布特征

于2013年6月2日—7月15日,利用扫描迁移性粒谱仪(SMPS)对广州城区大气17～800 nm的粒子谱进行了连续观测,同时结合在线小时ρ(PM_2.5)及气象数据,对颗粒物污染特征进行了分析. 结果表明:观测期间,凝结核模态粒子、爱根核模态粒子、积聚模态粒子的数浓度范围分别为68～7 687、1 009～47 724、238～14 781 cm-3.平均数浓度谱及体积谱均呈单峰分布,峰值分别出现在50和300 nm左右. 根据双模态对数正态分布模型对平均数浓度谱拟合的结果可知,爱根核模态粒子和积聚核模态粒子的几何平均粒径分别为48和144 nm. 颗粒物数浓度及其谱分布日变化特征明显,在交通高峰及太阳辐射较强的时间段均出现峰值. 在观测阶段,粒子增长现象频繁发生,推测大气光化学反应引起的气-粒转化是广州城区夏季大气颗粒物的重要来源. 7月12—13日广州城区发生了一次典型的大气污染过程,ρ(PM_2.5)由18 μg/m3增至112 μg/m3,能见度降至8 km. 在该时间段,积聚模态粒子体积分数与ρ(PM_2.5)变化一致,R2(相关系数)达到了0.85. 后向轨迹分析表明,污染气团主要来自于西南方向,在陆地停留时间较长.      

天津市冬季气溶胶吸湿因子的粒径分布特征

气溶胶粒径吸湿增长因子［g（RH）］是影响气溶胶消光和气溶胶辐射强迫的重要因素.利用吸湿性串联差分电迁移率分析仪（HTDMA）观测了天津市冬季不同污染状态下气溶胶粒子g_m（RH）的粒径分布.同时基于水溶性离子的粒径分布,利用κ-Köhler理论获取了较宽粒径范围内（60 nm~9.8 μm）的g_κ（RH）,为环境状态下气溶胶光学参数和直接辐射强迫的模拟提供基础.结果表明,清洁状态下大气光化学反应较为活跃,超细粒子（<100 nm）的g_m（RH）较高,g_m（RH=80%）在1.30以上.重度污染天,气溶胶中水溶性离子的质量分数随粒子粒径增大而增加,导致g_m（RH）随着粒子粒径增大而增大,300 nm粒子的g_m（RH=80%）和g_m（RH=85%）分别可达1.39和1.46.在较宽粒径范围（60 nm~9.8 μm）内,不同模态气溶胶的吸湿性强弱表现为积聚模态>爱根模态>粗模态.大气重污染过程中气溶胶粒径明显增大,积聚模态气溶胶中NO₃^-和SO₄^2-含量较清洁天明显增加,受此影响,污染状态下积聚模态气溶胶的吸湿性较清洁天明显增强,g_κ（RH）达到1.3~1.4,具有强吸湿性的气溶胶粒径范围也同时扩大,在0.18~3.1 μm粒径段均较高,对能见度恶化有重要的贡献.     

不同粒径镁铝合金粉尘爆炸与抑爆特性研究

为了研究镁铝合金粉爆炸危险特性,利用20L球形爆炸容器进行测试,结果表明:180目 (80 μm)、 120目(125 μm) 和60目(250 μm)3种粒径下的金属粉尘爆炸下限浓度分别为45 g/m3,55 g/m3和95 g/m3。相同浓度下最大爆炸压力随粒径增大的而减小。以碳化硅和石墨为代表的研究中,60目,120目和180目的镁铝合金粉以10%的浓度梯度加入碳化硅浓度分别至50%,70%和80%,石墨浓度至30%,50%和60%时,镁铝合金粉不会发生爆炸。表明碳化硅及石墨等惰性粉尘都能对粉尘爆炸有抑制作用,其中石墨对镁铝合金粉的抑爆作用明显优于碳化硅。     

RATES OF RECENT SEDIMENTATION IN LAKE PEPIN1

ABSTRACT: Sedimentation rates since 1954 in Lake Pepin, as determined from the content of fallout cesium-137 in the sediment profile, have exceeded 2.5 cm/yr in the upper part of the lake. These rates, although somewhat less than those of the previous half century (1895–1954), are sufficiently large that the upstream portion of Lake Pepin is threatened with conversion to a marsh within a century. The density of the sediments measured increased with depth in the sampled profile from 1.1 to 1.2 g/ml at the sediment surface to 1.4 to 1.5 g/ml at 2- or 3-m depth. There was little or no change in the patterns of textural composition or density of the sediment profile with depth and age over the past 80 to 150 years.     

UNDERSTANDING A WATERSHED FROM THE BIOLOGICAL VIEWPOINT1

In watershed management the effects of plants on water cannot be considered a constant and forgotten because: plants of different sizes and forms use water at different rates and plants of the same size differ in their needs for water because of anatomical differences. Many common denominators are present in all watersheds covered by vegetation. Forces exerted on the soil water by vegetation, climate and soil are the same kinds of forces. The differences between watersheds in water yield potential appear to be due to differences in the degree in which these forces are exerted. However, the influence of biotic factors are more individual. The similarities and differences existing between watersheds suggest some principles that can be used as guides to understanding individual watershed problems and as possible guides to determining when, how, and where to treat a given watershed. Eleven principles are given and their application to the definition and solution of biological or vegetational problems of watershed management are discussed.     

RUNOFF,EROSION, AND SOLUTES IN THE LOWER TRUCKEE RIVER,NEVADA, DURING 19691

The Truckee River heads in the Sierra Nevada at Lake Tahoe, and terminates in Pyramid Lake. During the 1969 water year, flow about 9 miles upstream from the mouth (974,000 acre-ft) was almost four times the long-term average, due mainly to heavy winter rains and spring snowmelt. A short period of low-altitude rainfall produced the highest concentrations of suspended sediment, whereas a much longer subsequent period of snowmelt yielded a much greater total quantity of material. The upper 90 percent of the basin yielded about 260 acre-feet (630,000 tons) of sediment at the Nixon gage, whereas an estimated 2,800 acre-feet (6.8 million tons) was contributed by erosion of about 200 acres of river bank below the gage. Solute content at the gage ranged from 80 to 450 mg/l, dominated by calcium, sodium, and bicarbonate, plus silica in the most dilute snowmelt and chloride in the most concentrated low flows. Solute load totaled about 130,000 tons, of which the principal constituents in Pyramid Lake-sodium plus equivalent bicarbonate and chloride-amounted to almost 40,000 tons. The total solute load during a year of average flow may be 45,000-55,000 tons, including 18,000-22,000 tons of principal lake constituents.     

Effects of Lime and Ash Treatments on DOC Fractions and Low Molecular Weight Organic Acids in Soil Solutions of Acidified Podzolic Soils

Dissolved organic carbon (DOC) fractions and different low molecular weight organic acids (LMWOAs) were determined in soil solutions from two lime or ash treated Norway spruce sites in the south of Sweden. At Hasslöv, 3.45 t ha^-1 or 8.75 t ha^-1 dolomite were applied 15 years before sampling. Horröd was treated with 4.28 t ha^-1 ash and 3.25 t ha^-1 dolomite and sampled four years later. Propionate (7–268 M) and malonate (2–34 M) were the LMWOAsfound in the highest concentrations at Hasslöv. Two other LMWOAs dominated at Horröd, namely citrate (18–64 M)and fumarate (5–31 M). The differences in concentration of most of the determined LMWOAs at Hasslöv were significantly increased due to treatment. The LMWOAs comprised between 1.1–6.3% of the DOC at Hasslöv and 4.5–17.6% at Horröd. At Hasslöv normally 3–10% of the total acidity (TA) was due to LMWOAs and the average specific buffer capacity was 74 ± 22 mmol mol^-1C.The total DOC concentration in the mor layer solution was 16 mM for the dolomite treated plots compared to 10 mM at the untreated plot. A major part of the increase in DOC at the treated plots apparently had a hydrophobic character and was of high molecular weight corresponding to 3–10 kDa. The concentration of DOC < 1 kDa in the control and treated plots was similar.     

Formation and Transport of Atmospheric Aerosol over Athens, Greece

The effects of meteorology on ambient aerosol concentrations and aerosol transport, within the Greater Athens Area during the summer period, was investigated. Measurements of size fractionated anions and cations were made at two sites (inland at Ag. Stefanos and on the coast at Pireas) within the Greater Athens Area. The wind regime exhibited a distinctinfluence such that the sea-breeze circulation strongly enhanced the formation of secondary aerosols. For sulphate the difference in concentration between the two sites was,on average, 8 times greater on sea-breeze days compared with Etesian days (warm days with NE winds). During `normal' days,any differences in concentrations were possibly due to localemissions. Elevated concentrations in the fine mode were detectedat both sites during the sea-breeze days. The sea-breezecirculation enhances the development of secondary aerosolswhich was clearly shown at the inland site. Nitrous acid,hydrochloric acid and particulate nitrate, sulphate andammonium increase during sea-breeze days. Elevated levelsof nitrate, 4 m diameter, were particularly observedon the days with a strong sea-breeze circulation. Sulphatewas well correlated with both sulphur dioxide and ammoniumsuggesting the production of NH₄HSO₄/(NH₄)₂SO₄ aerosols, formedthrough the neutralisation of NH₃ with sulphuric acids.Ammonium sulphate was found to be the major ammoniumcomponent in Athens.     

基于χ~2优化方法的铸钢侧架原始裂纹尺寸分布研究

将铸钢侧架清砂后未经修复的原始裂纹尺寸进行了统计 ,综合运用参数的点估计方法和区间估计方法 ,以置信区间作为优化的约束条件 ,提出了对检验值进行最优化处理的方法 ,并运用二参数约束非线性优化方法的直接解法 ,搜索出最佳点估计值。经过对裂纹尺寸分布参数的计算证明 ,其结果符合对数正态分布