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51.
52.
Jen-Hao Chi Sheng-Hung WuJean-Claude Charpentier Yet-Pole IChi-Min Shu 《Journal of Loss Prevention in the Process Industries》2012,25(1):142-147
Hydrogen peroxide (H2O2), historically, due to its broad applications in the chemical industries, has caused many serious fires and explosions around the world. Its thermal hazards may also be incurred by an incompatible reaction with other chemicals, and a runaway reaction may be induced in the last stage. This study applied thermal analytical methods to explore the H2O2 leading to these accidents by incompatibility and to discuss what might be formed by the upset situations. Thermal hazard analysis contained a solvent, propanone (CH3COCH3, so-called acetone), which was deliberately selected to mix with H2O2 for investigating the degree of thermal hazard. Differential scanning calorimetry (DSC) and vent sizing package 2 (VSP2) were employed to evaluate the thermal hazard of H2O2. The results indicated that H2O2 is highly hazardous while mixed with propanone, as a potential contaminant. The time to maximum rate (TMR) was used as emergency response time in the chemical industries. Therefore, TMR of H2O2 was calculated to be 70 min for runaway reaction (after T0) and TMR of H2O2/propanone was discovered to be 27 min only. Fire and explosion hazards could be successfully lessened if the safety-related data are properly imbedded into manufacturing processes. 相似文献
53.
54.
通过应用信息化网络技术,建立了作业场所职业病危害因素检测与评价数据库,实现了用人单位作业场所有害因素检测与评价数据的申报、传递、编制、审核、报告打印、统计等功能。信息化模板的建立,降低了职业卫生学调查工作难度,方便了检测方案和报告编辑,统一了作业场所职业病危害因素检测与评价报告书生成格式,并自动生成职业病危害因素检测与评价报告书,提高了作业场所职业病危害因素检测与评价工作的质量。本系统具有操作简易、处理功能强大、内部监督管理完善等特点,实现作业场所职业病危害因素检测与评价信息管理科学化、规范化、信息化,降低了劳动强度,提高了工作效率,有很好的应用价值,尤其适合现阶段基层职业卫生工作的需要。 相似文献
55.
This paper explores the level of vulnerability to the hazard of fire that exists in Makola Market in Accra, Ghana, and assesses how this threat can be reduced through a community‐based risk assessment. It examines the perceptions of both market‐stall occupants and primary stakeholders regarding the hazard of fire, and analyses the availability of local assets (coping strategies) with which to address the challenge. Through an evaluation of past instances of fire, as well as in‐depth key stakeholder interviews, field visits, and observations, the study produces a detailed hazard map of the market. It goes on to recommend that policymakers consider short‐to‐long‐term interventions to reduce the degree of risk. By foregrounding the essence of holistic and integrated planning, the paper calls for the incorporation of disaster mitigation measures in the overall urban planning process and for the strict enforcement of relevant building and fire safety codes by responsible public agencies. 相似文献
56.
Reducing the release pressure of fire extinguishing systems can decrease potential safety hazards in large transport airplanes. To explore whether reducing the release pressure can achieve the release effect required by the airworthiness standards or not, the transportation characteristics in the pipeline and diffusion behaviors in the enclosure space of a typical fire extinguishing agent (Halon 1301) were investigated under five release pressures in the present study. The effects of the release pressure on the degree of superheat, injection duration, jet structure, and concentration distribution of Halon 1301 were analyzed. The results show that both of the degree of superheat and the injection duration decrease with an increase in the release pressure. The supplement of bubble expansion in the fire extinguishing agent can slow down the pressure decrease in the vessel. Both of the maximum and mean values of the pipeline differential pressure increase with an increase in release pressure. The maximum value of the jet angle decreases linearly with the increase in release pressure, and the jet deflects upward owing to the effects of buoyancy. The maximum concentration value decreases with an increase in the distance from the nozzle. The maximum concentration values in the near field from the nozzle increase with an increase in the release pressure. Under five release pressures, the concentration and holding time (duration above 6% volume concentration) of Halon 1301 on the centerline of the jet meet the requirements of airworthiness provisions. 相似文献
57.
大数据时代的建筑施工现场会产生海量数据信息,如何利用这些数据并从中找出建筑施工现场内外环境中危险源之间的关联关系,对于施工安全尤为重要。利用Apriori算法挖掘施工隐患数据集,生成危险源关联规则;然后依据任务驱动思想令计算机将施工任务映射到相应施工情境下的危险源关联规则中,管理者便可根据具体施工任务搜索到更想要关注的安全规则信息;从这些规则信息的搜索结果发现,隐患的发生常常是由于危险源在时间上的连续或在空间上的交互所致,因此利用这些挖掘出的关联规则可以帮助施工管理人员对施工现场进行有效安全管理。 相似文献
58.
Statistical inference on patch-specific survival and movement rates from marked animals 总被引:1,自引:0,他引:1
Michael J. Conroy Jon E. Anderson Stephen L. Rathbun David G. Krementz 《Environmental and Ecological Statistics》1996,3(2):99-116
Empirical estimates of patch-specific survival and movement rates are needed to parametrize spatially explicit population
models, and for inference on the effects of habitat quality and fragmentation on populations. Data from radio-marked animals,
in which both the fates and habitat locations of animals are known over time, can be used in conjunction with continuous-time
proportional hazards models to obtain inferences on survival rates. Discrete-time conditional logistic models may provide
inference on both survival and movement rates. We use Monte Carlo simulation to investigate accuracy of estimates of survival
from both approaches, and movement rates from conditional logistic regression, for two habitats. Bias was low (relative bias
< 0.04) and interval coverage accurate (close to the nominal 0.95) for estimates of habitat effect on survival based on proportional
hazards. Bias was high (
relative bias 0.60) and interval coverage poor (
= 0.26 vs. nominal 0.95) for estimates of habitat effect based on conditional logistic regression; bias was especially influenced
by heterogeneity in survival and the shape of the hazard function, whereas both bias and coverage were affected by ‘memory’
effects in movement patterns. Bias estimates of movement rate was low (
relative bias < 0.05), but interval coverage was poor (
= 0.48–0.80), possibly as a result of poor performance of a Taylor series estimate of variance. An example is provided from
a radio-telemetry study of 47 wintering American woodcock (Scolopax minor), illustrating practical difficulties in field studies to parametrize these models. We also discuss extensions of continuous-time
models to explicitly include a movement process, and further examine tradeoffs between continuous and discrete models. 相似文献
59.
L. Viverette H. W. Mielke M. Brisco A. Dixon J. Schaefer K. Pierre 《Environmental geochemistry and health》1996,18(1):41-45
This study tests the hypothesis that exterior sources of lead dust are more important than interior sources in the route of exposure of children. Benign field methods were used to distinguish between potential and actual lead exposure problems. Utilising hand wipe and surface wipe techniques, hand and environmental samples were obtained from selected day care centres at different locations within New Orleans. Previous research has shown that soil lead is determined by location within the city. Private and public day care centres were selected from inner and outer city areas to estimate the extent of hand lead exposure. To measure and identify the extent of environmental lead exposure, hand wipes were taken before and after playing outdoors. Results of preliminary findings show that outdoor lead dust is a more potent contaminant of hands than indoor lead dust. An association was found between the amount of lead on children's hands after playing outdoors and the lead content in the exterior dust and soil. Although two girls out of forty children had exceptionally high hand lead quantities after playing outdoors, in general, boys have higher hand lead levels than girls. The private inner-city day care centre had a severe contamination problem in its outdoor play area. By contrast, the outdoor play area of the public inner city day care centre is of such a high quality that the quantity of lead dust is independent of location in the city. 相似文献
60.
Haihui Wang Bogdan Z. Dlugogorski Eric M. Kennedy 《Journal of Loss Prevention in the Process Industries》1998,11(6):373-381
A mathematical model is presented to describe steady-state mass transfer and oxidation processes in coal at low temperatures in a fixed-bed flow reactor. The model incorporates the effects of partial pressure of oxygen, temperature and coal particle size, and accounts for the rate of coal oxidation and the composition of oxygenated products at high pressures. This is an important development since previous models did not include the effect of pressure in their formulation. It is found that, when the partial pressure of oxygen increases the rate of oxygen consumption increases accordingly. However, the influence of partial pressure of oxygen on the rate of oxidation is less pronounced when the pressure surpasses 1 MPa. In addition the model predicts that, for a constant partial pressure of oxygen, higher rates of oxygen consumption occur at lower total pressures. The same trends are also found for the concentration of oxygenated products at the reactor outlet. It is suggested that, the variation of partial pressure of oxygen leads to different concentration levels of oxygen at the surface and within the pores of coal particles, substantially affecting the rate of oxidation. 相似文献