液化石油气站重大危险源的危险性评价

液化石油气站的罐区属于重大危险源 ,因其一旦发生泄漏 ,引起火灾、爆炸意外事故 ,造成的伤亡及财产损失巨大 ,评价其安全性 ,控制其危险 ,建立防范及应急救援系统是控制工业灾害的重大举措。笔者通过建立数学模型对液化石油气贮罐区的危险性进行定量化评价 ,得出罐区的危险等级以及其现实危险性 ,为控制重大危险源 ,提供了一种有效的方法。     

框架结构爆破倒塌方向安全性探讨

目前框架结构定向爆破拆除常采用炸高差h来进行方向控制,可靠性较低,安全性较差,本文对这个问题的原因进行分析以引起注意。     

一起氧气瓶爆炸事故的技术分析

针对一起氧气瓶爆炸事故,进行了详细的实际调查,并以科学理论和数据为依据,进行了多角度的技术分析。     

火灾中硅酸盐水泥制品的膨胀爆炸与开裂

本文介绍了四川消防科研所自1972年以来开展的钢筋混凝土建筑构件和建筑材料耐火性能研究工作中关于硅酸盐水泥制品在火灾温度条件下膨胀、爆炸与开裂方面的实验研究情况。通过对有关各类以硅酸盐为重要成分的建筑构件和制品的反复试验研究与理论分析，初步掌握了一定程度的膨胀、爆炸以及开裂的物理、化学变化特征。着重指出了应用于建筑中的硅酸盐水泥制品－诸如混凝土构建或装修板材之类，它们的这些特性对建筑物的防火、灭火都有很大的威胁，应该对其产生的根本原因和预防对策进行更加深入的研究，以避免因制品的破坏而导致火灾蔓延和减少消防人员在扑救火灾过程中所造成的不必要的伤亡。     

瓦斯爆炸阻隔爆装置失效原因的实验研究

通过对水平管道内瓦斯爆炸的火焰结构及压力结构的实验研究 ,分析了瓦斯爆炸阻隔爆装置的失效原因。结果表明 ,瓦斯爆炸火焰是沿着管道的底部向前传播的 ,火焰长度较长 ,并具有较高的内聚力。阻隔爆装置的失效原因是由于其动作延迟时间与火焰到达装置位置所需的时间不一致 ,使释放出的抑制剂不能有效地覆盖整个火焰区 ,造成具有较高内聚力的火焰 ,在其后部巨大爆炸产物膨胀压力的推动下继续向前传播     

浅谈提高爆炸容器使用安全性的技术措施

针对爆炸容器工作时 ,产生的爆炸冲击波、破片、有害气体、振动及噪声等危害因素 ,简述了国内外使用爆炸容器时 ,采取的一些相关安全技术措施 ;提出了将结构健康监测技术应用于爆炸容器寿命安全评估的构想     

浮桶式乙炔器爆炸原因分析

指出了浮桶式乙炔器发生爆炸的 3种原因 ,提出从事该行业的人员应了解这些知识 ,以防止类似事故发生。     

Effects of hydrogen addition on the confined and vented explosion behavior of methane in air

Multi-component gas mixture explosion accidents occur and recur frequently, while the safety issues of multi-component gas mixture explosion for hydrogen–methane mixtures have rarely been addressed.Numerical simulation study on the confined and vented explosion characteristics of methane-hydrogen mixture in stoichiometric air was conducted both in the 5 L vessel and the 64 m³ chamber, involving different mixture compositions and initial pressures. Based on the results and analysis, it is shown that the addition of hydrogen has a negative effect on the explosion pressure of methane-hydrogen mixture at adiabatic condition. While in the vented explosion, the addition of the hydrogen has a significant positive effect on the explosion hazard degree. Additionally, the addition of hydrogen can induce a faster reactivity and enhance the sensitivity of the mixture by reducing the explosion time and increasing the rate of pressure rise both in confined and vented explosion. Both the maximum pressure and the maximum rate of pressure rise increase with initial pressure as a linear function, and also rise with the increase of hydrogen content in fuel. The increase in the maximum rate of pressure rise is slight when hydrogen ratio is lower than 0.5, however, it become significant when hydrogen ratio is higher than 0.5. The maximum rate of pressure rise for stoichiometric hydrogen-air is about 10 times the one of stoichiometric methane-air.Furthermore, the vent plays an important role to relief pressure, causing the decrease in explosion pressure and rate of pressure rise, while it can greatly enhance the flame speed, which will extend the hazard range and induce secondary fire damages. Additionally it appears that the addition of hydrogen has a significant increasing effect on the flame speed. The propagation of flame speed in confined explosion can be divided into two stages, increase stage and decrease stage, higher hydrogen content, higher slope. But in the vented explosion, the flame speed keeps increasing with the distance from the ignition point.     

Explosion parameters of wood chip-derived syngas in air

The wood gasification process poses serious concerns about the risk of explosion. The design of prevention and mitigation measures requires the knowledge of safety parameters, such as the maximum explosion pressure, the maximum rate of pressure rise and the gas deflagration index, K_G, at standard ambient temperature (25 °C) and pressure (1 bar) conditions. However, the analysis at specific process conditions is strongly recommended, as the explosion behavior of gas mixtures may be completely different.In the work presented in this paper, the explosion behavior of mixtures with composition representative of wood chip-derived syngas (CO/H₂/CH₄/CO₂/N₂ mixtures with and without H₂O) was experimentally studied in a closed combustion chamber. Experiments were run at two temperatures, 300 °C and 10 °C, and at atmospheric pressure. Test conditions were requested by the safety engineering designer of an existing industrial-scale wood gasification plant. In order to identify the specific fuel–air ratios to be analyzed, thus reducing the number of experimental tests, a preliminary thermo-kinetic study was performed.Results have shown that the mixtures investigated can be classified as low-reactivity mixtures, the higher value of K_G found (∼36 bar m/s) being much lower than the K_G value of methane (55 bar m/s @ 25 °C).     

Comparison of explosion parameters for Methane–Air mixture in different cylindrical flameproof enclosures

Flameproof enclosures having internal electrical components are generally used in classified hazardous areas such as underground coalmines, refineries and places where explosive gas atmosphere may be formed. Flameproof enclosure can withstand the pressure developed during an internal explosion of an explosive mixture due to electrical arc, spark or hot surface of internal electrical components. The internal electrical component of a flameproof enclosure can form ignition source and also work as an obstacle in the explosion wave propagation. The ignition source position and obstacle in a flameproof enclosure have significant effect on explosion pressure development and rate of explosion pressure rise. To study this effect three cylindrical flameproof enclosures with different diameters and heights are chosen to perform the experiment. The explosive mixture used for the experiment is stoichiometric composition of methane in air at normal atmospheric pressure and temperature.It is observed that the development of maximum explosion pressure (P_max) and maximum rate of explosion pressure rise (dp/dt)_ex in a cylindrical flameproof enclosure are influenced by the position of ignition source, presence of internal metal or non-metal obstacles (component). The severity index, K_G is also calculated for the cylindrical enclosures and found that it is influenced by position of ignition source as well as blockage ratios (BR) of the obstacles in the enclosures.