Experimental study on fire suppression performance of the high pressure water mist in the engine room of an offshore platform

The total flooding application water mist system is a new type of environmentally-friendly fixed extinguishing system. The optimizing design can improve its fire extinguishing performance. At present, the water mist fire extinguishing system in the engine room of the offshore deepwater semi-submersible support platform has not attracted sufficient attention. In this paper, the water mist in the engine room of a deepwater semi-submersible support platform was studied. It contains the effect of water mist on the heat absorption and oxygen insulation of diesel pool fires. The applicable parameters of the water mist fire extinguishing system were also determined. Moreover, based on the shielding of the fire source in the engine room and the different requirements for water mist extinguishing parameters, a hierarchical multi-parameter combined high-pressure water mist fire extinguishing system was proposed. In the full-scale experimental engine room model, according to the fire extinguishing experiments for diesel pool fires with different areas, this kind of hierarchical multi-parameter water mist system is very effective on shielded and non-shielded fires. In addition, it is still effective even in a non-closed environment coupled with smoke exhausting.     

Experimental and theoretical research on the inhibition performance of ethanol gasoline/air explosion by C6F12O

The safety issue of ethanol gasoline and the methods to control or weaken its explosion have attracted attention. To clarify the effect of C₆F₁₂O (perfluoro(2-methyl-3-pentanone)) on the explosion of ethanol gasoline-air mixtures and intrinsic mechanism, the explosion overpressure and flame propagation behavior under different equivalence ratios (φ = 0.6–0.8) and C₆F₁₂O concentrations (χ_inh = 0–4.0%) were experimentally obtained. The detailed inhibitor reaction process was also obtained by CHEMKIN based on a new assembly kinetic mechanism. The results show that the effects of C₆F₁₂O on the explosion characteristics of ethanol gasoline varied with χ_inh and φ. For rich flames, C₆F₁₂O is more effective than and heptafluoropropane (C₃HF₇) and nitrogen (N₂) in suppressing explosions; for lean and equivalence ratio flames, the addition of C₆F₁₂O may result in more severe explosions. The decrease in chemical reactivity is mainly because the mole fractions of OH and H radicals and the proportion of paths H radicals involved decrease after adding C₆F₁₂O, and R1500: CF₃COF + H = CF₃CO + HF, R965: CF₂:O + H = CF:O + HF, R863: CF₃ + H = CF₂ + HF are main suppressing reactions.     

Experimental investigation of the performance of modified expanded graphite powder doped with zinc borate in extinguishing sodium fires

Sodium is the main cooling medium in the circuit of fourth-generation nuclear reactors, and its leakage constitutes a severe fire hazard because of its high chemical activity. In this study, expandable graphite (EG), which is a traditional sodium fire-extinguishing agent, was modified with zinc borate (ZB) as an intercalator, and the modified EG_ZB was characterized. Moreover, the effectiveness of the modified EG_ZB in extinguishing sodium fires was tested using a self-developed fire-extinguishing experimental device. This study's results indicated that EG, EG_ZB had a smaller particle size, higher thermal stability, higher fire-extinguishing speed, and lower powder mass consumption than EG. During the fire-extinguishing process, ZnO decomposed by ZB captured free radicals and inhibited the combustion reaction. Furthermore, B₂O₃ was adsorbed on the surface of the EG layer, which strengthened covering and asphyxiation. The findings of this study provide crucial information for effectively controlling fires caused by active metals and metallo-organic compounds.     

Holocene fire history from the Greater Blue Mountains World Heritage Area, New South Wales, Australia: the climate, humans and fire nexus

This study presents a reconstruction of the fire activity of the last ~14,200 cal. years BP (before AD 1950) from Gooches Crater Right, located on the Newnes Plateau, approximately 150 km to the west of Sydney (~33°27′S, 150°16′E) within the Blue Mountains National Park. Charcoal analysis and palynology were undertaken with the aim of untangling any inter-relationship between climate, humans and fire. A chronology of the site was provided by radiocarbon dating. The dominant control on fire in this environment during the Holocene appears to be climate. Periods of climate change, identified in previous studies, are associated with higher levels of fire activity. Fire was less ubiquitous between ~9,000 and 6,000 years BP, a period normally described as having a higher effective moisture in south-eastern Australia. The mid-Holocene fluctuations in charcoal may reflect anthropogenic fire, climate forcing or alternatively human responses to any climate change. Coeval changes in palaeoclimatic sequences elsewhere and palynology at the site support a climatic explanation or that Aboriginal people used fire within a climatic framework.     

磷酸铵盐亚纳米粉体灭火性能实验研究

使用溶剂-非溶剂法制备了粒径达到亚纳米量级（300nm-500mm）的磷酸铵盐灭火剂,建立了1．2m×1．2m×1．2m的小尺度灭火实验平台,开展了灭油池火和木垛火的全淹没灭火实验,对磷酸铵盐亚纳米粉体的灭火性能进行了研究,并与普通磷酸铵盐粉体的灭火性能进行了比较。实验结果显示磷酸铵盐亚纳米粉体的灭火性能要明显高于普通粉体,并且在低压下就可以获得很好的灭火果。工作压力的增加会缩短粉体的灭火时间,但是对于磷酸铵盐亚纳米粉体灭木垛火的情况,由于灭火时间相差示大,反而会导致灭火剂用量增加。     

火灾下匀质防火保护钢构件温度计算(Ⅰ):理论与公式

介绍了火灾下有匀质防火层保护的钢构件温度计算的一维传热模型。给出了求解该模型的相关边界条件和假定,并给出求解该一维传热模型在不同边界条件下的解。通过分析三种典型防火材料保护下、截面系数不同的三种截面的升温,比较了由我国规范CECS200、欧洲规范、欧钢协标准、美国规范及其他学者推荐的方法得到的结果,并对照有限元结果,考察了不同计算方法的有效性。结果表明,CECS200与国外规范给出的结果符合良好且略微偏高。通过计算典型截面在不同耐火极限要求下的最小保护层厚度,比较了各国规范的设计结果。结果显示,由不同规范推荐的公式计算得到的最小保护层厚度相差不大。CECS200计算的最小保护层厚度与国外规范一致,与欧洲规范得到的结果基本相同。研究表明,在标准火灾环境中我国规范给出的方法合理有效且形式简单便于工程运用。     

Numerical simulation of small-scale pool fires of LNG

Liquefied natural gas (LNG) has been largely indicated as a promising alternative solution for the transportation and storage of natural gas. In the case of accidental release on the ground, a pool fire scenario may occur. Despite the relevance of this accident, due to its likelihood and potential to trigger domino effects, accurate analyses addressing the characterization of pool fires of LNG are still missing.In this work, the fire dynamic simulator (FDS) has been adopted for the evaluation of the effects of the released amount of fuel and its composition (methane, ethane, and propane), on the thermal and chemical properties of small-scale LNG pool fire. More specifically, the heat release rate, the burning rate, the flame height, and thermal radiation, at different initial conditions, have been evaluated for pool having diameter smaller than 10 m. Safety distances have been calculated for all the investigated conditions, as well.Results have also been compared with data and correlations retrieved from the current literature. The equation of Thomas seems to work properly for the definition of the height over diameter ratio of the LNG pool fire for all the mixture and the investigated diameters.The addition of ethane and propane significantly affects the obtained results, especially in terms of radiative thermal radiation peaks, thus indicating the inadequacy of the commonly adopted assumption of pure methane as single, surrogate species for the LNG mixture.     

Effect of admixture of solid inertant on fire hazard of dust layers oriented at varying degrees of inclination

Unlike metallic dust layers, the layer flammability levels (LFL) of non-metallic dust layers exhibit a wide range from Class 1 (No self-sustained combustion) to Class 6 (explosive combustion). However, determinations of layer flammability have not considered the effect of inclination angle, thereby potentially underestimating fire hazard of combustible dust layers in many industrial situations. In this research, inclined dust layers showed greater fire hazard than did horizontally oriented dust layers. For example, LFL of wood dust jumped from class 3 to class 5 when layers were positioned with an incline. Flame spread rate of PMMA dust layers increased from 1.8 to 3.6 mm/s when the angle of inclination increased from 0 to 40°. Even small amounts of solid inertant significantly decreased surface layer fires. The required amount of inertant to completely inert layer fires was far less than that for smoldering layer fires or dust explosions.     

氯化钠/纳米疏水二氧化硅超细干粉制备及灭火性能研究

选用氯化钠为基体制备金属火灾超细干粉灭火剂。应用反溶剂法对其改性,使纳米疏水二氧化硅吸附在氯化钠晶体表面,其中分散剂为PEG-1000。结果表明,纳米疏水二氧化硅的添加有利于细化氯化钠颗粒,但过量的添加会起反作用,最佳用量为3 wt%左右,平均粒径为2.18μm。镁片灭火实验证明超细复合干粉的灭火性能明显好于传统氯化钠灭火剂(商用D类灭火剂),纳米疏水二氧化硅最佳添加量为3 wt%,此时灭火时间仅需传统灭火剂的一半。最后利用FDS5.0模拟干粉颗粒与燃烧火焰作用过程,模拟结果表明干粉覆盖对火焰具有一定的抑制效果,并分析了复合干粉灭火机理。     

基于层次分析法的热塑性聚氨酯及其纳米复合材料火灾危险性综合评价

聚合物的火灾危险性与热、烟、毒的释放密切相关,但采用不同指标对材料的评价结果不一致。以纳米级蒙脱土(MMT)、氢氧化铝(ATH)和聚磷酸铵(APP)为添加剂的热塑性聚氨酯(TPU)纳米复合材料为研究对象,选取其在静态管式炉、稳态管式炉和锥形量热仪中的相关实验数据,以HCN总浓度作为特殊毒性危害指标,CO和CO_2浓度为一般毒性危害指标,以热释放速率峰值、平均热释放速率、总热释放量为热危害指标,以产烟速率峰值、生烟总量为烟危害指标。进一步细分了火灾烟气中不同毒性气体对于火灾风险的影响,并运用层次分析法计算指标权重,综合评价了热塑性聚氨酯及其复合材料的火灾危险性。结果表明,当添加量为6 wt%聚磷酸铵、3 wt%氢氧化铝与3 wt%蒙脱土时,此时复合材料的火灾危险最低,证明了综合热、烟、毒三个层次来降低聚合物材料火灾危险性是可行的。