DPD分光光度法测定水质中余氯的方法研究

采用行业标准DPD分光光度法(HJ 568-2010)测定水中的游离余氯,验证了去掉第一点的低浓度曲线的有效性。分别比较不同的显色时间对吸光度的影响,结果表明显色时间应控制在10min以内。     

Characterization of primary precipitate composition formed during co-removal of Cr(VI) with Cu(II) in synthetic wastewater

BACKGROUND, AIMS AND SCOPE: Hexavalent chromium [Cr(VI)] cannot react with either carbonate or hydroxide to form chromium precipitates. However, by using a precipitation technology to treat plating wastewater containing Cr(VI), Cu(II), Ni(II) and Zn(II), approximately 78% of Cr(VI) (initial 60 mg/L) was co-removed with the precipitation of Cu(II), Ni(II) and Zn(II) (each 150 mg/L) by dosing with Na2CO3 (Sun 2003). Direct precipitation by forming Cu(II)-Cr(VI) precipitates followed by adsorption of Cr(VI) onto freshly formed Cu-precipitates was subsequently found to be the main mechanism(s) involved in Cr(VI) co-removal with Cu(II) precipitation by dosing Na2CO3 stepwise to various pH values (Sun et al. 2003). This study was. carried out to further characterize the formation of primary precipitates during the early stages of copper precipitation and simultaneous removal of Cr(VI) with Cu(II). METHODS: Test metal-solutions were prepared with industrial grade chemicals: CuCl2 x 2H2O, Na2SO4 and K2Cr2207. NaCO3 was added drop-wise to synthetic metal-solution to progressively increase pH. For each pH increment, removal of soluble metals was detected by atomic absorption spectrophotometer (AAS) and surface morphology of precipitates was analyzed by scanning electron microscope (SEM). To further characterize the formation of primary precipitates, a series of MINEQL+ thermodynamic calculations/analyses and equilibrium calculations/ analyses were conducted. RESULTS AND DISCUSSION: MINEQL+ thermodynamic calculation indicated that, for a system containing 150 mg/L Cu(II) and 60 mg/L Cr(VI) with gradual Na2CO3 dosing, if any precipitates can be formed at pH 5.0 or lower, it should be in the form of CuCrO4. Comparison tests using systems containing the same equivalent of Cu(II) plus Cr(VI) and Cu(II) plus SO4(2-) showed that the precipitation occurred at a pH of around 5.0 in the Cu(II)-Cr(VI) system and around 6.0 in the Cu(II)-SO4(2-) system. The discrepancy of the precipitation was indeed caused by the formation of Cu-Cr precipitates. The initiation of copper removal at pH around 5.0 for the Cu-Cr co-removal test was not attributable to the formation of Cu-CO3 precipitates, instead, it was most likely through the formation of insoluble Cu-Cr precipitates, such as CuCrO4 and CuCrO4 x 2Cu(OH)2. Experimental tests, equilibrium calculations, MINEQL+ thermodynamic calculations and surface morphologies for systems using higher concentrations of Cu(II) and Cr(VI) further verified the most probable composition of primary precipitates is copper-chromate. CONCLUSION: In the Cu-Cr co-removal test with Na2O3 dosing to increase pH and induce metal precipitation, copper-chromate precipitates are the primary precipitates produced and contribute to the initial simultaneous removal of copper and chromium.     

山东省经济发展与环境保护关系的计量分析

经济增长与环境污染之间的关系常用环境库兹涅茨曲线（EKC）来描述。典型的EKC一般量倒U形。本文选取1988-2002年的山东省环境与经济数据．建立单位GDP污染排放量横型和人均GDP污染排放量模型,对山东省经济发展与环境保护之间的关系进行了计量与分析。通过单位GDP污染负荷模型分析发现。单位GDP的污染负荷量下降态势。这说明山东省产业结构调整已产生明显成效。通过人均GDP污染排放量模型发现．山东省的EKC不完全符合典型的库兹涅茨曲线特征。呈显着的三次曲线特点。其中,工业废水曲线为“U＋倒U”形．两个转折点的理论计算值分别为3416元和9975元。废气与固废曲线近似于倒U形EKC的左半部分．尚来到达转折点。由此可见．环境质量的改善并非随着收入水平的提高而自动发生。除了收入因素。影响山东省EKC的因素还有国家或地区的环境政策、工业化进程等。     

IEC 61373两个版本标准的振动试验量级对比分析

通过对IEC 61373-1999与IEC 61373-2010铁路应用机车车辆设备冲击和振动试验试验标准的比较,主要分析了振动试验中的模拟长寿命试验的量级变化。两种版本振动试验量级变化的原因是标准中采用的S-N模型发生变化,从而导致计算加速度比的方法有所改变。     

ANALYSIS AND EXTRACTION OF LOW FLOW RECESSION CHARACTERISTICS1

ABSTRACT: It is important to extract and assess low flow recession characteristics for water resources planning in the upper reaches of streams. However, it is very difficult to express synthetically the low flow recession characteristics for a stream flow. In this paper, first a new method of constructing the master recession curve based on the exponential expression is proposed and applied with the restriction that there are no regulation or diversion structures in the upper reaches above the measurement station. Daily precipitation and stream flow were used for the analysis. Second, analysis for a recession constant was conducted and the relationship between the recession constant and low flow and/or geology was qualitatively examined. In conclusion, the application of the proposed method indicated that it is objective and useful for constructing the master recession curve. It became apparent that the recession constant of a master recession curve may be defined as the total index of low flow characteristics. In addition, it was found that baseflow value increases in the order of Paleozoic, Mesozoic, Tertiary, and Quaternary.     

SCS URBAN CURVE NUMBERS FROM A LANDSAT DATA BASE1

Estimating the Curve Numbers used in the Soil Conservation Service hydrologic models is a tedious and costly task. Recent advances in remote sensing and data processing have led to the development of readily available land cover data bases for many areas of the United States. This study evaluated the potential of using a Landsat data base to make the Curve Number estimation process more cost-effective and less tedious. Ten watersheds in the Washington, D.C., area were evaluated using a Landsat land cover data base developed by the U.S. Geological Survey. Results showed that these data can be useful. Predictions can be improved if ancillary data on residential lot size are included. It was concluded that this type of data base must be examined carefully before implementation.     

STORM RUNOFF PREDICTION BASED ON A SPATIALLY DISTRIBUTED TRAVEL TIME METHOD UTILIZING REMOTE SENSING AND GIS1

ABSTRACT: In this study, remotely sensed data and geographic information system (GIS) tools were used to estimate storm runoff response for Simms Creek watershed in the Etonia basin in northeast Florida. Land cover information from digital orthophoto quarter quadrangles (DOQQ), and enhanced thematic mapper plus (ETM+) were analyzed for the years 1990, 1995, and 2000. The corresponding infiltration excess runoff response of the study area was estimated using the U.S. Department of Agriculture (USDA), Natural Resources Conservation Service Curve Number (NRCS‐CN) method. A digital elevation model (DEM)/GIS technique was developed to predict stream response to runoff events based on the travel time from each grid cell to the watershed outlet. A comparison of predicted to observed stream response shows that the model predicts the total runoff volume with an efficiency of 0.98, the peak flow rate at an efficiency of 0.85, and the full direct runoff hydrograph with an average efficiency of 0.65. The DEM/GIS travel time model can be used to predict the runoff response of ungaged watersheds and is useful for predicting runoff hydrographs resulting from proposed large scale changes in the land use.     

纳氏试剂光度法测定废水中氨氮的问题讨论

应用纳氏试剂比色法测定废水中的氨氮时,水样显色后稳定时间短,影响测定结果的准确性,针对这一问题进行了实验研究。实验中对主要影响因素Ｉ－和ＯＨ－的浓度变化进行了条件实验,结果表明选用所配的Ⅲ型纳氏试剂（ＫＩ含量为７．５ｇ）,可获得稳定的有色胶体,也可采用Ⅰ型纳氏试剂（ＫＩ含量为７．０ｇ）、在中和硼酸后再多加２ｍＬＮａＯＨ（１ｍｏｌ／Ｌ）,也可获得稳定的有色胶体。     

EVALUATION OF CURVE NUMBER PROCEDURES TO PREDICT RUNOFF IN GLEAMS1

ABSTRACT: Proper selection of curve number values will improve the capability of the SCS-Curve Number procedure in predicting runoff. Both CREAMS and GLEAMS models use the Smith and Williams (1980) approach of converting CNII (curve number value for average antecedent moisture conditions) into CNI (curve number value for dry antecedent moisture conditions) in calculating the soil retention parameter (S). CREAMS and GLEAMS have been found to under predict runoff because of the internal conversion of CNII to CNI. This study shows modifications of the GLEAMS model using CMI without converting it to CM and it also shows the seasonal curve number approaches with and without converting CNII to CNI. Results indicate that using CNII without internal conversion to CNI provides better runoff and erosion predictions than the original version of GLEAMS and versions with seasonal curve numbers when tested with four years of field data in the Coastal Plain physiographic region of Maryland.     

ASSESSMENT OF REMOTE SENSING INPUT TO HYDROLOGIC MODELS1

Remotely sensed variables such as land cover type and snow-cover extent can currently be used directly and effectively in a few specific hydrologic models. Regression models can also be developed using physiographic and snow-cover data to permit estimation of discharge characteristics over extended periods such as a season or year. Most models, however, are not of an appropriate design to readily accept as input the various types of remote sensing parameters that can be obtained now or in the future. Because this new technology has the potential for producing hydrologic data that has significant information content on an areal basis, both inexpensively and repetitively, effort should be devoted now to either modifying existing models or developing new models that can use these data. Minor modifications would at least allow the remote sensing data to be used in an ancillary way to update the model state variables, whereas major structural modifications or new models would permit direct input of the data through remote sensing compatible algorithms. Although current remote sensing inputs to hydrologic models employ only visible and near infrared data, model modification or development should accommodate microwave and thermal infrared data that will be more widely available in the future.