全文获取类型
收费全文 | 198篇 |
免费 | 10篇 |
国内免费 | 48篇 |
专业分类
安全科学 | 9篇 |
废物处理 | 3篇 |
环保管理 | 10篇 |
综合类 | 96篇 |
基础理论 | 41篇 |
污染及防治 | 41篇 |
评价与监测 | 55篇 |
社会与环境 | 1篇 |
出版年
2022年 | 5篇 |
2021年 | 5篇 |
2020年 | 10篇 |
2019年 | 4篇 |
2018年 | 7篇 |
2017年 | 8篇 |
2016年 | 18篇 |
2015年 | 12篇 |
2014年 | 9篇 |
2013年 | 28篇 |
2012年 | 25篇 |
2011年 | 24篇 |
2010年 | 16篇 |
2009年 | 26篇 |
2008年 | 7篇 |
2007年 | 7篇 |
2006年 | 6篇 |
2005年 | 4篇 |
2004年 | 9篇 |
2003年 | 5篇 |
2002年 | 1篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有256条查询结果,搜索用时 399 毫秒
231.
232.
以管龄为11年的城市主供水管道上的DN300球墨铸铁管为研究对象,采用扫描电镜(SEM)、能谱分析(EDS)、晶体衍射结构分析(XRD)等手段对其径向不同位置的管垢进行了表征,并分析了其各类金属与有机污染物的分布差异.结果表明:管道下部的管垢总量高,平均粒径大.重金属在空间上的分布明显不同,铁、锰、锌、铅、铜和铬在上部的管垢中含量最高,而下部管垢中,铝的含量最高,该分布与管垢中其来源密切相关.管垢中累积了多种的有机污染物,除了微生物代谢形成的烃类物质之外,还累积了藻类的代谢产物及外源有机污染物,不同位置上出现的有机污染物类型也有所差异.该研究结果对将来饮用水管网生物化学安全的研究方法提出了更高的要求,并为管网的饮用水安全保障提供了理论依据. 相似文献
233.
为测定水节霉发生地河水中ρ(SVOCs)(SVOCs为半挥发性有机物),比较了LLE(液液萃取)和SPE(固相萃取)前处理法提取加标空白水样中ρ(SVOCs)的GC-MS/SIM测定结果,确定并采用重现性好的SPE-GC-MS/SIM法测定了水节霉发生地河水中的ρ(SVOCs). 结果表明,LLE和SPE法对SVOCs的加标回收率分别为41.8%~121.5%和31.5%~124.4%,相对标准偏差分别为6.0%~18.0%和0.9%~14.5%,二者回收率相差不大,但SPE法的相对标准偏差小于LLE法,SPE法重现性较好,因此采用SPE-GC-MS/SIM法测定2011年2月水节霉发生地河水中的ρ(SVOCs),共检出29种SVOCs,其中ρ(邻苯二甲酸二乙酯)、ρ(∑PAHs)、ρ(硝基苯)、ρ(1,2-二氯苯)和ρ(1,4-二氯苯)分别为1 020.59、532.14、43.39、38.52和19.57 ng/L,均未超出GB 5749—2006《生活饮用水卫生标准》相关限值,表明水节霉发生地未发生SVOCs污染. 相似文献
234.
土壤残留氯磺隆和镉联合胁迫对菠菜代谢产物的影响 总被引:1,自引:0,他引:1
通过盆栽试验,评价土壤长残效期除草剂氯磺隆与重金属镉单一污染及复合污染对后茬作物菠菜生长、代谢产物的影响。基于GC-MS技术对3个不同处理组菠菜的代谢产物进行了辨识和分析。主成分分析结果表明,3个处理组的代谢物含量存在显著差异。具体表现为:1)与空白对照相比,氯磺隆诱导菠菜多种氨基酸、与能量代谢相关的3种糖类物质、苹果酸、γ-氨基丁酸、乳酸和腐胺的含量显著上升(*P0.05);肌醇显著下降(*P0.05);镉诱导菠菜多种氨基酸、与能量代谢相关的5种糖类物质、参与三羧酸循环的苹果酸和柠檬酸含量显著上升(*P0.05);肌醇和腐胺含量显著下降(*P0.05)。2)与单一污染相比较,复合污染诱导菠菜多种氨基酸,多种糖类物质和苹果酸等含量显著下降(*P0.05)。由此可见,复合污染减弱了氯磺隆和镉单一污染时对氨基酸代谢和能量代谢的上调作用;氯磺隆和镉之间没有协同作用,相反对某些特定的代谢物存在拮抗作用。 相似文献
235.
Cattle treatment with antiparasitic drugs is associated with an important risk exposure for dung beetles. Previous studies demonstrated the impact of some avermectin and pyrethroid compounds on several species such as Onthophagus gazella and Neomyia cornicina. However, little information is available regarding the elimination of these compounds in faeces 8 days after a pour-on administration in dairy cows. The present study, utilising a dairy cow model with cypermethrin treatment, demonstrated that concentrations in dry faeces can reach levels of 5?mg?kg?1 between the first and fourth day after treatment and were present up to 3 months after a single dose of administration at a concentration around 10?µg?kg?1. Faecal samples were purified with three successive columns (silica gel, anion exchange phase, and basic alumina) and analysed by GC-MS. The limit of quantification of this method was 0.5?µg?kg?1. The high sensitivity of the method permitted one to see that the risk exposure of cypermethrin to dung beetles is longer than what was noted in the literature. According to other studies, repeated treatment with such agents may lead to the local extinction of dung beetles. Even if the impact of pyrethroid largely depends on the conditions of the ecosystem where the treated cattle are living, adverse effects of these agents may still occur. 相似文献
236.
237.
Summary. Summary. Oilseed rape, Brassica napus L. (cv Express),
plants were grown under three different sulphur regimes:
sulphur-free (S0), normal sulphur (Sn, normal field concentration)
and a sulphur-rich (S+, 2 × concentration of Sn). We
performed dual choice oviposition assays with the diamondback
moth, Plutella xylostella, using real plants and,
for the first time with this insect, artificial leaves sprayed
with methanolic leaf-surface extracts. The results mirrored
those of a separate study of preferences for whole plants.
Females laid more eggs on surrogate leaves that were
treated with Sn extracts than on S0 plants, while only a
slight, not significant, difference was observed between
extracts of normal and sulphur-rich plants. This shows
that chemical compounds on the leaf surface mediate the
oviposition preference and that the female insect can
perceive the quality of the host-plants in terms of their
fertilisation status.Since leaf volatiles are known to be oviposition stimulants,
we investigated the effects of leaf-surface extracts on
insect olfactory responses using electroantennograms
(EAGs). In agreement with the behavioural data, we found
that extracts of sulphur-treated plants yielded higher EAG
amplitudes than the S0 extracts. Since the leaf content of the
volatiles isothiocyanates is influenced by sulphur nutrition,
we analysed the extracts for these compounds. Above the
detection threshold of our GC-MS system, no isothiocyanates
were found. Thus, other compounds present in the
surface extracts must be perceived by the antenna.However, the HPLC analysis revealed 11 different
glucosinolates. Progoitrin (2-Hydroxy-3-butenyl) and
gluconapoleiferin (2-Hydroxy-4-pentenyl), which belong to
the hydroxy-alkene class of glucosinolates, were the most
abundant compounds. The total glucosinolate content
sharply increased from S0 to Sn plants, whereas it was slightly
lower in n versus S+ plants. Since it is known that glucosinolates
can stimulate oviposition, it seems likely that the
increased content we observed was influencing the insect
preference in this study too. 相似文献
238.
为了研究层燃炉块煤热解时有机气体的析出规律,在自行设计的可移动式-固定床上对神木煤进行了热解实验,煤颗粒尺寸为3~5mm;热解气在炉膛内的停留时间为1.76s,热解温度分别为1100K、1400K和1600K;采用气相色谱质谱联用仪(GC-MS)测试分析了热解气中有机气体的析出规律;离线测试热解气体试样。研究结果显示:随着热解温度的升高,热解气中饱和脂肪烃含量降低,其中2-甲基戊烷和2,2,3-三甲基丁烷降低幅度分别为83.29%和59.66%;芳香烃含量升高,其中甲苯浓度增加了8倍。随着热解温度的升高,热解气CH组分中,碳含量增大,氢含量减小;热解气中的部分饱和脂肪烃经历浓缩、环化和析氢过程形成芳香烃。 相似文献
239.
240.