气体反溶剂(GAS)过程细化技术及对炸药安全性能的影响研究

介绍了气体反溶剂 (GAS)过程细化技术原理及影响细化结果的主要因素 ,并从理论和实验角度分析了炸药重结晶细化处理后 ,对撞击感度和冲击波感度的影响 ;结果表明 ,GAS过程不仅可以有效地控制炸药颗粒的粒度、粒度分布、晶形 ,而且可以有效降低炸药撞击感度和冲击波感度 ,改善炸药安全性能     

Effects of a carbon monoxide-dominant gas mixture on the explosion and flame propagation behaviors of methane in air

This work aimed to experimentally evaluate the effects of a carbon monoxide-dominant gas mixture on the explosion characteristics of methane in air and report the results of an experimental study on explosion pressure measurement in closed vessel deflagration for a carbon monoxide-dominant gas mixture over its entire flammable range. Experiments were performed in a 20-L spherical explosion tank with a quartz glass window 110 mm in diameter using an electric spark (1 J) as the ignition source. All experiments were conducted at room temperature and at ambient pressure, with a relative humidity ranging from 52 to 73%. The peak explosion pressure (P_max), maximum pressure rise rate ((dp/dt)_max), and gas deflagration index (K_G) were observed and analyzed. The flame propagation behavior in the initial stage was recorded using a high-speed camera. The spherical outward flame front was determined on the basis of a canny method, from which the maximum flame propagation speed (S_n) was calculated. The results indicated that the existence of the mixture had a significant effect on the flame propagation of CH₄-air and increased its explosion risk. As the volume fraction of the mixed gas increases, the P_max, (dp/dt)_max, K_G and S_n of the fuel-lean CH₄-air mixture (7% CH₄-air mixture) increase nonlinearly. In contrast, addition of the mixed gas negatively affected the fuel-rich mixture (11% CH₄-air mixture), exhibiting a decreasing trend. Under stoichiometric conditions (9.5% CH₄-air mixture), the mixed gas slightly lowered P_max, (dp/dt)_max, K_G, and S_n. The P_max of CH₄-air mixtures at volume fractions of 7%, 9.5%, and 11% were 5.4, 6.9, and 6.8 bar, respectively. The S_n of CH₄-air mixtures at volume fractions of 7%, 9.5%, and 11% were 1.2 m/s, 2.0 m/s, and 1.8 m/s, respectively. The outcome of the study is comprehensive data that quantify the dependency of explosion severity parameters on the gas concentration. In the storage and transportation of flammable gases, the information is required to quantify the potential severity of an explosion, design vessels able to withstand an explosion and design explosion safety measures for installations handling this gas.     

Dynamic failure probability analysis of urban gas pipeline network

The gas pipeline network is an essential infrastructure for a smart city. It provides a much-needed energy source; however, it poses a significant risk to the community. Effective risk management assists in maintaining the operational safety of the network. The risk management of the network requires reliable dynamic failure probability analysis. This paper proposes a methodology of condition monitoring and dynamic failure probability analysis of urban gas pipeline network. The methodology begins with identifying key design and operational factors responsible for pipeline failure. Subsequently, a causation-based failure model is developed as the Bowtie model. The Bowtie model is transformed into a Bayesian network, which is analyzed using operational data. The key contributory factors of accident causation are monitored. The monitored data is used to analyze the updated failure probability of the network. The gas pipeline network's dynamic failure probability is combined with the potential consequences to assess the risk. The application of the approach is demonstrated in a section of the urban gas pipeline.     

Prediction of distance to maximum intensity of turbulence generated by grid plate obstacles in explosion-induced flows

The interaction of unburnt gas flow induced in an explosion with an obstacle results in the production of turbulence downstream of the obstacle and the acceleration of the flame when it reaches this turbulence. Currently, there are inadequate experimental measurements of these turbulent flows in gas explosions due to transient nature of explosion flows and the connected harsh conditions. Hence, majority of measurements of turbulent properties downstream of obstacles are done using steady-state flows rather than transient flows. Consequently, an empirical based correlation to predict distance to maximum intensity of turbulence downstream of an obstacle in an explosion-induced flow using the available steady state experiments was developed in this study. The correlation would serve as a prerequisite for determining an optimum spacing between obstacles thereby determining worst case gas explosions overpressure and flame speeds. Using a limited experimental work on systematic study of obstacle spacing, the correlation was validated against 13 different test conditions. A ratio of the optimum spacing from the experiment, x_exp to the predicted optimum spacing, x_pred for all the tests was between 2-4. This shows that a factor of three higher than the x_pred would be required to produce optimum obstacle spacing that will lead to maximum explosion severity. In planning the layout of new installations, it is appropriate to identify the relevant worst case obstacle separation in order to avoid it. In assessing the risk to existing installations and taking appropriate mitigation measures it is important to evaluate such risk on the basis of a clear understanding of the effects of separation distance and congestion. It is therefore suggested that the various new correlations obtained from this work be subjected to further rigorous validation from relevant experimental data prior to been applied as design tools.     

The study of a method of regional environmental risk assessment

Regional environmental risk assessment can be defined as risk assessment which deals with a spatial scale that contains multiple habitats with multiple sources of many stressors affecting multiple endpoints. The characteristics of the landscape also affect the estimated risk. In this paper, an information diffusion method based on a grid system is proposed to assess regional environmental risk. The risk information on a single environmental risk source can be diffused effectively by using fuzzy set theory. Regional environmental risk values obtained from information diffusion can be clustered on classification criteria and different environmental risk levels can be depicted in a spatial partition map. Huangge Town and Nansha Town located in the Nansha Area of Guangzhou City in China were selected as model cases. The results derived from this information diffusion method will help the local government to optimize the distribution of industrial areas and establish risk prevention measurements and emergency management procedures.     

An adsorption diffusion model for removal of para-chlorophenol by activated carbon derived from bituminous coal

Batch adsorption experiments were carried out to study the adsorptive removal and diffusion mechanism of para-chlorophenol (p-CP) onto Calgon Filtrasorb 400 (F400) activated carbon. The external mass transfer resistance is negligible in the adsorption process carried out under different conditions in batch operation. Intraparticle diffusion model plots were used to correlate the batch p-CP adsorption data; three distinct linear sections were obtained for every batch operation. The textural properties of F400 activated carbon showed that it has a large portion of supermicropores, which is comparable to the size of the p-CP molecules. Due to the stronger interactions between p-CP molecules and F400 micropores, p-CP molecules predominantly diffused and occupied active sites in micropore region by hopping mechanism, and eventually followed by a slow filling of mesopores and micropores. This hypothesis is proven by the excellent agreement of the intraparticle diffusion model plots and the textural properties of F400 activated carbon.     

受限空间中CO与水蒸汽阻尼瓦斯爆炸的反应动力学模拟研究

为了探求一氧化碳与水蒸汽参与瓦斯爆炸的化学反应动力学过程的阻尼效应,建立了受限空间中瓦斯爆炸反应的数学模型。数值计算结果表明,结果表明在瓦斯爆炸过程中,瓦斯-空气混合气体含有10%的一氧化碳,虽然会延迟瓦斯爆炸时间,抑制瓦斯爆炸,但是H、O自由基浓度、瓦斯爆炸温度和压力比不加入一氧化碳时升高,同时对CO2、NO的生成起促进作用;当混合气体中含有10%的水蒸汽时,H、O自由基浓度降低,瓦斯爆炸温度和压力也随之降低,致灾性气体CO2、NO的生成得到抑制。虽然一氧化碳对瓦斯爆炸有一定的阻尼效应,但是由于一氧化碳对部分致灾性气体的生成有促进作用,因此,在阻尼瓦斯爆炸方面,水蒸汽的效果要好于一氧化碳。     

机场周边大气中非甲烷总烃时空分布特征

为了研究机场周边大气中非甲烷烃的污染情况,于2011年4月21日起连续5天对某机场起降点附近2个采样点以及对照点农田区的大气中NMHCs进行测定.结果表明,NMHCs的含量为飞机开始滑行点（3.22mg/m3）＞降落点（2.92mg/m3）＞农田区（2.91 mg/m3）,均超出以色列的标准（2.0mg/m3）.非甲烷总烃在一天中下午16点达到最小值.飞机的起降对周边大气NMHCs排放有一定的影响.而对照点农田排放可能是当地NMHCs排放的重要来源. 3个采样点中,排放的碳氢化合物以非甲烷烃为主,占总烃的63.4％.NMHCs和总烃的线性关系良好,用统计回归的方法得到了研究区总烃和非甲烷烃的换算公式.     

横向风作用下喷口间距对射流扩散火焰特征的影响研究*

为研究横向风作用下喷口间距对射流扩散火焰特征的影响,以双喷口火焰为研究对象,利用CCD摄像机拍摄火焰几何形态,研究横向风条件下喷口间距对火焰形态演化、火焰长度和火焰吹熄极限的影响。研究结果表明:喷口间距较小时,2束火焰因空气夹带竞争和压差作用,彼此相互倾斜融合,火焰融合概率随喷口间距增加而逐渐降低,火焰临界融合间距随横向风的增加先增大后减小;由于火焰的空气夹带和热反馈处于较高水平,2束火焰被少量拉伸,火焰长度先增加后减小;喷口间距较小时,火焰吹熄极限显著增加。     

Apparent diffusion coefficients and chemical species of neptunium (V) in compacted Na-montmorillonite

Diffusion of neptunium (V) in compacted Na-montmorillonite was studied through the non-steady state diffusion method. In this study, two experimental attempts were carried out to understand the diffusion mechanism of neptunium. One was to establish the diffusion activation energy, which was then used to determine the diffusion process in the montmorillonite. The other was the measurement of the distribution of neptunium in the montmorillonite by a sequential batch extraction. The apparent diffusion coefficients of neptunium in the montmorillonite at a dry density of 1.0 Mg m-3 were from 3.7 x 10(-12) m2 s-1 at 288 K to 9.2 x 10(-12) m2 s-1 at 323 K. At a dry density of 1.6 Mg m-3, the apparent diffusion coefficients ranged between 1.5 x 10(-13) m2 s-1 at 288 K and 8.7 x 10(-13) m2 s-1 at 323 K. The activation energy for the diffusion of neptunium at a dry density of 1.0 Mg m-3 was 17.5 +/- 1.9 kJ mol-1. This value is similar to those reported for diffusion of other ions in free water, e.g., 18.4 and 17.4 kJ mol-1 for Na+ and Cl-, respectively. At a dry density of 1.6 Mg.m-3, the activation energy was 39.8 +/- 1.9 kJ mol-1. The change in the activation energy suggests that the diffusion process changes depending on the dry density of the compacted montmorillonite. A characteristic distribution profile was obtained by the sequential extraction procedure for neptunium diffused in compacted montmorillonite. The estimated fraction of neptunium in the pore water was between 3% and 11% at a dry density of 1.6 Mg m-3 and at a temperature of 313 K. The major fraction of the neptunium in the montmorillonite was identified as neptunyl ions sorbed on the outer surface of the montmorillonite. These findings suggested that the activation energy for diffusion and the distribution profile of the involved nuclides could become powerful parameters in understanding the diffusion mechanism.