改性竹炭颗粒对水溶液中孔雀绿的吸附动力学研究

用不同的酸碱溶液处理竹炭,研究改性竹炭颗粒对水溶液中孔雀绿的吸附效果,再对筛选出的竹炭颗粒进行吸附动力学试验,并用准二级动力学模型和颗粒扩散模型对试验数据进行拟合,在此基础上进一步探讨影响吸附过程的因素。试验结果表明,用0.5 mol.L-1NaOH溶液处理过的竹炭颗粒吸附效果最佳,最大吸附量可达9.96 mg.g-1。颗粒扩散模型能更好地描述吸附动力学过程。竹炭颗粒的质量增加会降低孔雀绿分子的扩散速率;孔雀绿溶液的初始浓度增加则提高孔雀绿分子的扩散速率;颗粒直径、搅拌速度以及溶液的初始pH值也会影响吸附过程。     

环境与经济形势的景气分析研究

为了识别社会经济发展对环境的影响,借鉴宏观经济景气分析的方法,构建了环境与经济形势景气分析框架.在识别影响环境发展态势的主要社会经济要素的基础上,构建环境与经济景气分析指标体系,并划分出针对污染物排放的先行和一致性指标,同时对其进行景气指数分析,预测预警未来环境的发展态势.应用该方法对全国大气环境SO2排放展开景气分析.2008年大气环境景气分析一致扩散指数为71.43,处于景气区间;合成指数为99.53,相对于2002年总体上呈下降趋势;社会经济发展对环境呈景气影响.但是先行扩散指数跌至不景气区间,部分指标出现环境不景气的变化趋势,会影响未来SO2减排.因此,需要进一步关注各预警指标的景气动向,通过控制重污染行业的产值比重及固定资产投资增长率,提高能源利用效率,优化能源消费结构,保证社会经济同环境的协调发展.     

Does more stringent environmental regulation induce or reduce technology adoption? When the rate of technology adoption is inverted U-shaped

We show that for a broad class of technologies the relationship between policy stringency and the rate of technology adoption is inverted U-shaped. This happens when the marginal abatement cost (MAC) curves of conventional and new technologies intersect, which invariably occurs when emissions are proportional to output and technological progress reduces emissions per output. This outcome does not result from policy failure. On the contrary, in social optimum, the relationship between the slope of the marginal damage curve and the rate of technology adoption is also inverted U-shaped. Under more general conditions, these curves can look even more complicated (e.g., such as inverted W-shaped).     

制备钙钛矿催化剂LaNiO3用于染料废水的降解脱色

为改善普通石墨电极的电催化性能,将以溶胶-凝胶法合成的钙钛矿氧化物LaNiO3混合其它原料做成气体扩散电极,用于电化学降解活性艳红X-3B,以脱色率来考核催化剂的氧还原活性.采用星点设计-效应面曲线法对催化剂制备工艺进行了优化,得出最佳工艺参数为:柠檬酸含量为金属离子物质的量的1.54倍,pH值为9.94,焙烧温度为824.39℃.采用X射线衍射(XRD)、动电位扫描等检测分析方法对所制备的催化剂进行表征和分析.结果表明,制备的催化剂晶相纯净、晶型完整、衍射峰强度较高,是较完整的钙钛矿结构;相比于普通石墨电极,掺杂催化剂的气体扩散电极极化阻力高,氧还原性能良好,有利于有机物的降解.     

Numerical simulation and study on the transmission law of flame and pressure wave of pipeline gas explosion

Based on FLUENT simulation software, the laws of transmission of flame and pressure wave in pipeline gas explosion were studied. It turned out that, the maximum pressure value of the explosion point is not the maximum value of the whole explosion process; the maximum pressure value of the pressure wave lowers firstly near the explosion point, then rises to a peak, and then drops gradually; two waves divide the space in the pipeline into three sections during the gas explosion transmission. The result is basically consistent between numerical simulation and experiment, and the conclusion from the simulation provides theoretical basis for research on explosion-proof and suppression devices for underground gas pipeline, as well as for technical regulations of installation.     

码头油品泄漏扩散事故危险危害评价

运用“泄漏扩散”模型对某码头油品泄漏扩散事故危险危害程度进行了评价,得到了爆炸危险区域和中毒危害区域的面积,为码头制定应急救援预案提供了依据.     

深水内波条件下井喷原油扩散规律数值仿真分析

为研究深水内波条件下井喷原油扩散问题,基于计算流体动力学CFD方法,建立深水内波条件下的溢油扩散后果预测模型,研究深水溢油在内波流场中的扩散规律,评估溢油在内波流中的上浮时间、扩散距离等关键风险参数,探讨内波工况、井喷流量及海况条件对深水溢油扩散行为和后果的影响。研究表明:泄漏原油喷射涌入海水中形成射流和羽流,向下部海流出口方向偏移,上升至250m处原油破碎分散为小油滴,受内波剪切作用,扩散范围增大,并向上部海流出口方向偏移,溢出点位置位于泄漏口正上方附近;内波流速变化对原油运移至海面所需时间无明显影响,对横向扩散参数有较明显影响;泄漏速率变化对原油的溢出时间和横向扩散参数均有较明显影响;海况条件对原油溢出时间、运移过程和扩散范围均有较明显影响,其中内波条件下,井喷溢油造成的危害最大。     

损失瓦斯量与煤的破坏类型关系研究

损失瓦斯量是准确获取煤层瓦斯含量的基础数据。通过实验室测定和不同损失量计算模型的对比分析,表明采用 传统的t法和幂函数法获取损失瓦斯量时,Ⅱ类、Ⅲ类和Ⅳ类煤符合性较好,误差小于20%,I类煤和Ⅴ类煤的损失瓦斯 量误差为25%~31%;煤中孔隙结构的差异是误差产生的原因,I类煤中原生孔隙占多数,Ⅴ类煤的孔隙受构造影响最大, 其它类型煤的孔隙结构介于I类煤和Ⅴ类煤之间;对于I类煤和Ⅴ类煤,采用表征原生孔隙和构造孔隙双孔隙特征的模型 获得的损失瓦斯量误差低于10%。研究结论对煤层瓦斯含量测定具有重要意义。     

Pressure characteristics and dynamic response of coal mine refuge chamber with underground gas explosion

Coal mine refuge chambers are new devices for coal mine safety which can provide basic survival conditions after gas explosion. In order to simulate the propagation of underground methane/air mixture blast wave, and check structural safety of coal mine mobile refuge chamber, an underground tunnel model and a refuge chamber model have been established based on explicit nonlinear dynamic ANSYS/LS-DYNA 970 program. Results show that the reflected wave pressure on the impact surface was about two times higher than that on the incident one. The relationship between the pressure fields of the chamber was analyzed. The maximum pressure of gas explosion reached about 0.71 MPa, and the pulse width was 360 ms. The maximum absolute displacement and stress occurs at the main door center and the connection of stiffeners and the front plate, respectively. The entire coal mine mobile refuge chamber was in elastic state and its strength and stiffness meet the safety requirements. The cabin door, the front plate and the connecting flange at cabin back as well as the stiffeners on each side were the most critical components. Suggestions were put forward for the refuge chamber.     

中压天然气管道泄漏扩散模拟研究

建立了埋地中压天然气管道发生泄漏时时的数学模型,将土壤视为各向同性的多孔介质,采用FLUENT对天然气在土壤中的扩散规律及浓度分布进行模拟,分析不同时刻地表的危险区域范围,并对比了不同管道压力、泄漏孔径大小、泄漏位置等工况下危险半径随时间的变化。结果表明:管道压力越大,泄漏的体积流量越大,同一时间危险范围越大;相同的泄漏压力下,泄漏孔径对危险半径没有很大影响;不同泄漏孔位置,泄漏初期向上开口时危险半径最大,一段时间后向下开口危险半径最大。