燃煤烟气脱硝技术的应用与进展

介绍了近年来国内外应用和正在研究开发的一些主要的燃煤烟气脱硝技术,并对这些技术的优缺点作了比较和评述。     

长白山低山丘陵区生态农业建设与小流域治理——以吉林省柳河试验区为例

吉林省柳河试验区是长白山低山丘陵区域的典型代表。本文在分析了该试验区的农业自然条件及其存在的主要问题的基础上,提出了生态农业建设与小流域综合治理的技术模式,并报道了初步实施结果     

瓦斯气体在煤层中的扩散机理及模式

根据气体在多孔介质中的扩散模式 ,结合煤结构的实际特点 ,分析了瓦斯气体在煤孔隙中的扩散机理 ,得出瓦斯在煤体中几种扩散模式 :菲克型扩散、诺森扩散、过渡型扩散、表面扩散和晶体扩散。从微观上看 ,影响瓦斯气体在煤层中扩散的主要因素是瓦斯气体的平均自由程和煤不同尺寸微孔隙的分布情况。根据不同孔隙分布的煤层 ,探讨了各种扩散模式的适用条件     

GIS支持下的河网密度提取及其在洪水危险性分析中的应用

流域结构特征包含着丰富的洪水危险性信息。本文主要分析流域结构特征的一个重要指标－河网密度与洪水危险性之间的关系,并重点探讨了GIS支持下的河网密度自动提取方法,最后给出了辽河流域的实例分析。     

两种主要泥石流排导槽的比较

通过大量的实例工程的考察,对两种主要泥石流排导槽－东川槽和V型槽的设计,投资及运行现状进行比较,分析总强出排种导槽各自的优缺点,以供以后设计时参考,优化设计,更有效防治泥石流,节约投资,保护生命财产安全。     

Novel polymer monolith microextraction using a poly-(methyl methacrylate-co-ethylene dimethacrylate) monolith and its application to the determination of polychlorinated biphenyls in water samples

A novel and simple method based on polymer monolith microextraction (PMME) coupled to gas chromatography with electron-capture detection (GC-ECD) was developed for the determination of six polychlorinated biphenyls (PCBs) residues in water samples. The proposed method used poly-(methyl methacrylate-co-ethylene dimethacrylate) (MMA-co-EDMA) monolith as extraction media. Several factors affecting experiments such as sample flow rate, sample volume, the type of eluent, eluent volume, eluent flow rate, effect of salt addition and carry over effect were investigated and optimized systematically. The limits of detection (LODs) for six PCBs were 0.028-0.043 ng mL⁻¹ in water samples. The intra-day and inter-day precisions (R.S.D.) were less than 9.2% and 9.6%, respectively. The proposed method was successfully applied to the determination of six PCBs in tap water, lake water and industrial waste water and the trueness has been evaluated by recovery experiments. The obtained relative recoveries were in the range of 63.3-105.6%.     

Naphthenic acid biodegradation by the unicellular alga Dunaliella tertiolecta

Naphthenic acids (NAs) are a major contributor to toxicity in tailings waste generated from bitumen production in the Athabasca Oil Sands region. While investigations have shown that bacteria can biodegrade NAs and reduce tailings toxicity, the potential of algae to biodegrade NAs and the biochemical mechanisms involved remain poorly understood. Here, we discovered that the marine alga Dunaliella tertiolecta is able to tolerate five model NAs (cyclohexanecarboxylic acid, cyclohexaneacetic acid, cyclohexanepropionic acid, cyclohexanebutyric acid and 1,2,3,4-tetrahydro-2-naphthoic acid) at 300 mg L⁻¹, a level which exceeds that of any single or combination of NAs typically found in tailings ponds. Moreover, we show that D. tertiolecta can metabolize four of the model NAs. Analysis of NA-amended cultures of D. tertiolecta via low resolution gas chromatography-mass spectrometry allowed us to quantify decreasing NA levels, identify metabolites, and formulate putative mechanisms of biodegradation. Degradation of cyclohexanebutyric acid and cyclohexanepropionic acid proceeded via β-oxidation and resulted in the transient accumulation of cyclohexaneacetic acid and cyclohexanecarboxylic acid, respectively. Cyclohexanecarboxylic acid was metabolized via 1-cyclohexenecarboxylic acid suggesting that further degradation may occur by step-wise β-oxidation. When D. tertiolecta was inoculated in the presence of oil sands tailings water from the Athabasca region, biodegradation of single-ring NAs was observed relative to controls. This result corroborates the trend we observed with the single-ring model NAs.     

典型高混接率分流制排水泵站雨天放江污染特征研究

通过对上海市中心城区典型分流制系统z泵站汛期降雨放江水质水量分析,在调查系统服务区特点、泵站运行和开展现场实测的基础上,得出如下结论：（1）由于管网系统混接情况严重,加上高水位运行、雨前预抽空等原因,Z泵站汛期放江频率高,污染严重;（2）放江污染物的EMC在不同雨型情况下表现不同,溶解性污染物随降雨量的增大而降低,而包含悬浮物的污染指标呈先升后降的变化趋势,这主要与管道沉积物特征有关;（3）随着降雨量的增大,泵站的放江负荷量显著增加。在同等降雨条件下,前峰雨使得泵站放江污染负荷远大于后峰雨;（4）受雨型与预抽空的影响,不论小雨、中雨、大雨,SS初期效应均不显著;COD与TP主要来源于管道沉积污染物,初期效应显著;溶解态污染物初期效应显著,不受降雨雨量与雨型的影响;（5）为有效降低Z泵站降雨放江污染负荷,提出包括雨污混接改造、优化泵站运行、提高截流能力、疏通管道等措施在内的污染控制策略。     

改进的"两相优化法"在排水管网优化设计中的应用

介绍了改进的"两相优化法"在排水管网管径和埋深的优化设计中的应用.改进的方法依次从充满度、坡度、流速3方面对管段进行优化设计.通过算例分析可知,改进的方法较原方法优化效果更好,工程造价更低.     

对截流式合流制排水体制的探讨

以瑞安市为例,对老城区普遍采用的截流式合流制排水体制的优劣做了具体的分析,并结合污水管线设计、建设、管理中存在的问题进行了探讨。