浙江省人口分布的空间格局及其时空演变

改革开放以来,随着经济社会的快速发展,浙江省各地区人口分布发生了明显的变化。文章运用空间自相关、不均衡系数、人口重心和偏移增长法,对浙江省69个县级行政单元人口分布的空间格局及其在1985-2007年间的时空演变特征进行了深入分析,并得出以下几点结论:①浙江省人口密度分布具有"点—带—区"结构特征,即以经济发展水平高的地区为高值点,通过杭甬高速和甬台温高速将各高值点连接成带,其他地区则形成人口密度低值区;②浙江省人口分布存在一定的空间关联性,在浙东北环杭州湾地区和浙东南沿海地区呈现高高集聚,在浙中和西南内陆地区呈现低低集聚;③浙江省人口呈不均衡分布状态,并且人口不均衡系数不断增大;④浙江省人口偏移增长在三大区域之间具有明显差异,浙东南沿海地区人口总偏移量为正,浙东北环杭州湾地区基本稳定、浙中和西南内陆地区为负,人口重心逐渐向东南沿海偏移。     

电除尘器斜气流状态下粉尘沉降试验研究

针对电除尘器在实际运行过程中出现的除尘效率下降问题,提出斜气流这一新型技术,对均匀气流与斜气流分布状态进行可视化研究;在两种气流状态下进行粉尘沉降试验,对试验结果进行对比分析、总结相应规律;对我国电除尘器气流技术的发展提出了建议。     

中国火灾的时空演变特征——基于GIS的统计分析

研究对象为2000-2009年中国341个地级以上城市(不含台湾及港澳地区)的火灾统计数据。首先应用主成分分析法,计算火灾综合损失(fire composite losts,FCL);再对FCL进行分级,将所有研究单元按FCL从小到大分为5个级别,较高FCL单元主要分布于黑河—腾冲线以东地区。对每个研究单元分别进行时间序列分析,观察其FCL变化趋势,将各区域分为平稳区、改善区、恶化区和波动区,其分别占比41%,40%,8%和11%,表明绝大多数城市FCL呈平稳或下降趋势。恶化区明显地沿黑河—腾冲线、淮河—大别山—雪峰山沿线和东南沿海分布,这可能与气候变化或社会经济发展有关。     

中国自然资源政策演进历程与发展方向

自然资源政策是国家政策体系的重要组成部分,其社会关注度、复杂性、地区差异性等特征较为突出.1980年代以来,中国自然资源政策大致经历了上世纪80年代、1991-1997、1998-2003、2004 - 2010等四个阶段的演进,期间,社会经济发展形势不断发展变化,自然资源政策的需求和目标也不断变化,并为社会经济快速发展提供了政策基础;但同时也在政策一致性、政策权威性、政策公正性、政策认知性等方面,暴露出一些不足和缺憾.自2011年开始,资源政策的演进进入了第五个阶段.展望未来,为全面落实科学发展观和加快转变经济发展方式,中国自然资源政策应不断创新,重点在政府规制、全面负责、促进转型、系统协调和差异设计等方面不断优化和发展.     

变革中的中国水资源管理

水资源短缺是世界面临的共同危机,是制约国民经济健康稳定发展的重要“瓶颈”,水资源的可持续利用已经成为经济社会可持续发展的基础性、战略性问题.缓解水资源供需矛盾的关键是加强水资源的管理.文章回顾了中国水资源管理制度的发展演变历程:只管工程的非正式水资源管理、行政命令为主的正式制度萌芽、取水许可管理和基于水权的正规制度管理等四个阶段.尽管在确立以流域管理和区域管理相结合的综合管理体制,建立以水量分配、取水许可、水资源论证为主要内容的水权管理制度和以全成本核算为原则的水价管理制度等方面成绩显著,水资源管理中仍存在水资源权属不清、水环境权得不到保障等问题.今后中国水资源改革,首先应继续深化水权改革,推动水权明晰化,建立水权交易制度;其次,健全水环境权的法律法制规范,提供相关的法律保障;最后,完善部门间的合作协调机制,真正实现对水的协同管理.     

我国海洋产业结构与总体产业结构的演进规律对比分析

总体产业结构和海洋产业结构的发展演进呈现出不同的规律性.运用三轴图法对比分析1992-2009总体产业和海洋产业结构的演进规律及我国总体产业和海洋产业的发展情况,在此基础上探讨促进总体产业结构和海洋产业结构演进的主导因素,为产业政策的制订提供科学依据.     

基于“四元主体模型”的城市技术创新体系研究

依据创新型城市的基本内涵,构建出四元城市创新体系模型,形成以四元创新主体为核心,集知识、技术于一体的网络创新体系,说明城市创新体系四元模型中,各主体之间的关系及其伴随社会的不同发展时期四元模型的变化趋势和变化过程中主导驱动元素扮演的角色、作用和地位。     

Retention time profiling of all 136 tetra- through octa- chlorinated dibenzo-p-dioxins and dibenzofurans on a variety of Si-Arylene gas chromatographic stationary phases

The applicability of three different Silphenylene Silicone co-polymer (Si-Arylene) GC stationary phases (J&W Scientific DB-5ms, Varian VF-5ms, and VF-Xms) has been evaluated for the separation of all 136 tetra- through the octa- chlorinated dibenzo-p-dioxins (PCDD) and chlorinated dibenzofurans (PCDF) from closely eluting isomers using gas chromatography/high resolution mass spectrometry (GC/HRMS). Their relative performance data are compared to the “conventional” 5% diphenyl 95% dimethylpolysiloxane GC column (Supelco Equity-5) and to each other based on absolute retention times, visualized mass chromatograms, and the separation of 2,3,7,8-substituted isomers. VF-Xms GC column was able to demonstrate a better performance towards separation of 2,3,7,8-substituted PCDD/PCDF compared to other Si-Arylene GC columns tested, where only 2,3,4,7,8-PnCDF can not be resolved from 1,2,3,6,9-PnCDF and 2,3,4,6,7,8-/1,2,3,6,8,9-HxCDF and 1,2,3,7,8,9-/1,2,3,4,8,9-HxCDF can be at least partially resolved. These data suggest that the development of a single GC column for the separation of all 17 2,3,7,8-substituted dioxins and furans is feasible, which therefore could be used as a standard tool for the PCDD/PCDF methods globally including USEPA methods 1613b, 8290A, 8280B, European Standard Method EN 1948, Canadian methods DFPCB-E3418, EPS 1/RM/19, Japanese methods JIS K0311 and JIS K0312. Having one specific GC column to separate all 2,3,7,8-substituted PCDD/PCDF will significantly improve the data quality, comparability by the various methods and assessment techniques while simultaneously leading to a more cost and time efficient operation.     

Determination of chlorinated paraffins in sediments from the Firth of Clyde by gas chromatography with electron capture negative ionisation mass spectrometry and carbon skeleton analysis by gas chromatography with flame ionisation detection

Short chain chlorinated paraffins (SCCPs) are a group of persistent organic pollutants (POPs) of increasing concern, but are to date not widely investigated in the environment, largely due to the challenges involved in their quantification. Here, SCCPs were quantified in marine sediments from the Firth of Clyde, Scotland, by gas chromatography with electron capture negative ionisation mass spectrometry (GC-ECNIMS) and through carbon skeleton analysis by gas chromatography with flame ionisation detection (GC-FID), and the analytical challenges encountered are discussed. Concentrations in the sediments ranged from 0.4 to 69 μg kg⁻¹ when determined by GC-ECNIMS, and from 5.6 to 379 μg kg⁻¹ when determined by GC-FID. For 8 out of 11 samples, analysis by GC-FID gave higher results than analysis by GC-ECNIMS. Unexpected aspects of the analysis, such as the presence of high concentrations of longer chain chlorinated paraffins in the samples, are also presented.     

Analysis of Organophosphorus Pesticides in Whole Milk by Solid Phase Microextraction Gas Chromatography Method

Solid phase microextraction (SPME) was used for the extraction of residual coumaphos and dichlorvos in whole milk. The residues were analyzed by capillary gas chromatography equipped with nitrogen phosphorus detector (GC-NPD). A manual SPME holder with a 100-μm polyacrylate fiber was used. The optimized conditions for extraction by SPME method were: sample agitation, absorption temperature of 30°C, absorption time of 40 min, desorption time of 10 min, and sample volume was 16.0 mL in the vial. Under these conditions, the calibration graphs were linear in the range of 0.17 μgL^?1 to 1.75 μgL^?1 for coumaphos and 0.69 μgL^?1 to 6.90 μgL^?1 for dichlorvos. Precision was good with RSD values of 13% for coumaphos and 14% for dichlorvos. The detection limits (LOD) were 0.060 μgL^?1 for dichlorvos and 0.052 for coumaphos. The quantification limits (LOQ) were 0.086 μgL^?1 for dichlorvos and 0.066 μgL^?1 for coumaphos. The results obtained in this study suggest that SPME is a suitable technique for residual pesticide analysis of milk. The data demonstrate that particular OP pesticides used in dairy farming in the region of Minas Gerais were found to contaminate cow whole milk, and the residues are not removed by treating the milk by boiling.