怀化城市形态的演变特征及形成机制

根据城市规划土地利用现状图、怀化市1〖DK1〗∶10 000地形图、遥感影像图、社会经济统计数据以及其他相关资料,借助ArcGIS 92平台和统计分析软件(SPSS 115),采用空间形态分析、地统计分析、等扇分析、景观测度及分形理论等研究方法,对我国中部铁路枢纽城市怀化的城市形态演变特征及形成机制展开研究。结果表明：城市形态的紧凑度、分维数偏低,形状指数偏大,城市以正东、西南、正北方位的扩展为主,演化轨迹为“据点型”-“散点组团型”-“团城型”-“枝状放射型”-“‘T’字型”;城市形态演变是经济发展、交通设施发展、自然地理条件限制等多重驱动力共同作用的结果.     

Validation of a QuEChERS-based gas chromatographic method for analysis of pesticide residues in Cassia angustifolia (senna)

A simple multi-residue method based on modified QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) approach was established for the determination of 17 organochlorine (OC), 15 organophosphorous (OP) and 7 synthetic pyrethroid (SP) pesticides in an economically important medicinal plant of India, Senna (Cassia angustifolia), by gas chromatography coupled to electron capture and flame thermionic detectors (GC/ECD/FTD) and confirmation of residues was done on gas chromatograph coupled with mass spectrometry (GC-MS). The developed method was validated by testing the following parameters: linearity, limit of detection (LOD), limit of quantification (LOQ), matrix effect, accuracy–precision and measurement uncertainty; the validation study clearly demonstrated the suitability of the method for its intended application. All pesticides showed good linearity in the range 0.01–1.0 μg mL^?1 for OCs and OPs and 0.05–2.5 μg mL^?1 for SPs with correlation coefficients higher than 0.98. The method gave good recoveries for most of the pesticides (70–120%) with intra-day and inter-day precision < 20% in most of the cases. The limits of detection varied from 0.003 to 0.03 mg kg^?1, and the LOQs were determined as 0.01-0.049 mg kg^?1. The expanded uncertainties were <30%, which was distinctively less than a maximum default value of ±50%. The proposed method was successfully applied to determine pesticide residues in 12 commercial market samples obtained from different locations in India.     

高度城市化区域土地利用结构演化与驱动因素分析——以苏州市为例

分析高度城市化区域土地利用结构演化以及驱动因素,可为优化区域未来的土地利用结构、促进土地资源的保护和高效利用提供科学依据。采用1998～2008年苏州市土地利用变更调查数据,运用土地利用数量变化、程度变化和空间变化等指标测算模型分析土地利用演化规律。结果表明：1998～2008年,苏州市耕地面积显著减少,农业结构调整明显;居民点及独立工矿用地面积急剧增加,与耕地减少呈显著负相关;土地利用程度综合指数逐年提升;苏州全域耕地、园地、城市用地相对变化率最大的均为昆山市,建制镇和独立工矿用地相对变化率最大的分别是张家港市和吴江市;利用主成分分析法对影响土地利用结构演化的人文因素进行了分析,得出驱动因素主要为：人口增长、经济发展、工业化和城镇化水平。走集约型城市化道路,实现“效率型”土地利用模式,注重社会、经济、生态效益相结合是今后土地利用努力的方向     

基于复杂网络的台风灾害演化系统风险分析与控制研究

基于复杂网络理论,提出了一种针对自然灾害演化系统的风险分析与控制的思路与方法。以"莫拉克"台风为例,构建了包含30个危机事件与39条连接边的台风网络演化模型;采用网络节点的出入度、子网节点数和包含节点的支链数进行风险分析,并确定关键节点,进一步提出断链方案和控制建议。结果表明:狂风、暴雨、洪水、山体滑坡、泥石流、交通堵塞和村庄毁坏等事件风险较大,是台风灾害系统的关键节点。据此提出建议:提高城市排水系统运行能力,加强交通系统监管和调度力度,启动农村人员安置和灾后重建预案。     

基于贝叶斯网络的城市地震次生灾害演化机理分析

为了解城市地震次生灾害的演化路径及扩散机理,进而为城市防震救灾工作提供科学的参考依据,通过对城市地震有关资料和文献的分析,确定出城市地震次生灾害演化系统贝叶斯网络的节点变量及取值范围,并根据节点变量之间的因果关系构建出贝叶斯网络结构图。通过对国内外典型震例中的16个受灾城市相关数据进行统计,分析获得网络结构各个变量的条件概率。结合贝叶斯网络推理知识,利用贝叶斯网络工具箱分析了在相同的地震输入变量、不同的控制输入变量取值条件下,各类城市地震次生灾害的发生概率。算例分析结果表明不同的应急管理水平对城市地震各类次生灾害的发生概率有显著影响。     

东北地区开发规模扩张的资源环境响应演变及影响因素

提出"区域开发规模扩张的资源环境响应"的概念,并构建了区域开发规模扩张的资源环境响应指数、响应度模型及评价指标体系,通过定量分析1995-2008年东北地区开发规模扩张的资源环境响应变化及影响因素,得出以下结论:1995年以来东北地区开发规模不断扩大,而资源环境水平总体呈现出"先升后降"的波动变化态势。资源环境对东北地区开发规模扩张具有由"正响应"向"负响应"转变的特征,与此相对应,区域开发规模扩张对资源环境的影响程度也呈现出由"弱促进"向"强胁迫"变化的态势,这说明近年来在东北地区开发规模加速扩展的同时,其对区域资源环境造成的压力也日益增大。1995-2008年由经济快速增长导致的资源环境压力增长是引致东北地区开发规模扩张对资源环境影响由"正向促进"向"负向胁迫"转化的重要内部因素,而区域投资的不断增长以及工业的快速发展是东北地区开发规模扩张对资源环境影响由"弱促进"向"强胁迫"变化的主要因素。     

中部四大城市群（圈）外商直接投资的时空演化与竞争格局

采用熵指数与偏移一分享分析方法,对中部四大城市群近10年来外商直接投资（FDI）的时空演化与竞争格局进行了定量分析。结果表明,中部城市群FDI在不断增长过程中有分散化的总趋势,但城市群之间差异显著,具有阶段性特征;中部城市群FDI偏移增长量逐年增加,城市群之间的偏移增长量远大于城市群内部;高正偏增长城市前期主要集中在武汉城市圈、长株潭城市群,近期转向皖江城市带、东部沿江地带和中原城市群内沿京广、陇海线交汇一带。     

Characterization of an urban landfill soil by using physicochemical analysis and solid phase microextraction (SPME)—GC/MS

We have aimed at characterizing top soil samples taken in-situ from five different locations of the unregulated dumping site in Eskişehir/Turkey for a period of six months. The study is the first attempt in the city and in Turkey, regarding particularly the SPME (Solid Phase Microextraction Technique) analysis method utilized. A comprehensive research has been conducted to produce critical soil data to be used for indicating current risks as well as the urgency of rehabilitating the site and establishing a sanitary landfill in the site. Conventional physicochemical analytical methods and SPME technique were used to analyze the samples. Physicochemical analyses were performed for determining the pH, total dried matter, volatile matter, total nitrogen, phosphorus, macro elements and heavy metals. Meteorological data were also recorded for the same period. SPSS.10.0 statistical program was used to determine the correlation between meteorological data and physicochemical analysis results. Mean values were used in the correlation analyses. These data indicated that the air temperature and precipitation have significant effects on soil characteristics. SPME, coupled with GC/MS, was used to identify eighty six volatile and semi-volatile organic compounds contained in soil samples. The samples were extracted by headspace SPME with heating (δHS-SPME). SPME analyses were conducted using a commercially available polydimethylsiloxane/divinylbenzene (PDMS/DVB) fiber having a film thickness of 65 μm (Supelco) as a capture medium. The experimentally optimized headspace sampling conditions were arranged (15 min. at 50^˚C) before a 30 min. sampling period.     

Deriving ozone dose-response of photosynthesis in adult forest trees from branch-level cuvette gas exchange assessment

Branch-level gas exchange provided the basis for assessing ozone flux in order to derive the dose-response relationship between cumulative O3 uptake (COU) and carbon gain in the upper sun crown of adult Fagus sylvatica. Fluxes of ozone, CO2 and water vapour were monitored simultaneously by climatized branch cuvettes. The cuvettes allowed branch exposure to an ambient or twice-ambient O3 regime, while tree crowns were exposed to the same O3 regimes (twice-ambient generated by a free-air canopy O3 exposure system). COU levels higher than 20mmolm(-2) led to a pronounced decline in carbon gain under elevated O3. The limiting COU range is consistent with findings on neighbouring branches exposed to twice-ambient O3 through free-air fumigation. The cuvette approach allows to estimate O3 flux at peripheral crown positions, where boundary layers are low, yielding a meso-scale within-crown resolution of photosynthetic foliage sensitivity under whole-tree free-air O3 fumigation.     

Atmospheric chemistry of HFE-7000 (CF(3)CF (2)CF (2)OCH (3)) and 2,2,3,3,4,4,4-heptafluoro-1-butanol (CF (3)CF (2)CF (2)CH (2)OH): kinetic rate coefficients and temperature dependence of reactions with chlorine atoms

Background, aim, and scope  The adverse environmental impacts of chlorinated hydrocarbons on the Earth’s ozone layer have focused attention on the effort to replace these compounds by nonchlorinated substitutes with environmental acceptability. Hydrofluoroethers (HFEs) and fluorinated alcohols are currently being introduced in many applications for this purpose. Nevertheless, the presence of a great number of C–F bonds drives to atmospheric long-lived compounds with infrared absorption features. Thus, it is necessary to improve our knowledge about lifetimes and global warming potentials (GWP) for these compounds in order to get a complete evaluation of their environmental impact. Tropospheric degradation is expected to be initiated mainly by OH reactions in the gas phase. Nevertheless, Cl atoms reaction may also be important since rate constants are generally larger than those of OH. In the present work, we report the results obtained in the study of the reactions of Cl radicals with HFE-7000 (CF₃CF₂CF₂OCH₃) (1) and its isomer CF₃CF₂CF₂CH₂OH (2). Materials and methods  Kinetic rate coefficients with Cl atoms have been measured using the discharge flow tube–mass spectrometric technique at 1 Torr of total pressure. The reactions of these chlorofluorocarbons (CFCs) substitutes have been studied under pseudo-first-order kinetic conditions in excess of the fluorinated compounds over Cl atoms. The temperature ranges were 266–333 and 298–353 K for reactions of HFE-7000 and CF₃CF₂CF₂CH₂OH, respectively. Results  The measured room temperature rate constants were k(Cl+CF₃CF₂CF₂OCH₃) = (1.24 ± 0.28) × 10⁻¹³ cm³ molecule⁻¹ s⁻¹and k(Cl+CF₃CF₂CF₂CH₂OH) = (8.35 ± 1.63) × 10⁻¹³ cm³ molecule⁻¹ s⁻¹ (errors are 2σ + 10% to cover systematic errors). The Arrhenius expression for reaction 1 was k ₁(266–333 K) = (6.1 ± 3.8) × 10⁻¹³exp[−(445 ± 186)/T] cm³ molecule⁻¹ s⁻¹ and k ₂(298–353 K) = (1.9 ± 0.7) × 10⁻¹²exp[−(244 ± 125)/T] cm³ molecule⁻¹ s⁻¹ (errors are 2σ). The reactions are reported to proceed through the abstraction of an H atom to form HCl and the corresponding halo-alkyl radical. At 298 K and 1 Torr, yields on HCl of 0.95 ± 0.38 and 0.97 ± 0.16 (errors are 2σ) were obtained for CF₃CF₂CF₂OCH₃ and CF₃CF₂CF₂CH₂OH, respectively. Discussion  The obtained kinetic rate constants are related to the previous data in the literature, showing a good agreement taking into account the error limits. Comparing the obtained results at room temperature, k ₁ and k ₂, HFE-7000 is significantly less reactive than its isomer C₃F₇CH₂OH. A similar behavior has been reported for the reactions of other fluorinated alcohols and their isomeric fluorinated ethers with Cl atoms. Literature data, together with the results reported in this work, show that, for both fluorinated ethers and alcohols, the kinetic rate constant may be considered as not dependent on the number of –CF₂– in the perfluorinated chain. This result may be useful since it is possible to obtain the required physicochemical properties for a given application by changing the number of –CF₂– without changes in the atmospheric reactivity. Furthermore, lifetimes estimations for these CFCs substitutes are calculated and discussed. The average estimated Cl lifetimes are 256 and 38 years for HFE-7000 and C₃H₇CH₂OH, respectively. Conclusions  The studied CFCs’ substitutes are relatively short-lived and OH reaction constitutes their main reactive sink. The average contribution of Cl reactions to global lifetime is about 2% in both cases. Nevertheless, under local conditions as in the marine boundary layer, τ _Cl values as low as 2.5 and 0.4 years for HFE-7000 and C₃H₇CH₂OH, respectively, are expected, showing that the contribution of Cl to the atmospheric degradation of these CFCs substitutes under such conditions may constitute a relevant sink. In the case of CF₃CF₂CF₂OCH₃, significant activation energy has been measured, thus the use of kinetic rate coefficient only at room temperature would result in underestimations of lifetimes and GWPs. Recommendations and perspectives  The results obtained in this work may be helpful within the database used in the modeling studies of coastal areas. The knowledge of the atmospheric behavior and the structure–reactivity relationship discussed in this work may also contribute to the development of new environmentally acceptable chemicals. New volatile materials susceptible of emission to the troposphere should be subject to the study of their reactions with OH and Cl in the range of temperature of the troposphere. The knowledge of the temperature dependence of the kinetic rate constants, as it is now reported for the case of reactions 1 and 2, will allow more accurate lifetimes and related magnitudes like GWPs. Nevertheless, a better knowledge of the vertical Cl tropospheric distribution is still required.