甲胺、二甲胺及三甲胺的气相色谱测定

采用气相色谱法、大口径毛细管柱分离了甲胺、二甲胺、三甲胺.用氮磷检测器(NPD)检测,得到了良好的分离效果和很高的灵敏度,检测限可达0.025mg/L.同时,对甲胺类在NPD和氢火焰离子化检测器(FID)上的灵敏度作了比较,发现甲胺类物质在NPD上的灵敏度大大高于FID,因此,前者特别适用于检测环境试样中低含量甲胺类有机物的监测.     

“十二五”以来中国应对气候变化政策和行动评述

基于广泛系统的文献梳理和总结,凝练了“十二五”以来中国应对气候变化政策和行动的现状、特点及成效,并提出针对性建议。主要结论包括:从外部环境看,国际形势对中国应对气候变化事业的推动作用呈现递减态势,之前“以外促内”的国内气候治理特点逐步转化为“内生动力为主”和“内外协调”;从政策制定和执行模式看,“集思广益”“上书模式”持续,“上下互动”“智库支持”的政策学习特点更加明显;从政策体系上看,已经形成相对成熟的符合中国国情的完整体系,推动气候治理能力显著提高;从政策总体特点看,呈现规划主导并引领、行政手段先行市场机制跟进、由点到面有序扩展、环境与气候协同治理、中央和地方互动博弈形成动态平衡、短期内政策成本较高等特点。“十二五”至今,中国应对气候变化政策行动效果明显,提前实现了2020年应对气候变化目标,并在污染治理、经济发展等方面产生广泛协同效应。“十三五”中期以来,中国应对气候变化组织管理机构进行了重大调整,从中央到地方气候政策和行动进入调整阶段。同时,更加强调气候政策和环境政策的协同。展望未来,中国应对气候变化政策和行动应该尽快走出调整期,充分利用新体制的优势,以碳总量控制目标为抓手,坚定推动以全国碳排放权交易为中心、多措互补的政策体系,注重适应行动以应对不断放大的气候风险,继续提高公众对应对气候变化政策的认知度、接受度和参与度,并不断加强技术研发和储备。     

Experimental investigation of limiting oxygen concentration of hybrid mixtures

An investigation into the limiting oxygen concentration (LOC) of fifteen combustible dusts and methane, ethanol and isopropanol hybrid mixtures in the standard 20 L explosion chamber was performed. Three ignition energies (10 J, 2 kJ and 10 kJ) were used. The results show that a 10 J electrical spark ignition leads to significantly higher limiting oxygen concentration values than either 2 kJ or 10 kJ pyrotechnic igniters. This could be due to the “overdriving” effect of the chemical igniters, which produce a hot flame that virtually covers the entire explosion chamber during combustion. With respect to hybrid mixture investigation, the 20 L sphere was modified to allow the input of methane gas and flammable solvents. The limiting oxygen concentrations of the hybrid mixtures were found to be considerably lower than those of dust air mixtures when the relatively weaker spark igniter was used. There was no significant change in limiting oxygen concentration when the higher energy chemical igniters were used.     

Failure Mode and Effect Analysis using an integrated approach of clustering and MCDM under pythagorean fuzzy environment

Failure Mode and Effect Analysis (FMEA) is an effective risk analysis and failure avoidance approach in the design, process, services, and system. With all its benefits, FMEA has three limitations: failure mode risk assessment and prioritization, complex FMEA worksheets, and difficult application of FMEA tables. This paper seeks to overcome the shortcomings of FMEA using an integrated approach based on a developed Pythagorean fuzzy (PF) k-means clustering algorithm and a popular MCDM method called PF-VIKOR. In the first step, Pythagorean fuzzy numbers (PFNs) were used to collect Severity (S), Occurrence (O), and Detection (D) factors for failure modes to incorporate uncertainty and fuzziness into subjective judgments. Afterward, failure modes were clustered by developing a novel k-means clustering algorithm that accepts PFNs as input. Finally, the PF-VIKOR approach was used to analyze the ordering of cluster risks. The proposed approach was implemented in the dehydration unit of an Iranian gas refinery and the results were compared with the traditional FMEA. The findings showed the flexibility and applicability of the proposed approach in addressing real-world problems. This research provides two key contributions: (1) designing a PFN-based k-means clustering algorithm that tackles FMEA limitations and (2) using the PF-VIKOR method for prioritizing and evaluating failure mode clusters.     

Influence of water storage on deflagration characteristics of methane in confined space

Comparative experiments were conducted under different water level heights and methane concentration conditions using a self-designed explosion experiment pipeline. The results showed that, in comparison with the scenario without water storage, when the water level was 2 cm and methane concentration was 6.5–12.5%, there was a dual effect including a pressure decrease caused by the endothermic cooling of liquid water and a pressure increase caused by the expansion of water vapour. These effects caused the pressure time history curve to exhibit a double-peak or multi-peak structure, and the average decrease in the peak deflagration pressure was 23.76%. The heat of vaporisation absorbed by the stored water and barrier effect of water vapour on the transfer of the heat slowed down the increase in the deflagration temperature. The average decrease in the peak deflagration temperature of methane was 13.82%, and the time to reach the peak deflagration temperature was extended as a whole, with an average delay of 0.22 s. Water storage also changed the shape of the deflagration flame front, which exhibited ‘knife’, ‘V’, and ‘crescent’ structures. Moreover, the flame propagation speed was significantly reduced, with the peak and average flame propagation speeds decreased by 83.3% and 83.6%, respectively. The research results can provide a certain reference for preventing gas explosions in typical confined spaces, and also help to explore new anti-explosion methods, which can be applied to marine equipment such as ships.     

Explosions of gasoline–air mixture in the tunnels containing branch configuration

In order to investigate the effects of branch tunnels on explosion propagation, experiments were performed in five different configuration tunnels (straight configuration and configurations with 1 branch, 2 branches, 3 branches and 4 branches). Pressure and flame transducers were used to record the history of the pressure development and track the velocity of the flame front. It was shown that the branch tunnels had ability to enhance the maximum overpressure, rate of overpressure rise, and deflagration index (K_G) of the gasoline–air mixture explosion due to the turbulence induced by the branch tunnels. The overpressure rise rate and K_G of the explosion increased as a function of the number of branch tunnels. Experiments also showed that the maximum flame speed increased as the branch number increasing from 0 to 3 due to the enlargement of turbulence induced by the branch tunnels. However, an increase of branch number did not always lead to an enhancement of flame speed because the heat loss was intensified resulting from the increase of flame surface caused by the branch tunnels. When the number of branch tunnels exceeded 3, the maximum flame speed dropped.     

Assessment and improvement of integrated HSE and macro-ergonomics factors by fuzzy cognitive maps: The case of a large gas refinery

This study analyzes and assesses the integrated health, safety, environment (HSE) and ergonomics (HSEE) factors by fuzzy cognitive maps (FCM) approach. This is achieved through integrating ergonomic and macro-ergonomic as well as occupational health and safety arrangements in an integrated modeling for assessment of their multi-faceted impact on workers' productivity, injury rate and satisfaction. This paper uses FCM to assess the direct and indirect effects of HSEE factors on system performance indicators. The results of FCM are used to develop leading indicators useful for proactive management of productivity, injury rate, and job satisfaction. The result of a comprehensive survey of 37 experts in control rooms and maintenance activities in a large gas refinery is used to show the applicability and usefulness of FCM approach. Moreover, FCM results are used to determine the causal structure of HSEE factors and system performance indicators. It is concluded that macro-ergonomics factors such as instructions and education, familiarity with organization's rules, and proper communications most contribute to improve workers' safety, satisfaction, and productivity.     

Experimental investigation of gas explosion in single vessel and connected vessels

Gas explosion in connected vessels usually leads to high pressure and high rate of pressure increase which the vessels and pipes can not tolerate. Severe human casualties and property losses may occur due to the variation characteristics of gas explosion pressure in connected vessels. To determine gas explosion strength, an experimental testing system for methane and air mixture explosion in a single vessel, in a single vessel connected a pipe and in connected vessels has been set up. The experiment apparatus consisted of two spherical vessels of 350 mm and 600 mm in diameter, three connecting pipes of 89 mm in diameter and 6 m in length. First, the results of gas explosion pressure in a single vessel and connected vessels were compared and analyzed. And then the development of gas explosion, its changing characteristics and relevant influencing factors were analyzed. When gas explosion occurs in a single vessel, the maximum explosion pressure and pressure growth rate with ignition at the center of a spherical vessel are higher than those with ignition on the inner-wall of the vessel. In conclusion, besides ignition source on the inner wall, the ignition source at the center of the vessels must be avoided to reduce the damage level. When the gas mixture is ignited in the large vessel, the maximum explosion pressure and explosion pressure rising rate in the small vessel raise. And the maximum explosion pressure and pressure rising rate in connected vessels are higher than those in the single containment vessel. So whenever possible, some isolation techniques, such as fast-acting valves, rotary valves, etc., might be applied to reduce explosion strength in the integrated system. However, when the gas mixture is ignited in the small vessel, the maximum explosion pressures in the large vessel and in the small vessel both decrease. Moreover, the explosion pressure is lower than that in the single vessel. When gas explosion happens in a single vessel connected to a pipe, the maximum explosion pressure occurs at the end of the pipe if the gas mixture is ignited in the spherical vessel. Therefore, installing a pipe into the system can reduce the maximum explosion pressure, but it also causes the explosion pressure growth rate to increase.     

黄河流域植被覆盖度变化及驱动因素

利用Google Earth Engine(GEE)遥感云计算平台通过像元二分模型反演出1999~2019年植被覆盖度,采用一元线性回归和变异系数法来研究FVC的变化趋势特征及其稳定性,通过地理探测器进行植被变化的驱动分析。结果表明:黄河流域FVC总体上西北低东南高;中高和高被覆盖区分别占研究区总面积的21.74%和17.87%;近20a年黄河流域FVC已有较好改善,流域中部植被改善最明显,改善区域占流域总面积的48.52%;FVC的稳定性以较平稳为主。降水、日照时间及相对湿度三个驱动因子对黄河流域FVC影响力最强。各驱动因子对FVC影响存在交互作用,以双因子增强或者非线性增强为主,双因子交互作用增强了单因子的影响;本研究也揭示了促进植被生长的各因子最适宜范围,有助于更好地理解自然和社会因素对植被覆盖变化的影响及其驱动机制。