Fe-C合金中辐照缺陷特征的剂量率效应计算模拟

目的尝试采用计算模拟方法探究剂量率对辐照微结构特征的影响,探究常温辐照下剂量率效应的机理。方法采用动力学蒙特卡罗(OKMC)方法,结合近些年第一性原理和分子动力学的计算参数,研究了常温下铁-碳体系中辐照缺陷随剂量率的变化特征。结果在较低的剂量范围(<0.01 dpa)内,间隙型位错环的密度随剂量率的增加而增加;但在较高的剂量范围内,高剂量率辐照呈现较低的间隙型位错环密度、较大的缺陷尺寸。通过比较不同剂量率下的位错线对点缺陷的吸收数目,把剂量率在不同剂量范围内的特征归结于位错吸收与缺陷复合之间的竞争。结论在较低的剂量范围内,位错吸收具有重要影响,随着剂量率的增加,位错吸收的缺陷数目显著减少;而在较高的剂量范围内,基体中间隙-空位缺陷的复合随剂量率的增加而显著增加,以至于高剂量率辐照可能产生较低的辐照硬化。文中的工作对理解剂量率效应的机理提供了一定的科学依据,为离子束模拟中子辐照提供了一定的科学参考。     

Effect of separation distance on gas dispersion and vapor cloud explosion in a storage tank farm determined using computational fluid dynamics

Storage tank separation distance, which considerably affects forestalling and mitigating accident consequences, is principally determined by thermal radiation modeling and meeting industry safety requirements. However, little is known about the influence of separation distance on gas dispersion or gas explosion, which are the most destructive types of accidents in industrial settings. This study evaluated the effect of separation distance on gas dispersion and vapor cloud explosion in a storage tank farm. Experiments were conducted using Flame Acceleration Simulator, an advanced computational fluid dynamics software program. Codes governing the design of separation distances in China and the United States were compared. A series of geometrical models of storage tanks with various separation distances were established. Overall, increasing separation distance led to a substantial reduction in vapor cloud volume and size in most cases. Notably, a 1.0 storage diameter separation distance appeared to be optimal. In terms of vapor cloud explosion, a greater separation distance had a marked effect on mitigating overpressure in gas explosions. Therefore, separation distance merited consideration in the design of storage tanks to prevent gas dispersion and explosion.     

事故车辆影响下的城市道路交通仿真研究

为研究事故车辆影响下城市道路交通的特征，构建考虑车辆抢道行为的元胞自动机交通流模型，研究给定冲突区域长度下不同进车率和不同事故持续时间对城市道路交通流的影响。研究结果表明:事故车辆会诱发交通瓶颈，对城市交通产生显著干扰并形成拥堵带，且拥堵带向事故车辆上游传递。不同事故持续时间下交通流演化存在差异，道路平均车流量、车流平均密度随着事故持续时间的增加而增加，车辆平均速度随之减小。当道路中车辆较少（pin=0.3）且事故持续时间达到15 min时，交通处于严重拥堵状态；当道路中车辆较多（pin=0.5）、事故持续时间达到5 min时，交通即处于严重拥堵状态。研究结果可为优化城市交通事故处理机制提供依据。     

Simplified multiple equations' inverse problem of vented vessels subjected to internal gas explosions

This paper analyses the experimental data reported by Höchst and Leuckel (1998) for combustion in partially confined vessels and uses the data from these experiments to establish the burning rate based on a simplified model for the combustion process in such vessels. The model establishes three fundamental parameters which are necessary in characterizing the combustion process. These are: i) the burning rate, ii) the fraction of vent area occupied by burnt gas (or discharge sub-model), and iii) the vent area model (if cover mechanisms with variable vent areas are utilized). A set of independent equations is derived to determine the burning rate according to conservation of mass and volume for each gas fraction separately along with a general equation based on general volume conservation. Using this method we are able to describe the combustion process and examine the effect of various discharge models. The advantages of the model presented here include rapid applicability and a valuable analysis to derive mass burn rate and other useful parameters using experimental data from vented explosions with reasonable residual reactant values. Based on these results, the correct interpretation of the obtained burning rate can be used in order to explain the correct prediction of flame velocity and position according to a reasonable discharge model. The paper also evaluates the suitability of several discharge models for phenomenological models of vented explosions. The most appropriate is a Heaviside step function which considers that only unburnt gas is initially expelled, with that component decreasing and the burnt gas component increasing until finally only burnt gas is expelled. The obtained results in this study can be used to predict the burning rate behavior and the combustion process of similar problems.     

Locating the gas leakage source in the atmosphere using the dispersion wave method

A new and simple method for locating emission source was proposed in this work based on gas dynamic dispersion information. The simulation of the unsteady state dispersion of leakage gas emission from the geosequestration project showed that the transportation process of emission gases in the atmosphere is similar to wave propagation, and the time parameter of the dispersion wave is linearly related to the downwind distance. Therefore, monitoring the dispersion wave at different downwind positions can be used to estimate the leakage source position. An estimation formula for locating emission sources was derived. First, an estimation formula for locating emission sources was derived under some initial assumptions. Then, the deviation of the location formula was investigated using a computational fluid dynamics (CFD) model and analytic solution to get the offset distance under different conditions. The results showed that the average distance is stable for a certain atmosphere and terrestrial conditions. This method needs no more than 3 sensors’ dynamic information to locate the emission source, and hence it is highly useful for conditions with limited sensors. A numerical test demonstrated that the absolute error of the source estimation is within the range of 1–30 m. Finally, experimental tests were conducted to verify the feasibility of the source location with dispersion waves. Therefore, the dispersion wave monitor is a potentially simple and feasible way to estimate the source location for gas emission event management with limited sensors in the process industries.     

New tools predict monoethylene glycol injection rate for natural gas hydrate inhibition

In the oil and gas production operations, hydrates deposition leads to serious problems including over pressuring, irreparable damages to production equipment, pipeline blockage, and finally resulting in production facilities shut down and even human life and the environment dangers. Hence, it is of great importance to forecast the hydrate formation conditions in order to overcome problems associated with deposition of hydrate. In this article, an effective, mathematical and predictive strategy, known as the least squares support vector machine, is employed to determine the hydrate forming conditions of sweet natural gases as well as the monoethylene glycol (MEG) flow-rate and desired depression of the gas hydrate formation temperature (DHFT). The outcome of this study reveals that the developed technique offers high predictive potential in precise estimation of this important characteristic in the gas industry. Beside the accuracy and reliability, the proposed model includes lower number of coefficients in contrast with conventional correlations/methods, implying an interesting feature to be added to the modeling simulation software packages in gas engineering.     

城市旅游地景观格局演变与优化研究——以南京为例

城市旅游地景观格局是城市旅游与景观生态共同的研究热点。研究以南京为例,利用Arc GIS技术,以累积耗费距离及旅游地景观演化模型为分析手段,探讨了研究区自1991年以来的景观格局演变与优化问题。结果表明:(1)1991~2003年,旅游景观比重减少而非旅游景观增加;2003~2014年,旅游景观比重增加而非旅游景观递减。景观演化表现为先后台化再旅游化的特征。(2)河湖水面、公园与绿地、建设用地景观形状日趋规则化,林地、交通用地景观形状复杂度不断提升,景观破碎化程度加剧且多样性先上升后下降,表现出快速、高度城市化过程。(3)根据景观生态系统服务功能价值和空间作用,构建生态源地、生态廊道和生态节点等景观组分来加强生态网络的空间联系,提出格局优化方案。(4)非旅游型城市景观应进一步转变为典型旅游景观,以保持景观旅游化及旅游地景观演化的可持续性。     

Study of coal oxidation behaviour in re-opened sealed heating

Possible changes in the oxidation behaviour of coal in the spontaneous combustion site of re-opened sealed heating were studied. Two samples of bituminous coal and three types of coal pre-treatment procedures were applied to simulate in situ conditions at the “spon-com” site: i) pre-oxidation of coal, ii) pre-heating of coal under inert gas, and iii) immersion of pre-heated coal in liquid water. Pre-treated samples were then examined for the production rate of the indication gases evolved during oxidation and for oxidation heat effects. Two main conclusions were drawn with respect to oxidation of the coal in re-opened sealed heating: i) carbon monoxide and unsaturated hydrocarbons maintain their relevance as spontaneous combustion indication gases, however, increased production of both carbon oxides can be expected; ii) coal in the extinguished spontaneous combustion site gains increased susceptibility to the self-heating process.     

新疆入境旅游发展的空间差异及其演变趋势分析

基于新疆2001-2010年旅游外汇收入指标,对新疆入境旅游发展的空间差异和演变趋势进行了定量分析.结果表明：近10年来新疆入境旅游发展的空间格局发生了较大变化,且存在明显的区域极化现象;新疆旅游外汇收入的“省域差异”、“地带内差异”和“北疆差异”变化趋势高度一致;自然条件的显著差异,旅游资源的空间集聚分布以及区位和交通条件的空间差异,是新疆入境旅游空间差异形成的主要影响因素.     

中国居民消费磷足迹时空格局及驱动因素研究

在磷足迹内涵界定及其计算模型构建的基础上,探究了中国城乡居民食物消费磷足迹的时空格局,并解析了其驱动机制.结果表明：1978~2018年间,中国食物消费磷资源和磷污染足迹分别增长了6倍和4倍,达到2018年的715.9万t和78.7万t,其中城镇居民是主要贡献源,占比分别达到67%和64%.从结构上看,城乡食物消费磷资源足迹均由荤食主导,其中家禽、水产品和蛋奶消费的磷资源足迹占比不断增加;而磷污染足迹主要源于上游食物生产过程,其中种植业和水产养殖业增幅最为显著.我国31个省市食物消费磷资源足迹和磷污染足迹在空间分布上具有一致性,呈现从东向西减小的趋势,东部省市诸如广东、上海、江苏、北京和山东等远高于其他地区,并且具有高度的空间集聚性,在东部沿海形成高-高（H-H）聚集区.因此调控磷开发利用活动的资源环境压力需要着眼于这些重点区域.我国食物消费磷足迹增长的关键驱动因素是利用效率下降、消费水平提升和饮食结构改变,因此有效提升食物生产的养分利用效率和引导合理的消费理念和饮食习惯是减缓磷的开发活动资源环境压力的重要途径.