化工园区突发事件应急管理信息系统研究

近年来化工园区突发事件的发生,不仅造成人员和财产的巨大损失,而且造成化工园区周边环境的严重污染,给园区管理者以及各级政府部门带来了巨大的压力和挑战。为了降低和预防化工园区突发事件带来的破坏,本文在利用ArcIMS和专家系统的原理及体系结构的基础上,构建了一种基于ArcIMS平台开发的化工园区突发事件应急管理系统,并对该系统的开发目标、开发环境以及主要功能组成进行了详细的设计与配置,以为化工园区安全规划、应急管理和事故救援工作提供有效的辅助手段。     

基于组织因素的航空安全评价与分析

基于组织因素,从事故类型出发寻找影响航空安全的因素,并采用层次分析法进行评价,得出各个指标因素的权重,确定机组、天气、公司管理是事故链中居于前3位的因素.对机组提出采用"PACE进谏法"和建立人为失误数据库进行训练等建议;针对天气提出改进气象装备,尽早预测并采取措施等建议;对公司管理提出借鉴瑞典航空公司的事前评估、自愿报告免责制度以及安全旁听制度等建议.     

北京餐饮源排放细粒子理化特征及其对有机颗粒物的贡献

调研了北京餐饮业发展现状,通过在线监测、采样分析等手段研究北京4家不同烹调方式的餐馆所排放颗粒物的质量浓度、粒径分布、形貌特征、化学组分,并初步估算餐饮源排放细粒子对北京细粒子中颗粒有机物的贡献.结果表明,餐馆的原料、烹饪过程、油烟去除装置以及客流量都会影响餐馆所排放颗粒物的物理、化学性质.样本餐馆营业期间排放颗粒物PM_{2 .5}质量浓度是当日环境大气PM_{2 .5}质量浓度的8～35倍,PM_{1 .0}在PM_{2 .5}的质量浓度中约占50%～85%.餐饮源排放颗粒物多以固态和液态颗粒物形貌存在,化学组分质量百分数由多到少依次是有机物、无机离子和元素碳,分别占到PM_{2 .5}质量浓度的70%左右、5%～11%和小于2%.初步估计结果表明,北京餐饮源排放细粒子对有机颗粒物的贡献和交通源的排放相当,成为北京细粒子有机颗粒物的主要来源之一.认识餐饮源排放颗粒物的理化性质,可以为改善北京空气质量和保证居民身体健康提供数据支持.     

Chemical cleaning of fouled PVC membrane during ultrafiltration of algal-rich water

Cleaning of hollow-fibre polyvinyl chloride (PVC) membrane with di erent chemical reagents after ultrafiltration of algal-rich water was investigated. Among the tested cleaning reagents (NaOH, HCl, EDTA, and NaClO), 100 mg/L NaClO exhibited the best performance (88.4% 1.1%) in removing the irreversible fouling resistance. This might be attributed to the fact that NaClO could eliminate almost all the major foulants such as carbohydrate-like and protein-like materials on the membrane surface, as confirmed by Fourier transform infrared spectroscopy analysis. However, negligible irreversible resistance (1.5% 1.0%) was obtained when the membrane was cleaning by 500 mg/L NaOH for 1.0 hr, although the NaOH solution could also desorb a portion of the major foulants from the fouled PVC membrane. Scanning electronic microscopy and atomic force microscopy analyses demonstrated that 500 mg/L NaOH could change the structure of the residual foulants on the membrane, making them more tightly attached to the membrane surface. This phenomenon might be responsible for the negligible membrane permeability restoration after NaOH cleaning. On the other hand, the microscopic analyses reflected that NaClO could e ectively remove the foulants accumulated on the membrane surface.     

化学事故应急处置中环保对策的研究

文章分析化学事故中环境污染问题的形成,阐述了化学事故本身对环境的污染和处置不当造成的环境污染,提出我国消防工作在化学事故处置环保方面存在的不足之处,为消防人员处置化学事故做好环保工作提出建议和对策。     

超声波辅助提取雨水管道沉积物中磷的存在形态

在SMT法的基础上采用超声波技术对实验条件进行优化,用于雨水管道沉积物中磷的提取。通过对提取时间、提取温度等影响提取效率的因素进行分析,确定了提高闭蓄态磷提取效率的条件,从而建立了管道沉积物中磷形态分析的最佳条件。在确定的最佳提取条件下对北京城区雨水管道内沉积物中磷的存在形态进行提取,并对不同形态磷的污染水平和分布状况进行分析,结合环境状况等因素对不同形态磷的污染特性进行了综合研究。     

三峡库区(重庆-宜昌段)沉积物中钒的污染特征及生态风险评价

为全面了解三峡库区(重庆—宜昌段)干支流沉积物中钒的含量水平、空间分布、赋存形态、污染程度,在三峡库区采集水体沉积物样品67个,测定了沉积物中钒的含量及其化学赋存形态,并采用地积累指数法和潜在生态危害指数法进行分析和评价.结果表明:1三峡库区研究区范围内沉积物中钒的含量范围为89.4~175.2 mg·kg-1,平均值为123.7 mg·kg-1,略高于长江沉积物背景值;2库区沉积物中钒的空间分布特征主要呈现库区干流含量大于支流,干流下游沉积物中钒含量高于上游;3沉积物中钒含量的极值点出现在较发达县(区)附近,考虑其来源可能是人为源汇入;4库区沉积物中钒的赋存形态主要以残渣态为主,所占质量分数为80%~89%,并与总量呈现显著正相关关系;5沉积物中钒污染程度较小,潜在环境危害影响较弱.     

Effect of a high strength chemical industry wastewater on microbial community dynamics and mesophilic methane generation

A high strength chemical industry wastewater was assessed for its impact on anaerobic microbial com- munity dynamics and consequently mesophilic methane generation. Cumulative methane production was 251 mL/g total chemical oxygen demand removed at standard temperature and pressure at the end of 30 days experimental period with a highest recorded methane percentage of 80.6% of total biogas volume. Volatile fatty acids （VFAs） analysis revealed that acetic acid was the major intermediate VFAs produced with propionic acid accumulating over the experimental period. Quantitative analysis of microbial communities in the test and control groups with quantitative real time polymerase chain reaction highlighted that in the test group, Eubacteria （96.3%） was dominant in comparison with methanogens （3.7%）. The latter were dominated by Methanomicrobiales and Methanobacteriales while in test groups increased over the experimental period, reaching a maximum on day 30. Denaturing gradient gel electrophoresis profile was performed, targeting the 16S rRNA gene of Eubacteria and Archaea, with the DNA samples extracted at 3 different time points from the test groups. A phylogenetic tree was constructed for the sequences using the neighborhood joining method. The analysis revealed that the presence of organisms resembling Syntrophomonadaceae could have contributed to increased production of acetic and propionic acid intermediates while decrease of organisms resembling Pelotomaculum sp. could have most likely contributed to accumulation of propionic acid. This study suggested that the degradation of organic components within the high strength industrial wastewater is closely linked with the activity of certain niche microbial communities within eubacteria and methanogens.     

创新应对重大环境事件思维推动环保战略转型

本文系环境保护部原总工程师、中国环境科学学会副理事长杨朝飞在“2013年全国环境政策法制工作研讨会”上做的关于我国如何应对重大环境事件专题讲座内容整理,以飨读者.     

危险废物回转窑焚烧系统的控制参数分析及调节方法研究

随着我国经济的迅速发展,危险废物产量持续增长,它们带来了严重的社会危害和环境危害。焚烧法是一种高温热处理技术,危险废物通过焚烧处理可实现无害化、减量化和资源化。回转窑焚烧系统具有处置范围广、处理量大、焚毁率高、安全可靠和可长期持续运行等特点,被国内外广泛应用。文章通过分析回转窑焚烧系统的主要控制参数,根据工程运行的实际经验,绘制了回转窑焚烧系统控制参数和焚毁率关系图,并提出了“最佳焚烧区域”的概念,对于回转窑焚烧系统的调试和运行工作,有积极的指导作用和重要的现实意义。