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921.
Teuchies J de Deckere E Bervoets L Meynendonckx J van Regenmortel S Blust R Meire P 《Environmental pollution (Barking, Essex : 1987)》2008,155(1):20-30
A historical input of trace metals into tidal marshes fringing the river Scheldt may be a cause for concern. Nevertheless, the specific physicochemical form, rather than the total concentration, determines the ecotoxicological risk of metals in the soil. In this study the effect of tidal regime on the distribution of trace metals in different compartments of the soil was investigated. As, Cd, Cu and Zn concentrations in sediment, pore water and in roots were determined along a depth profile. Total sediment metal concentrations were similar at different sites, reflecting pollution history. Pore water metal concentrations were generally higher under less flooded conditions (mean is (2.32 ± 0.08) × 10−3 mg Cd L−1 and (1.53 ± 0.03) × 10−3 mg Cd L−1). Metal concentrations associated with roots (mean is 202.47 ± 2.83 mg Cd kg−1 and 69.39 ± 0.99 mg Cd kg−1) were up to 10 times higher than sediment (mean is 20.48 ± 0.19 mg Cd kg−1 and 20.42 ± 0.21 mg Cd kg−1) metal concentrations and higher under dryer conditions. Despite high metal concentrations associated with roots, the major part of the metals in the marsh soil is still associated with the sediment as the overall biomass of roots is small compared to the sediment. 相似文献
922.
Chowdhury AG Das C Kole RK Banerjee H Bhattacharyya A 《Environmental monitoring and assessment》2007,131(1-3):467-473
A detailed study has been presented on heavy metal content of the Iture Estuary. Waters of the Sorowie and Kakum rivers that
supply water into the Estuary were investigated to ascertain heavy metal pollution levels due to anthropogenic activities.
Concentration s of Cd, Zn, Se and Pb were measured. The study shows pre-occupying pollution levels that constitute a threat
to both terrestrial and aquatic ecosystems. The abundance of metals in the Estuary is in the order Zn > Pb > Cd > Se. The
level of Cd in the Iture Estuary ranged between 0.011 mg/l and 0.041 mg/l while Se was in the range 0.018 mg/l to 0.029 mg/l,
Pb 0.020 mg/l to 0.075 mg/l and Zn 0.040 to 2.45 mg/l. The impact of contaminated water from the Sorowie River on the Iture
Estuary was outstanding and the study points out the importance of the Sorowie River as a primary pollution source to the
Iture Estuary. The pollution of the Iture Estuary was found to be connected to human activities in its catchments. 相似文献
923.
Cadmium and lead were determined simultaneously in seawater by differential pulse stripping voltammetry (DPSV) preceded by
adsoptive collection of complexes with 8-hydroxyquinoline (oxine) on to a hanging mercury drop electrode (HMDE). In preliminary
experiments the optimal analytical condition for oxine concentration was found to be 2.10−5 M, at pH 7.7, the accumulation potential was −1.1 V, and the initial scannig potential was −0.8 V. The peak potentials were
found −0.652 V for Cd and −0.463 V for Pb At the 60 s accumalation time. The limit of detection (LOD) and limit of quantitatification
(LOQ) were found to be by voltammetry as 0.588 and 1.959 μg l−1 (RSD, 5.50%) for Cd and 0.931 and 3.104 μg l−1 (RSD, 4.10%) for Pb at 60 s stirred accumulation time respectively. In these conditions the most of the seawater samples
are amenable for direct voltammetric determination of cadmium and lead using a HMDE. An adsorptive stripping mechanism of
the electrode reaction was proposed. For the comparison, seawater samples were also analysed by ICP-atomic emission spectrometry
method (ICP-AES). The applied voltammetric technique was validated and good recoveries were obtained. 相似文献
924.
Naszradi T Badacsonyi A Keresztényi I Podar D Csintalan Z Tuba Z 《Environmental monitoring and assessment》2007,134(1-3):279-285
Moss transplants of Tortula ruralis were used as active biomonitoring organisms as part of a monitoring study to assess the metals (Al, Cd, Cu, Cr, Fe, Ni, Pb, V and Zn) associated with ambient particles on mosses in Budapest, the capital town of Hungary. The moss samples were collected in a nature conservation area from a semi-arid sand grassland (Festucetum vaginatae danubiale), less than 1 month before transplantation. Moss cushions were exposed to pollution in Budapest during October–November 1993 and February–March 1994. In the study area, 16 sites were marked out as measuring sites, in accordance with the structure of the city. A similar stand was established in the Botanical Gardens of the Szent István University in Gödöll? as a control site. ICP-AES analysis of moss for metals showed the ability of Tortula ruralis to accumulate the metals under study. Control site showed lower impact in comparison to the other sites. 相似文献
925.
Heavy metal contamination in sediments of the Karasu spring was investigated in the presented study. In this respect, sediment
samples were collected from contaminant sites along the spring starting from the spring water manifestation site, base of
the Akkaya dam to the dam exit site. Heavy metal concentrations were determined by X-ray Fluorescence Spectrometer. Cobalt,
copper, arsenic, tin, nickel, zinc, cadmium, lead, aluminum, iron, titan, chromium and manganese contents of the Karasu creek
sediments are found as 18.30–69.00, 12.40–595.0 5.50–345.3, 5.80–15.1, 10.9–64.1, 28.90–103,300, 4.1–356.2, 7.70–37,840, 13,460–109,400,
11,740–62,900, 22.18–59.04, 41.70–369 and 12.09–3,480 mg/kg, respectively. Results indicate the presence of a contamination
in the Karasu creek. All the metal concentrations were found to be exceeding their acceptable limit values. Eutrophication
is developed in the Karasu creek and the Akkaya dam. It is thought that heavy metal accumulation in the creek is originated
from discharge from mine quarries, industrial and domestic wastes. Protection zones should be defined and all necessary measures
must be taken along the Karasu creek. 相似文献
926.
Demirel Z 《Environmental monitoring and assessment》2007,132(1-3):15-23
In this study, heavy metal contents of groundwater from the Mersin aquifer were determined with photometric methods and used
to determine the main factors controlling the pollution of groundwater in the area. Using MapInfo GIS software, spatial analysis
and integration were carried out for mapping drinking water quality in the basin. From the photometric heavy metal analysis,
it is inferred that the excess concentration of Fe, Ni, Mn, Mo and Cu at some locations is the cause of undesirable quality
for drinking purposes. Similarly, the EC thematic map shows that considerable areas in the basin are having high salinity
hazards. The reason for excess concentration of various heavy metals is the industrial activities and petroleum pipelines
and salinity levels show the sea water intrusion. 相似文献
927.
In this work, water and sediment samples were collected from three different stations located along the Sakarya river between
May and September 2003. Lead, copper, chromium, zinc, nickel and cadmium concentrations were determined by using solvent extraction
and flame atomic absorption spectrometric method. The results show that differences based upon sampling times, regions, sediment
and water samples were observed. The mean levels of copper, nickel, chromium, lead, cadmium, zinc for sediment samples are;
4.630 μg g−1, 13.520 μg g−1, 8.780 μg g−1, 2.550 μg g−1, 9.990 μg g−1 and for water samples are; 0.851 μg g−1, 1.050 μg g−1, 0.027 μg g−1, 1.786 μg g−1, 0.236 μg g−1, 0.173 μg g−1, respectively. 相似文献
928.
Syed S 《Environmental monitoring and assessment》2007,130(1-3):311-322
‘Metal ash’ presents a waste disposal problem in most of the developing countries as the industries employ obsolete technologies.
In this paper we describe analysis of tin ash, zinc ash and aluminium ash by means of optical methods, such as X-ray diffraction
(XRD), inductively coupled plasma mass spectrometry (ICP-MS), electron probe micro analysis (EPMA), scanning electron microscopy
(SEM) and chemical methods. The results of tin ash obtained by XRD method matched well with the cassiterite, a naturally occurring
mineral of tin. ICP-MS studies reveal the presence of a large number of tracer metals, which may cause pollution by tertiary
dispersion and this aspect is discussed. Conversely, the data generated by chemical methods are limited. However, the methods
are simple and cost-effective. Then, they can easily be adopted by low-budget industries. Simple and cost-effective process
to recover tin from tin ash is described. It is based on heating tin ash with sodium cyanide to about 900°C to separate tin
component from the metal ash. The process recovers good quality tin and offers a very high yield. The process can be scaled
up to small pilot plant. 相似文献
929.
Heavy Metal Concentrations in Water, Sediment, Fish and Some Benthic Organisms from Tigris River, Turkey 总被引:4,自引:0,他引:4
In this study concentrations of heavy metals, such as Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn were determined in water, sediment,
muscle, liver and gill of fish (Silurus triostegus, Mastacembelus simack, Mystus halepensis, Orthrias euphraticus) the muscle and liver of crab (Potamon fluviatilis), the internal organs of fresh water snail (Physa acuta), and mussel (Unio elongatulus), and in whole biomass of green algae (Spirogyra sp.) examples collected seasonally from three selected sites (I, II, and III) of Tigris River and from a reference site on
Resan Creek. In general, the average Cd, Cu, Mn, Ni, Zn, and Fe values in Sites I, II, and III were found to be high in spring
and summer. The concentrations of heavy metals in the Tigris River are compared with previous studies in the same sites. The
results showed that Cu levels have gradually decreased during recent years. In Tigris River, among the living organisms, i.e.,
those which are living in benthic region and showing biomonitor characteristic, crab, snail, green algae, mussel and fish
are seen to be formed in sequence. Cu, Fe, Mn and Zn values obtained from the muscle of fish and from the mass of internal
organs of mussel and snail were found to be under the acceptable values suggested. 相似文献
930.
Kimiran-Erdem A Arslan EO Sanli Yurudu NO Zeybek Z Dogruoz N Cotuk A 《Environmental monitoring and assessment》2007,125(1-3):219-228
A hundred Enterococcus strains were isolated from seawater samples collected from coastal areas of Istanbul. Isolates were identified to the species
level using standard biochemical tests specified by Facklam and Collins. The species distribution was as follows Enterococcus
faecalis (96%), Enterococcus gallinarum (3%) and Enterococcus solitarius (1%). The resistance of bacteria to both heavy metals (zinc [Zn], iron [Fe], cadmium [Cd], chrome [Cr], cobalt [Co]) and
antibiotics (ampicillin 10 μg [AP], penicillin G 10 Units [PG], gentamycin 10 μg [GM], streptomycin 10 μg [S], chloramphenicol
10 μg [C], erythromycin 15 μg [E], kanamycin 30 μg [K], amikacin 30 μg [AK], nalidixic acid 30 μg [NA], and vancomycin 30 μg
[VA]) was evaluated. None of the strains was resistant to VA. It was found that among the 100 isolates, those that exhibit
resistance to antibiotics, particularly NA, S and K, were also resistant all the heavy metals tested. To our knowledge this
is the first report focusing on determination of resistance of environmental enterococci found in Istanbul against heavy metals
and antibiotics. Thus, combined expressions of antibiotic and heavy metal resistance may help to reinforce ecological and
epidemiological studies and to determine the role of these strains in antibiotic and heavy metal resistance dissemination. 相似文献