基于节点流量校核的供水管网爆管定位研究

针对目前基于节点压力变化定位供水管网爆管的方法,当供水管网中泵切换时,导致定位爆管位置存在误报的问题,提出了基于节点流量校核的管网爆管定位方法.利用奇异矩阵法推导出节点流量灵敏度矩阵,采取奇异矩阵中的最优搜索向量计算方法找到节点流量变化位置,确定爆管管道.首先,将该方法应用于一个小管网,阐述基于节点流量校核的管网爆管定...     

Optimal biomass allocation in heterogeneous environments in a clonal plant—Spatial division of labor

When interconnected ramets of clonal plants are growing in heterogeneous environments, ramets may specialize to uptake locally abundant resources rather than scarce resources. This biomass allocation pattern may result in more efficient sharing of resources through physiological integration and an overall benefit to the plants (spatial division of labor; DoL).     

Non-Fickian dispersion in a single fracture

Solute transport in fractured rocks is of major interest in many applications, from the petroleum industry to ground water management. This work focuses on the dispersion process in a transparent replica of a real single fracture. The fracture exhibits strong changes in heterogeneity, with the first half very heterogeneous and the second half fairly homogeneous. Three models have been used to interpret the tracer experiments: the classical advection-dispersion equation (ADE), the continuous time random walk (CTRW), and the stratified model. The main goals were to test these models and to study possible correlations between fitting parameters and heterogeneities. As expected, the solution derived from the ADE equation appears to be unable to model long-time tailing behavior. On the other hand, the results confirm the CTRW robustness and the coefficient beta seems well correlated to heterogeneities. Finally, the stratified model is also able to describe non-Fickian dispersion. The parameters defined by this model are correlated to the heterogeneities of the fracture.     

The explosion of non-nano iron dust suspension in the 20-l spherical bomb

The understanding of dust explosion is still incomplete because of the lack of reliable data and accurate models accounting for all the physic-chemical aspects. Besides, most of the experimental data available in the current literature has been accumulated on the 20-l spherical bomb tests, which gives coarse results for the pressure history that cannot be easily converted into fundamental combustion parameters. Nevertheless, the large amount of experimental data available in the spherical bomb is attractive. In this work, the explosion of non-nano iron dust in the standard spherical vessel is analyzed, aiming at evaluating the burning velocity from the theoretical point of view and the simple experiments performed by the standard explosion tests. The choice of iron is of relevance because its adiabatic flame temperature is below the boiling temperature of both the reactants and oxidized gaseous, liquid, or solid (intermediate and final) products and for the negligible particle porosity, which instead is typical of organic dust. Therefore, a non-nano iron dust explosion can be reconducted to a reduced mechanism since heterogeneous (surface) combustion may be determinant, and the diffusion mechanism for oxygen is the only relevant. The laminar burning velocity is strongly dependant on the particle diameter, whereas little effects are due to the dust concentration. The reported final value was found in agreement with typical limiting laminar burning velocity, adopted for the estimation of flammability limits.     

The effects on welfare of the imposition of individual transferable quotas on a heterogeneous fishing fleet

This paper examines the determination of effort levels, the rental price of quotas and the number of participants in a fishery managed with a total allowable catch and individual transferable quotas. How these variables change is determined for three phases of the management process. Potential participants in the fishery are assumed to be heterogeneous in their catching capabilities so that almost all active fishers earn positive net profits from fishing activities. It is shown that these quasirents are reduced during any of the management phases considered here. The impact of free allocations of permanent quota rights on fishers’ welfare is also considered. This may increase the welfare of all fishers if the allocation is based on catch history. However, an example is provided where the welfare of some highliners is reduced when the allocation is based on effort history.     

Functionalization of nitrogen-doped graphene quantum dot: A sustainable carbon-based catalyst for the production of cyclic carbonate from epoxide and CO2

A series of organic compounds were successfully immobilized on an N-doped graphene quantum dot (N-GQD) to prepare a multifunctional organocatalyst for coupling reaction between CO₂ and propylene oxide (PO). The simultaneous presence of halide ions in conjunction with acidic- and basic-functional groups on the surface of the nanoparticles makes them highly active for the production of propylene carbonate (PC). The effects of variables such as catalyst loading, reaction temperature, and structure of substituents are discussed. The proposed catalysts were characterized by different techniques, including Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy/energy dispersive X-ray microanalysis (FESEM/EDX), thermogravimetric analysis (TGA), elemental analysis, atomic force microscopy (AFM), and ultraviolet–visible (UV-Vis) spectroscopy. Under optimal reaction conditions, 3-bromopropionic acid (BPA) immobilized on N-GQD showed a remarkable activity, affording the highest yield of 98% at 140°C and 10⁶ Pa without any co-catalyst or solvent. These new metal-free catalysts have the advantage of easy separation and reuse several times. Based on the experimental data, a plausible reaction mechanism is suggested, where the hydrogen bonding donors and halogen ion can activate the epoxide, and amine functional groups play a vital role in CO₂ adsorption.     

Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process

Sewage sludge from a biological wastewater treatment plant was converted into sewage sludge based activated carbon(SBAC) with Zn Cl2 as activation agent, which was used as a support for ferric oxides to form a catalyst(Fe Ox/SBAC) by a simple impregnation method.The new material was then used to improve the performance of Fenton oxidation of real biologically pretreated coal gasification wastewater(CGW). The results indicated that the prepared Fe Ox/SBAC significantly enhanced the pollutant removal performance in the Fenton process, so that the treated wastewater was more biodegradable and less toxic. The best performance was obtained over a wide p H range from 2 to 7, temperature 30°C, 15 mg/L of H2O2 and 1 g/L of catalyst, and the treated effluent concentrations of COD, total phenols,BOD5 and TOC all met the discharge limits in China. Meanwhile, on the basis of significant inhibition by a radical scavenger in the heterogeneous Fenton process as well as the evolution of FT-IR spectra of pollutant-saturated Fe Ox/BAC with and without H2O2, it was deduced that the catalytic activity was responsible for generating hydroxyl radicals, and a possible reaction pathway and interface mechanism were proposed. Moreover, Fe Ox/SBAC showed superior stability over five successive oxidation runs. Thus, heterogeneous Fenton oxidation of biologically pretreated CGW by Fe Ox/SBAC, with the advantages of being economical, efficient and sustainable, holds promise for engineering application.     

环境因子对某新型延时起爆装置性能影响研究

目的研究环境因子对某火工元件延时性能和输出能量的影响。方法根据某型延时起爆装置的组成结构特点,依据火工品试验法、军械装备环境试验法,结合极限使用环境条件设计了高温高湿、温度冲击试验。结果高温高湿的延迟时间范围为260~630 ms;温度冲击的延迟时间范围为283~513 ms,高温高湿输出能力范围为13~17 mm,温度冲击输出能力范围为13~18 mm。结论高温高湿试验对延迟时间影响较大,出现超出指标的延迟时间。     

温压炸药弹内爆轰特性试验研究

研究温压炸药爆炸初期弹内爆炸波作用过程,可以进一步分析温压炸药分散爆轰的作用机理,为温压炸药武器设计和系统优化提供可靠依据.设计了用测时法研究温压炸药爆轰波传播速度的试验装置,并用探针对相同组分和密度条件下、温压战斗部弹内爆炸初期的爆炸作用过程进行了对比试验,记录了触发时间信号,计算并分析了温压炸药弹内爆炸波的传播特性,得到了波阵面与弹径方向夹角α的变化规律.试验结果表明,温压炸药的爆轰波传播速度为4.632km/s,其弹内爆轰波的传播特性与中心高能分散药的爆轰波有密切联系,通过合理设计弹体结构和比药量,可以实现温压炸药的分散爆轰,提高温压炸药的爆炸威力.     

采空区遗煤自燃过程及其规律的数值模拟研究

基于非均质多孔介质中的连续性方程、多相气体渗流———扩散方程和综合传热方程,建立了工作面动态推进下的采空区自燃数值模型。结合实例,从理论上描绘了工作面开采过程中采空区的漏风流态、氧、CO、瓦斯和温度等分布状态及其动态过程。计算中考虑了瓦斯涌出对自燃的耦合作用;工作面动态推进对自燃的影响,以及沿边界冒落非压实性对漏风供氧、自燃高温区产生的影响。从理论上重点讨论了采空区自燃与各因素的定量化关系,得出自然发火期与煤氧化速度、工作面风量二者均呈显著的反比例关系;对于综放工作面采场漏风供氧系统,自然发火期主要取决于煤的耗氧能力,提高工作面风量仅能扩大自燃高温区的范围,增大自燃的发生几率;提高推进度能显著延长采空区自然发火期,呈指数变化。