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511.
以改性海泡石为载体,采用浸渍-共沉淀法负载Cu0、MnO制备了中性条件下催化H_2O_2氧化催化剂(简称中性催化剂)。以铝材切削液废水为处理对象,研究了催化剂在中性条件下的催化性能,通过投加不同浓度的羟基自由基捕捉剂叔丁醇,对反应机理进行了探讨,同时研究了过氧化氢用量、催化剂用量等因素对废水COD去除率的影响。结果表明:在中性条件下,催化剂对铝材切削液废水具有较高的COD去除率,当过氧化氢用量为1.25 mol/L,催化剂用量为25 g/L,室温条件反应120 min时,COD去除率达到88%;经该方法处理后,废水ρ(BOD5)/ρ(COD)由处理前的0.09提升到处理后的0.36,可生化性得到了明显提高。 相似文献
512.
在碱性介质中,鲁米诺和过氧化氢能产生稳定的发光信号,Pb2+-EDTA络合物对鲁米诺-过氧化氢体系的化学发光产生微弱的抑制作用,而表面活性剂吐温-80的加入可以改变发光体系的微环境性质,从而对化学发光体系起到增敏作用。据此建立测定环境水样中痕量Pb2+的流动注射化学发光分析方法。此方法用于测定环境水样中Pb2+的含量,具有检出限高,操作简便,分析速度快等优点。 相似文献
513.
514.
A numerical simulation of the spontaneous ignition of high-pressure hydrogen in a duct with two obstacles on the walls is conducted to explore the spontaneous ignition mechanisms. Two-dimensional rectangular ducts are adopted, and the Navier–Stokes equations with a detailed chemical kinetic mechanism are solved by using direct numerical simulations. In this study, we focus on the effects of the initial pressure of hydrogen and the position of the obstacles on the ignition mechanisms. Our results demonstrate that the presence of obstacles significantly changes the spontaneous ignition mechanisms producing three distinct ignition mechanisms. In addition, the position of the obstacles drastically changes the interaction of shock waves with the contact surface, and spontaneous ignition may take place at a relatively low pressure in some obstacle positions, which is attributed to the propagation direction and interaction timing of two reflected shock waves. 相似文献
515.
A series of medium-scale experiments on vented hydrogen deflagration was carried out at the KIT test side in a chamber of 1 × 1 × 1 m3 size with different vent areas. The experimental program was divided in three series: (1) uniform hydrogen–air mixtures; (2) stratified hydrogen–air mixtures within the enclosure; (3) a layer deflagration of uniform mixture. Different uniform hydrogen–air mixtures from 7 to 18% hydrogen were tested with variable vent areas 0.01–1.0 m2. One test was done for rich mixture with 50% H2. To vary a gradient of concentration, all the experiments with a stratified hydrogen–air mixtures had about 4%H2 at the bottom and 10 to 25% H2 at the top of the enclosure. Measurement system consisted of a set of pressure sensors and thermocouples inside and outside the enclosure. Four cameras combined with a schlieren system (BOS) for visual observation of combustion process through transparent sidewalls were used. Four experiments were selected as benchmark experiments to compare them with four times larger scale FM Global tests (Bauwens et al., 2011) and to provide experimental data for further CFD modelling. The nature of external explosion leading to the multiple pressure peak structure was investigated in details. Current work addresses knowledge gaps regarding indoor hydrogen accumulations and vented deflagrations. The experiments carried out within this work attend to contribute the data for improved criteria for hydrogen–air mixture and enclosure parameters to avoid unacceptable explosion overpressure. Based on theoretical analysis and current experimental data a further vent sizing technology for hydrogen deflagrations in confined spaces should be developed, taking into account the peculiarities of hydrogen–air mixture deflagrations in presence of obstacles, concentration gradients of hydrogen–air mixtures, dimensions of a layer of flammable cloud, vent inertia, etc. 相似文献
516.
One of conservation transfer methods for such widely-used gases as natural gas and hydrogen is buried pipelines. Safety of these pipelines is of great importance due to potential risks posed by inefficiencies of the pipelines. Therefore, an accurate understanding of release and movement characteristics of the leaked gas, i.e. distribution and speed within soil, the release to the ground surface, the movement of hydrogen gas through the ground, gas underground diffusion, gas dispersion in atmosphere, and following consequences, are very important in order to determine underground dispersion risks. In the present study, consequences of gas leakage within soil were evaluated in two sub-models, i.e. near-field and far-field, and a comprehensive model was proposed in order to ensure safety of buried gas supply pipelines. Near-field model which is related to soil and ground and its output is the gas released at different points and times from ground surface and it was adopted as input of far-field sub-model which is dispersion model in atmosphere or an open space under the surface. Validation of near-field sub-model was performed by the experimental data obtained by Okamoto et al. (2014) on full-scale hydrogen leakage and then, possible scenarios for far-field sub-model were determined. 相似文献
517.
518.
Analytical models or abacus are of importance to predict explosion effects in open and congested areas for industrial safety reasons. The goal of this work is to compare overpressure and flame speed values of small-scale deflagration experiments to predicted values from the TNO multi-energy (TNO ME) method and the Baker-Strehlow-Tang (BST) method. Experiments were performed in cylindrical congested volumes of hydrogen – air mixtures varying from 1.77 L to 7.07 L. The reactivity was controlled by the equivalence ratio of hydrogen-air mixtures, ranging from 0.5 to 2.5. The congestion was realized with varying numbers of grid layers and configurations. The influence of the obstacle density and the importance of the mixture reactivity to choose the strength index in order to predict the effects of an explosion has been highlighted for the TNO ME method. Predictive flame speed values from the BST method are in accordance with almost half of the experimental results and the method is conservative in most tested configurations. The use of the TNO ME method has been validated on a small-scale experiment to predict maximal overpressures generated by the deflagration of medium and large-scale H2/air clouds. 相似文献
519.
520.
The process of producing synthetic gas from waste plastics by steam reforming was investigated. To evaluate this process,
the steam reforming of the oils derived from low-density polyethylene and polystyrene were carried out using a laboratory-scale
fluidized bed of Ni-Al2O3 catalysts. The performance of gasification in terms of carbon conversion, gas yield, and gas compositions was examined. Although
oils derived from plastics contain many kinds of heavy hydrocarbons and aromatics, they were well gasified at temperatures
above 1023 K with a steam/carbon ratio of 3.5 and a weight hourly space velocity of 1 h−1. The hydrogen content of the product gas was very high at approximately 72 vol% for polyethylene-derived oil and 68 vol%
for polystyrene-derived oil. These compositions agreed well with the values calculated from chemical equilibrium. 相似文献