Al（Ⅲ）溶液的水解─沉淀特性研究─—磷酸根的作用

采用连续碱滴定方法和Ｘ射线衍射及红外光谱分析，研究了在Ａｌ（Ⅲ）－磷酸根溶液体系中Ａｌ（Ⅲ）的水解－沉淀特性，结果表明，当Ｐ／Ａｌ＞０．０５时，磷酸根对Ａｌ（Ⅲ）的水解－成核－沉淀过程有显的促进作用，描述了磷酸根作用的动力学机理。     

沉淀—树脂吸附法处理对氨基偶氮苯盐酸盐生产废水的研究

对氨基偶氮苯盐酸盐（ＰＡＢＳ）是生产染料的重要中间体。在ＰＡＢＳ生产过程中，排放出高浓度（ＣＯＤ４万～８万ｍｇ／Ｌ）、高色度（４万～８万）、高毒性（含苯胺和对氨基偶氮苯）和高氯（Ｃｌ－４万～１０万ｍｇ／Ｌ）的废水。利用中和沉淀—大孔吸附树脂吸附法进行了处理工艺的小试研究。结果表明，废水色度去除率达到９９９％，降到２０以下；出水中基本不含对氨基偶氮苯（ＰＡＢ）；出水中苯胺的浓度降到３ｍｇ／Ｌ。ＧＣ／ＭＳ分析的结果表明，乙醇脱附液中苯胺是最主要的有机物，所以利用该工艺能实现苯胺的回收。     

Influence of no-tillage on the distribution and lability of phosphorus in Finnish clay soils

No-tillage (NT) is a method adopted to reduce erosion and particulate phosphorus (P) load from arable land to watercourses. However, it has been found to increase the loss of dissolved P with surface runoff, but the reasons for that have rarely been examined in detail. The objective of the present study was to determine the chemical factors explaining this response by investigating the impact of NT on the type and distribution of P reserves as well as on organic carbon (C) in the 0–35 cm topsoil layer of clay soil profiles (Vertic Cambisols). Soil samples were taken from two experimental fields (Jokioinen and Aurajoki) at 0–5, 5–20 and 20–35 cm depths in conventionally tilled (CT) and non-tilled (for 4–5 years) plots. The plots had been cultivated and fertilized according to the common field practices in Finland (15–18 kg P and 100–128 kg N ha⁻¹ year⁻¹).Inorganic and organic P reserves characterized by a modified Chang and Jackson fractionation procedure were not significantly affected by the cultivation methods. However, in the uppermost soil layer (0–5 cm) in NT of the Jokioinen field, the labile P determined by water extraction (P_w) increased significantly, whereas the increase in P extracted with acid ammonium acetate (P_AAC) remained statistically insignificant. The increase in labile P coincided with a significant increase in organic carbon (C), which supports the theory that competition between organic anions and phosphate for the same sorption sites on oxide surfaces will enhance the lability of soil P. In the Aurajoki field with distinct soil cracking, P_w and P_AAC were not affected by NT in the uppermost soil layer, but they increased in the deepest soil layer (20–35 cm) concomitantly with an increase in Al-bound P and organic C. However, the increases were not statistically significant. In both fields, soil acidification due to the repeated application of N fertilizers at a shallow soil depth as well as the accumulation of organic C lowered pH of the uppermost soil layer in NT compared to the deeper soil layers. The results indicated that even short-term NT can increase the labile P in clay soil. However, further studies are needed to assess the long-term changes in lability of surface soil P and, consequently, the possible need for readjustment of the fertilization level in NT.     

底泥盐分释放对北塘水库水质成化的影响

为研究南水北调通水后,水源改变及水库调度对底泥盐分释放的影响,2005年7月,取0～60cm深度的北塘水库原状底泥样品,在实验室内模拟分析不同底泥含盐量、不同蓄水水质及水位变动和扰动条件下底泥氯化物释放规律。结果表明,底泥中Cl~-含量为0.043%,释放强度为0.12g/m~2·d,Cl~-含量越高,释放强度越大。在底泥含盐量相同的条件下,蓄去离子水的底泥Cl~-释放强度是蓄水库水的1.87倍。扰动状态下,底泥中的Cl~-有5.0%～9.5%释放出来,高于静止状态的3.2%～5.6%。水库运行水位发生变化,将影响底泥盐分的释放。1.0m水深条件下Cl~-的释放量是1.5m水深的5.8倍。水库四周地下水中Cl~-浓度为8.0×10~3～4.2×10~4mg/L,远高于目前水库水的Cl~-浓度。因此,一定要避免水库在低于设计低水位和周边地下水水位的条件下运行,防止底泥盐分释放及地下水反向补给造成水库水质的成化。     

河口水质氨氮的自动监测影响因素研究

作了国内首台营养盐连续监测分析仪对光波长、显色时间、样品盐度、显色剂储存时间、测定过程的气泡等影响因素的分析 ,自动分析时这些因素可被控制使结果稳定。将测定结果与国家标准方法作比较 ,表明能较好吻合     

青海省盐湖卤虫资源的开发与保护--以尕海湖为例

通过在青海省的实地考察和对尕海湖周边植被的调查，总结出造成青海省尕海湖卤虫产量减少的影响因素，得出防治对策，并对若干卤虫开发利用的问题进行了讨论，为青海省卤虫资源的保护与开发提供参考。     

电力系统的污闪问题及防护

重点介绍了有关防污闪机理,深入研究并探讨了四种防污闪的常用技术和方法,分析了绝缘子从积污、湿润到闪络的详细过程,并通过附盐密度法绘制了盐密与闪络电压的关系,为防污闪工作提供理论指导。     

三种强度准则的盐穴应力弹塑性解及参数敏感性分析

为了更安全地建造地下盐穴储气库，采用Hoek-Brown(H-B)，Mohr-Coulomb(M-C)及Drucker-Prager(D-P)3种强度准则，推导了在内压作用下盐穴的塑性区应力解及塑性半径，讨论了各准则对塑性区半径的影响规律及各准则参数的估计方法。分别运用单因素分析法及多因素分析法，分析了塑性半径对H-B准则参数的敏感性。研究结果表明:同等条件下，H-B准则受岩性、造腔等因素影响时，微小内压的波动使得塑性半径的变化更剧烈，岩体质量较差时更显著。盐穴塑性应力与M-C，D-P相比偏小，更接近实际工程状况。围岩塑性半径受H-B准则参数影响程度的大小依次为:GSI，mi，σci，D。各参数的互相关性对结果影响不大。其中，H-B准则参数GSI，mi，σci的增大会使塑性半径减小，参数D的增大使得塑性区半径增大。研究成果可为合理选择盐穴储库硐室的力学模型及优化参数提供参考价值。     

Using environmental heterogeneity to plan for sea‐level rise

Environmental heterogeneity is increasingly being used to select conservation areas that will provide for future biodiversity under a variety of climate scenarios. This approach, termed conserving nature's stage (CNS), assumes environmental features respond to climate change more slowly than biological communities, but will CNS be effective if the stage were to change as rapidly as the climate? We tested the effectiveness of using CNS to select sites in salt marshes for conservation in coastal Georgia (U.S.A.), where environmental features will change rapidly as sea level rises. We calculated species diversity based on distributions of 7 bird species with a variety of niches in Georgia salt marshes. Environmental heterogeneity was assessed across six landscape gradients (e.g., elevation, salinity, and patch area). We used 2 approaches to select sites with high environmental heterogeneity: site complementarity (environmental diversity [ED]) and local environmental heterogeneity (environmental richness [ER]). Sites selected based on ER predicted present‐day species diversity better than randomly selected sites (up to an 8.1% improvement), were resilient to areal loss from SLR (1.0% average areal loss by 2050 compared with 0.9% loss of randomly selected sites), and provided habitat to a threatened species (0.63 average occupancy compared with 0.6 average occupancy of randomly selected sites). Sites selected based on ED predicted species diversity no better or worse than random and were not resilient to SLR (2.9% average areal loss by 2050). Despite the discrepancy between the 2 approaches, CNS is a viable strategy for conservation site selection in salt marshes because the ER approach was successful. It has potential for application in other coastal areas where SLR will affect environmental features, but its performance may depend on the magnitude of geological changes caused by SLR. Our results indicate that conservation planners that had heretofore excluded low‐lying coasts from CNS planning could include coastal ecosystems in regional conservation strategies.     

西大海湖沉积物营养盐垂直分布特征变化分析

通过对西大海湖心柱状沉积岩芯有机质(OM)、总氮(TN)、总磷(TP)、磷形态和粒度指标的测试和分析,探讨其垂向分布特征及影响因素.结果表明,营养盐中OM、TN和TP的含量分别为0.633%~2.756%、0.150%~0.429%和648.00~1 480.67 mg·kg-1.Ca-P是TP的主要部分,占TP含量66.04%.1843~1970年间,Ca-P、IP、OM含量变化较小,Fe/Al-P、OP、TP、TN含量波动较大;1970~1996年间,Ca-P、IP、TP含量变化均呈减小趋势,Fe/Al-P、OP、OM含量不同程度上先减少后增加,TN波动较大;1996~2009年营养元素含量相对波动较大,Fe/Al-P、OP和OM的平均含量是3个阶段中最高的.西大海湖沉积岩芯营养元素污染来源以工业废水、生活污水和化肥农药的流失为主.沉积物中C/N比值显示有机质主要来源于水生生物.沉积物粒度组成以黏土和细粉砂为主.相关性研究表明,Ca-P、IP与TP均呈显著的正相关关系,表明Ca-P对IP、TP的增长贡献大.