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31.
The effect of the vent burst pressure on explosion venting of a rich methane-air mixture was experimentally investigated in a small cylindrical vessel. The experimental results show that Helmholtz oscillation of the internal flame bubble of the methane-air mixture can occur in a vessel with a vent area much smaller than that reported by previous researchers, and the period of Helmholtz oscillation decreases slightly when the vent burst pressure increases. The maximum overpressure in the vessel increases approximately linearly with the increase in the vent burst pressure; however, the pressure peaks induced by Helmholtz oscillation always remain approximately several kilopascals. The external flame reaches its maximum length in a few milliseconds after vent failure and then oscillates in accordance with the pressure oscillation in the vessel. The maximum length of the external flame increases, but its duration time decreases with the increase in the vent burst pressure. 相似文献
32.
As an important intermediate product, short-chain fatty acids(SCFAs) can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion process. In order to obtain more SCFA and methane,most studies in literatures were centered on enhancing the hydrolysis of sludge anaerobic digestion which was proved as un-efficient. Though the alkaline pretreatment in our previous study increased both the hydrolysis and acidification processes, it had a vast chemical cost which was considered uneconomical. In this paper, a low energy consumption pretreatment method, i.e. enhanced the whole three stages of the anaerobic fermentation processes at the same time, was reported, by which hydrolysis and acidification were both enhanced, and the SCFA and methane generation can be significantly improved with a small quantity of chemical input. Firstly, the effect of different pretreated temperatures and pretreatment time on sludge hydrolyzation was compared. It was found that sludge pretreated at 100°C for 60 min can achieve the maximal hydrolyzation. Further, effects of different initial p Hs on acidification of the thermal pretreated sludge were investigated and the highest SCFA was observed at initial p H 9.0with fermentation time of 6 d, the production of which was 348.63 mg COD/g VSS(6.8 times higher than the blank test) and the acetic acid was dominant acid. Then, the mechanisms for this new pretreatment significantly improving SCFA production were discussed. Finally,the effect of this low energy consumption pretreatment on methane generation was investigated. 相似文献
33.
Qi Yin Xiaoyu Zhu Guoqiang Zhan Tao Bo Yanfei Yang Yong Tao Xiaohong He Daping Li Zhiying Yan 《环境科学学报(英文版)》2016,28(4):210-214
The anaerobic digestion(AD)and microbial electrolysis cell(MEC)coupled system has been proved to be a promising process for biomethane production.In this paper,it was found that by co-cultivating Geobacter with Methanosarcina in an AD–MEC coupled system,methane yield was further increased by 24.1%,achieving to 360.2 m L/g-COD,which was comparable to the theoretical methane yield of an anaerobic digester.With the presence of Geobacter,the maximum chemical oxygen demand(COD)removal rate(216.8 mg COD/(L·hr))and current density(304.3 A/m_3)were both increased by 1.3 and 1.8 fold compared to the previous study without Geobacter,resulting in overall energy efficiency reaching up to 74.6%.Community analysis demonstrated that Geobacter and Methanosarcina could coexist together in the biofilm,and the electrochemical activities of both were confirmed by cyclic voltammetry.Our study observed that the carbon dioxide content in total gas generated from the AD reactor with Geobacter was only half of that generated from the same reactor without Geobacter,suggesting that Methanosarcina may obtain the electron transferred from Geobacter for the reduction of carbon dioxide to methane.Taken together,Geobacter not only can improve the performance of the MEC system,but also can enhance methane production. 相似文献
34.
35.
This study deals with the emission of methane in relation to changing environmental conditions and human impact, in three
mangrove ecosystems of south India. Time-varying fluxes of methane adopting the close chamber technique were used to estimate
CH4 emission from an unpolluted site (Pichavaram mangroves) and two polluted sites viz. (1) Ennore Creek mangroves (affected
by fertilizer effluents and crude oil discharges) and (2) Adyar estuary mangroves (affected by the discharges of organic and
industrial wastes), covering monthly and seasonal variations. The results indicate annual average CH4 emissions of 7.4, 5.02 and 15.4 mg m−2 h−1 from the sediment–water interface of the Pichavaram, Ennore Creek and Adyar estuary respectively. Emission characteristics
obtained at Pichavaram mangroves represent a natural variability with changing physico-chemical factors, whereas the emission
characteristics at Ennore Creek and Adyar estuary mangroves show anthropogenic influence. Several environmental factors such
as oxygen availability, organic matter, soil physical and chemical properties, in addition to human-mediated interventions
have been identified as influencing emission rates in the mangrove ecosystems. Preliminary CH4 emission estimates for the mangrove ecosystems along the Indian sub- continent and the tropical and subtropical coastline
of the world by linear extrapolation based on surface area range from 0.05 to 0.37 and 2.8 to 19.25 Tg CH4 year−1 respectively. Our results also highlight the impact of human activities on future emission of methane from the mangrove ecosystems.
Received: 3 March 1999 / Accepted: 14 September 1999 相似文献
36.
Mitigation of methane and nitrous oxide emissions from drained irrigated rice fields 总被引:23,自引:0,他引:23
One of the important cultural practices that affect methane and nitrous oxide emissions from tropical rice plantations is the water drainage system. While drainage can reduce methane emissions, it can also increase nitrous oxide emissions, as well as reduce yields. In this experiment, four different water drainage systems were compared in a rice field in central Thailand including: (1) continuous flooding, (2) mid-season drainage, (3) multiple drainage and (4) a local method (drainage was done according to local cultural practice) in order to find a system of drainage that would optimize yields while simultaneously limiting methane and nitrous oxide emissions. Methane and nitrous oxide emission were observed and compared with rice yield and physical changes of rice plants. It was found that drainage during the flowering period could reduce methane emission. Interestingly, nitrous oxide emission was related to number of drain days rather than the frequency of draining. Fewer drain days can help reduce nitrous oxide emission. The mid-season drainage and the multiple drainage, with 6.9% and 11.4% reduction in rice yield, respectively, had an average methane emission per crop 27% and 35% lower when compared to the local method. Draining with fewer drain days during the flowering period was recommended as a compromise between emissions and yield. The field drainage can be used as an option to reduce methane and nitrous oxide emissions from rice fields with acceptable yield reduction. Mid-season drainage during the rice flowering period, with a shortened drainage period (3 days), is suggested as a compromise between the need to reduce global warming and current socio-economic realities. 相似文献
37.
Mariusz O. Jedrysek 《Environmental Chemistry Letters》2005,3(3):100-112
Microbial oxidation of organic compounds (including methane), in freshwater sediments, may result in precipitation of carbonates,
which may become an important geochemical archive of paleoenvironmental variations. Most probably low δ13C value in calcite in eutrophic systems results from an advanced oxidation of organic compounds in turbulent or/and sulphate-rich
conditions. Likewise, high δ13C value in calcite from organic-rich sediments may evidence low redox potential of the freshwater system. Oxidation of methane
and organic matter results in significant isotope effects in sulphates dissolved in water. Therefore, to better understand
the origin of carbon isotope signal in carbonates, concentration and stable isotope measurements in dissolved sulphate (water
column), bubble methane and calcite (freshwater sediments) have been carried out in 24 lakes, 2 ponds and 4 rivers in Poland.
The highest concentration of sulphate has been detected in rivers (85.47 SO4
2− mg/l) and an artificial lake (70.30 SO4
2− mg/l) located in the extremely SO4
2−-polluted region called the “Black Triangle”. The lowest concentration of sulphate is found in dystrophic and mountain lakes
(from 0.5 SO4
2− to about 3 mg/l). The lowest δ34S(SO4
2−) and δ18O(SO4
2−) values occur in unpolluted lakes in eastern Poland (−0.94 and 1.38‰, respectively). The highest S and O isotopic ratios
are found in a polluted lake in western Poland (δ14S(SO4
2)=12.95‰) and in a dystrophic lake in eastern Poland (δ18O(SO4
2) = 16.15‰) respectively. It is proposed that δ34SO4
2− and (18O(SO4
2−) values in lakes represent a good tool to assess and quantify anthropogenic impact by acid precipitation and to monitor variations
in the trophic state and redox processes controlled by biodegradation of organic compounds in sediments and water column.
In general, increasing depth (up to 12 m) of the water column is associated with decreasing trend the δ13C(CH4) value from about –35 to about –78‰. However, δ13C value in sedimentary calcite (δ13C vary from –10 to 0.5‰) shows opposite trends as compared to the corresponding methane. This is probably due to redox processes
and distribution of heavy isotopes between methane and calcite. Likewise, turbulent water (river) show high δ13C value in methane and low δ13C value in calcite—this is probably due to an enhanced oxidation of methane producing 13C-depleted CO2. In contrast to clean lakes, it is observed that an increase of the δ13C(CH4) value occurs with increasing depth of the water column in a strongly SO4
2−-contaminated lake. This is probably due to a loss of biological buffering potential of the lake accompanied by an active
oxidation of methane precursors. 相似文献
38.
Effect of dissolved oxygen on methane production from bottom sediment in a eutrophic stratified lake
《环境科学学报(英文版)》2023,35(3):61-72
Clarifying the role of sulfate and dissolved oxygen (DO) in methane production may allow for precise and accurate modeling of methane emissions in eutrophic lakes. We conducted field observations of sulfate, methane, and DO concentrations in Lake Abashiri, a typical brackish and eutrophic lake in a cold region, to develop a DO-based method for quantitively estimating methane production in a eutrophic lake and analyzed the results. We found that sulfate concentrations decreased rapidly from 900.0 mg/L in water overlying the sediments to nearly 0.0 mg/L in the bottom sediment. Methane production was almost uniform across sediment depths of 0.05 to 0.25 m, ranging from 1400 to 1800 µmol/m2/day. Also, methane production was found to be a function of DO concentrations in water overlying the bottom and could be modeled by a logistic function: constant production at 1,400 µmol/m2/day for DO concentrations of 0.0 to 3.0 mg/L, rapidly decreasing to 0 µmol/m2/day for DO concentrations of 3.0 to 6.0 mg/L. This methane model was verified using a simple one-dimensional numerical model that showed good agreement with field observations. Our results thus suggest that the proposed methane model reduces uncertainty in estimating methane production in a eutrophic lake. 相似文献
39.
《环境科学学报(英文版)》2023,35(3):786-797
Microbial electrosynthesis system (MES) is a promising method that can use carbon dioxide, which is a greenhouse gas, to produce methane which acts as an energy source, without using organic substances. However, this bioelectrical reduction reaction can proceed at a certain high applied voltage when coupled with water oxidation in the anode coated with metallic catalyst. When coupled with the oxidation of HS– to SO42−, methane production is thermodynamically more feasible, thus implying its production at a considerably lower applied voltage. In this study, we demonstrated the possibility of electrotrophic methane production coupled with HS– oxidation in a cost-effective bioanode chamber in the MES without organic substrates at a low applied voltage of 0.2 V. In addition, microbial community analyses of biomass enriched in the bioanode and biocathode were used to reveal the most probable pathway for methane production from HS– oxidation. In the bioanode, electroautotrophic SO42− production accompanied with electron donation to the electrode is performed mainly by the following two steps: first, incomplete sulfide oxidation to sulfur cycle intermediates (SCI) is performed; then the produced SCI are disproportionated to HS– and SO42−. In the biocathode, methane is produced mainly via H2 and acetate by electron-accepting syntrophic bacteria, homoacetogens, and acetoclastic archaea. Here, a new eco-friendly MES with biological H2S removal is established. 相似文献
40.
Turbulent mixing is enhanced in shallow lakes. As a result, exchanges across the air–water and sediment–water interfaces are increased, causing these systems to be large sources of greenhouse gases. This study investigated the effects of turbulence on carbon dioxide(CO_2)and methane(CH_4) emissions in shallow lakes using simulated mesocosm experiments.Results demonstrated that turbulence increased CO_2 emissions, while simultaneously decreasing CH_4 emissions by altering microbial processes. Under turbulent conditions, a greater fraction of organic carbon was recycled as CO_2 instead of CH_4, potentially reducing the net global warming effect because of the lower global warming potential of CO_2 relative to CH_4. The CH_4/CO_2 flux ratio was approximately 0.006 under turbulent conditions, but reached 0.078 in the control. The real-time quantitative PCR analysis indicated that methanogen abundance decreased and methanotroph abundance increased under turbulent conditions, inhibiting CH_4 production and favoring the oxidation of CH_4 to CO2.These findings suggest that turbulence may play an important role in the global carbon cycle by limiting CH4 emissions, thereby reducing the net global warming effect of shallow lakes. 相似文献