Nitrogen (N) and phosphorus (P) released from the sediment to the surface water is a major source of water quality impairment. Therefore, inhibiting sediment nutrient release seems necessary. In this study, red soil (RS) was employed to control the nutrients released from a black-odorous river sediment under flow conditions. The N and P that were released were effectively controlled by RS capping. Continuous-flow incubations showed that the reduction efficiencies of total N (TN), ammonium (NH4+-N), total P (TP) and soluble reactive P (SRP) of the overlying water by RS capping were 77%, 63%, 77% and 92%, respectively, and nitrification and denitrification occurred concurrently in the RS system. An increase in the water velocity coincided with a decrease in the nutrient release rate as a result of intensive water aeration.
This study proposed an integrated biogeochemical modelling of nitrogen loads from anthropogenic and natural sources in Japan. Firstly, the nitrogen load (NL) from different sources such as crop, livestock, industrial plant, urban and rural resident was calculated by using datasets of fertilizer utilization, population distribution, land use map, and social census. Then, the nitrate leaching from soil layers in farmland, grassland and natural conditions was calculated by using a terrestrial nitrogen cycle model (TNCM). The Total Runoff Integrating Pathways (TRIP) was used to transport nitrogen from natural and anthropogenic sources through river channels, as well as collect and route nitrogen to the river mouths. The forcing meteorological and hydrological data is a 30-year (1976–2005) dataset for Japan which were obtained by the land surface model, Minimal Advanced Treatments of Surface Interaction and Runoff (MATSIRO). For the model validation, we collected total nitrogen (TN) concentration data from 59 rivers in Japan. As a comparison result, calculated TN concentration values were in good agreement with the observed ones, which shows the reliability of the proposed model. Finally, the TN loads from point and nonpoint sources were summarized and evaluated for 59 river basins in Japan. The proposed modelling framework can be used as a tool for quantitative evaluation of nitrogen load in terrestrial ecosystems at a national scale. The connection to land use and climate data provides a possibility to use this model for analysis of climate change and land use change impacts on hydrology and water quality. 相似文献
Agricultural crops can be either a source or a sink of ammonia (NH3). Most NH3 exchange models developed so far do not account for the plants nitrogen (N) metabolism and use prescribed compensation points. We present here a leaf-scale simplified NH3 stomatal compensation point model related to the plants N and carbon (C) metabolisms, for C3 plants. Five compartments are considered: xylem, cytoplasm, apoplasm, vacuole and sub-stomatal cavity. The main processes accounted for are the transport of ammonium (NH4+), NH3 and nitrate (NO3−) between the different compartments, NH4+ production through photorespiration and NO3− reduction, NH4+ assimilation, chemical and thermodynamic equilibriums in all the compartments, and stomatal transfer of NH3.The simulated compensation point is sensitive to paramaters related to the apoplastic compartment: pH, volume and active transport rate. Determining factors are leaf temperature, stomatal conductance and NH4+ flux to the leaf. Atmospheric NH3 concentration seem to have very little effect on the compensation point in conditions of high N fertilization. Comparison of model outputs to experimental results show that the model underestimates the NH3 compensation point for high N fertilization and that a better parametrisation of sensitive parameters especially active trasport rate of NH4+ may be required. 相似文献
