基于膨胀特性的厌氧流化床反应器的设计和运行控制

生物流化床的床层膨胀行为直接与生化反应区的水动力学和效率相关 ,床层膨胀特性是进行合理设计和运行的重要依据。目前流化床设计一般没有考虑生物膜的影响 ,但生物颗粒的流化行为有别于光滑载体 ,因此需要对曳力系数Cd 和膨胀特性方程中的ui 进行必要的修正。在综合分析基础上 ,探讨了优化两相流化床设计和运行的程序和方法     

Analysis of accumulation, extractability, and metabolization of five different phenylarsenic compounds in plants by ion chromatography with mass spectrometric detection and by atomic emission spectroscopy

Phenylated arsenic compounds occur as highly toxic contaminants in former military areas where they were formed as degradation products of chemical warfare agents. Some phenylarsenic compounds such as roxarsone and aminophenylarsonic acids were applied as food additive and veterinary drugs in stock-breeding and therefore pose an environmental risk in agricultural used sites. Very few data exist in the literature concerning uptake and effects of phenylarsenic compounds in plants growing on contaminated soils. In this study, the accumulation, extractability, and metabolization of five different phenylarsenic compounds, phenylarsonic acid, p- and o-aminophenylarsonic acid, phenylarsine oxide, and 3-nitro-4-hydroxyphenylarsonic acid called roxarsone, by the terrestrial plant Tropaeolum majus were investigated. Ion chromatography coupled to inductively coupled plasma mass spectrometry was used to differentiate these arsenic compounds, and inductively coupled plasma atomic emission spectroscopy was used for total arsenic quantification. All compounds considered were taken up by the roots and transferred to stalks, leaves, and flowers. The strongest accumulation was observed for unsubstituted phenylarsonic acid followed by its trivalent analogue phenylarsine oxide that was mostly oxidized in soil whereas the amino- or nitro- and hydroxy-substituted phenylarsonic acids were accumulated to a smaller degree.The highest extraction yield of 90% for ground leaf material was achieved by 0.1 M phosphate buffer, pH 7.7, in a two-step extraction with a total extraction time of 24 h. The extraction of higher amounts of arsenic (50–70% of total arsenic present in leaves depending on arsenic species application) from non-ground intact leaves with deionized water in comparison with the buffer (20–40% of total arsenic) is ascribed to osmotic effects. The arsenic species analysis revealed a cleavage of the amino groups from the phenyl ring for plants treated with aminophenylarsonic acids. A further important metabolic effect consisted in the production of inorganic arsenate and arsenite from the phenylated arsonic acid groups.     

Use of Co speciation and soil properties to explain variation in Co toxicity to root growth of barley (Hordeum vulgare L.) in different soils

The influence of soil properties on the bioavailability and toxicity of Co to barley (Hordeum vulgare L.) root elongation was investigated. Ten soils varying widely in soil properties were amended with seven doses of CoCl₂. Soil properties greatly influenced the expression of Co toxicity. The effective concentration of added Co causing 50% inhibition (EC₅₀) ranged from 45 to 863 mg kg⁻¹, representing almost 20-fold variation among soils. Furthermore, we investigated Co toxicity in relation to Co concentrations and free Co²⁺ activity in soil solution. The EC₅₀ values showed variation among soils of 17- and 29-fold, based on the Co concentration in soil solution and free Co²⁺ activity, respectively. Single regressions were carried out between Co toxicity threshold values and selected soil properties. Models obtained showed that soil effective cation exchange capacity (eCEC) and exchangeable calcium were the most consistent single predictors of the EC₅₀ values based on soil added Co.     

水泥厂生料库底除尘系统的改造

分析了原设计中存在的问题,提出了改造措施和方案,并介绍了改造后的结果。     

大空间建筑室内火蔓延全尺寸实验设计

大空间建筑室内火蔓延的全尺寸实验能较好反应和说明大空间建筑室内火灾过程的主要规律,也是当前研究建筑室内火灾机理较理想的一种实验方法。文中介绍了大空间建筑室内火蔓延全尺寸实验室的设计思想和实现方法,简要介绍了其在建筑火灾研究中的主要应用前景。     

CAST污水处理工艺中计算机控制系统的设计

以陕西省某污水处理工程为例,介绍了循环式活性污泥法(CAST)污水处理工艺中基于PLC计算机控制系统的主要内容:包括使用目的、控制系统结构、并分述三个PLC子站各自功能及在整个系统中的地位作用,探讨典型CAST工艺中计算自动控制系统的一般设计方法,将生产过程的自动化与办公自动化相结合,从而为中小城市CAST工艺污水处理厂设计提供借鉴,推动该工艺在污水处理中的应用.     

改良A2/O型氧化沟处理城市污水工程实例

介绍了重庆市童家溪区污水处理厂的工艺流程,及其各构筑物和主要设备的参数.该工艺采用改良A2/O型氧化沟处理城市污水,该工艺将A2/O与氧化沟相结合,具有两者的优点,且能耗省、脱N除P的特点,出水水质达到<城镇污水处理厂污染物排放标准>(GB18918-2002)中的一级标准的B标准.     

生物膜法光发酵制氢的研究现状与展望

21世纪被誉为氢能世纪.光发酵制氢作为绿色可持续生物制氢方式的一种,可以利用独特的光合系统固定太阳能,并利用有机物产生清洁能源氢气,因而受到广泛关注.但光发酵细菌凝集力差、底物转化效率和光能利用率低导致产氢效能下降,从而阻碍了光发酵制氢的发展.光发酵细菌可以通过形成生物膜而被有效固定,进而增加反应器内光发酵细菌的生物持有量,提高光发酵细菌对不利环境的抵抗力;同时,光发酵细菌形成生物膜后可以调控产氢细菌新陈代谢和生理活性使其更利于产氢.其中,光发酵生物膜反应器的设计尤为重要,尤其是反应器内光源的均匀分配对于光发酵制氢是一项关键因素,需要对光源设计、空间摆放和遮光性进行综合分析和设计;其次,需要考虑载体性质和载体安装以充分吸附光发酵细菌并形成生物膜;同时,结合未来可持续绿色发展的需求,光发酵生物膜反应器设计需要逐步过渡到以室外环境作为常规环境和太阳作为光源.尽管光发酵生物膜制氢前景良好,但目前对于光发酵生物膜反应器和制氢机制的研究仍然不够充分,需要更加深入地探索和优化以突破光发酵制氢的瓶颈,推动氢能行业的发展.     

深圳市中银花园中水回用示范工程设计与运行

深圳市水资源严重短缺,中水回用对于节约水资源有着重要的意义。文章详细介绍了深圳市第一个中水回用示范工程——中银花园中水回用工程的设计、运行情况,并进行了技术经济指标分析。     

基于安全疏散的高速铁路桥梁救援定点站台设计参数研究

应用安全疏散性能化设计的理论方法,研究了桥梁救援定点疏散站台的尺寸参数 ,以保证设计更为安全、经济、合理。首先,采用FDS软件模拟火灾警戒线随疏散时间 的发展趋势,分析ASET对站台长度的影响;其次,采用EVACNET4软件模拟了列车中部和 端部火灾情境下,乘客在站台的疏散运动,研究站台宽度对疏散时间的影响。结果表明 :从火灾警戒范围考虑,站台长度取值为450 m是经济合理的;有效宽度1.75 m为站台 疏散时间特征变化的分界点,有效宽度为1.75 m时的疏散时间均小于有效宽度为1.5 m 时的疏散时间,而当有效宽度大于1.75 m后,疏散时间的变化不大。研究成果可为救援 定点疏散站台的尺寸设计提供参考和依据。