分散液液微萃取气相色谱-质谱法测定水中15种硝基苯类化合物

建立了超声辅助基质分散液液微萃取（UA-DLLME）作为前处理联合气相色谱串联质谱（GC-MS）同时测定地下水和地表水中15种硝基苯类化合物的分析方法。萃取剂、分散剂、萃取温度、萃取时间和离子强度等影响因素采用Plackett-Burman设计,快速筛选出最显著影响因素,利用中心组合设计（CCD）简化实验步骤优化显著因素,结合响应曲面图最终确定最佳的萃取条件：5 mL水样在3%氯化钠条件下迅速加入40 μL四氯化碳（萃取剂）和0.5 mL乙腈（分散剂）,50 ℃下超声4 min,混合液4 000 r/min离心3 min。结果表明：15种硝基苯类化合物在50.0~1 000.0 μg/L的浓度范围内线性相关系数均大于0.995;采用超声辅助基质分散液液微萃取时,方法检出限（MDL）为0.018~0.039 μg/L;15种目标物的加标平均回收率为83.31%~99.08%,相对标准偏差均不高于5.0%（n=6）。     

Incentivizing biodiversity conservation in artisanal fishing communities through territorial user rights and business model innovation

Territorial user rights for fisheries are being promoted to enhance the sustainability of small‐scale fisheries. Using Chile as a case study, we designed a market‐based program aimed at improving fishers’ livelihoods while incentivizing the establishment and enforcement of no‐take areas within areas managed with territorial user right regimes. Building on explicit enabling conditions (i.e., high levels of governance, participation, and empowerment), we used a place‐based, human‐centered approach to design a program that will have the necessary support and buy‐in from local fishers to result in landscape‐scale biodiversity benefits. Transactional infrastructure must be complex enough to capture the biodiversity benefits being created, but simple enough so that the program can be scaled up and is attractive to potential financiers. Biodiversity benefits created must be commoditized, and desired behavioral changes must be verified within a transactional context. Demand must be generated for fisher‐created biodiversity benefits in order to attract financing and to scale the market model. Important design decisions around these 3 components—supply, transactional infrastructure, and demand—must be made based on local social‐ecological conditions. Our market model, which is being piloted in Chile, is a flexible foundation on which to base scalable opportunities to operationalize a scheme that incentivizes local, verifiable biodiversity benefits via conservation behaviors by fishers that could likely result in significant marine conservation gains and novel cross‐sector alliances. Incentivar la Conservación de la Biodiversidad con Comunidades de Pesca Artesanal por medio de Derechos de Uso Territorial y la Innovación de Modelos de Negocio     

Assessing the Distribution and Protection Status of two Types of Cool Environment to Facilitate Their Conservation under Climate Change

Strategies to mitigate climate change can protect different types of cool environments. Two are receiving much attention: protection of ephemeral refuges (i.e., places with low maximum temperatures) and of stable refugia (i.e., places that are cool, have a stable environment, and are isolated). Problematically, they are often treated as equivalents. Careful delineation of their qualities is needed to prevent misdirected conservation initiatives; yet, no one has determined whether protecting one protects the other. We mapped both types of cool environments across a large (～3.4M ha) mixed‐use landscape with a geographic information system and conducted a patch analysis to compare their spatial distributions; examine relations between land use and their size and shape; and assess their current protection status. With a modest, but arbitrary, threshold for demarcating both types of cool environments (i.e., values below the 0.025 quantile) there were 146,523 ha of ephemeral refuge (62,208 ha) and stable refugia (62,319 ha). Ephemeral refuges were generally aggregated at high elevation, and more refuge area occurred in protected areas (55,184 ha) than in unprotected areas (7,024 ha). In contrast, stable refugia were scattered across the landscape, and more stable‐refugium area occurred on unprotected (40,135 ha) than on protected land (22,184 ha). Although sensitivity analysis showed that varying the thresholds that define cool environments affected outcomes, it also exposed the challenge of choosing a threshold for strategies to address climate change; there is no single value that is appropriate for all of biodiversity. The degree of overlap between ephemeral refuges and stable refugia revealed that targeting only the former for protection on currently unprotected land would capture ～17% of stable refugia. Targeting only stable refugia would capture ～54% of ephemeral refuges. Thus, targeting one type of cool environment did not fully protect the other. Evaluación de la Distribución y Estado de Protección de Dos Tipos de Ambientes Fríos para Facilitar su Conservación bajo el Cambio Climático     

Surveys of historic parks and gardens

The United Kingdom offers some of the finest designed parks and garden landscapes in the world and, whilst there is a wide range of skills and a wealth of literature on the subject, there is little evidence of official effort to systematically record historic sites. This, it is argued, is a factor in the continuing decline of many examples. This paper records an attempt at a comprehensive examination of one county — Cheshire — begun in 1970. The method is described and the results discussed in some detail. Some suggestions are put forward for improvements to official incentives for site owners.     

The landscape design of forestry

The value placed by the public on the nation's rural landscapes is emphasised by vociferous criticism of insensitive, large‐scale afforestation. As forestry causes massive changes in the landscape in the short term, with results that last for decades, the opportunity provided to improve and conserve should be positively grasped. There is evidence that concensus exists over a considerable part of landscape and design, and this paper explores some of the major factors in landscape design which are consistently important in forest landscapes.     

Design-based ranked set sampling using auxiliary variables

A ranked set sampling protocol is proposed when an auxiliary variable is available in addition to the target variable in sample surveys. The protocol may be practically carried out without additional sampling effort or costs. Under the suggested sampling scheme, the estimators usually adopted in surveys with auxiliary information - such as the ratio estimator or the regression estimator - display surprising theoretical properties as well as high performance in practice.     

危险性评估与经济性分析在性能化消防设计中的应用

分析了性能化消防设计中危险性评估与经济性分析的关系，以仓库火灾为例，介绍了危险性评估的思路、程序。     

高速公路路域植被恢复设计与施工技术初探

在高速公路建设之后 ,对其破坏的植被尽快进行恢复是一项重要内容 ,多年来由于指导思想不同 ,实施效果与预想相差很大。本文力求从生态学的角度出发 ,从设计、施工和养护几个植被恢复重要环节进行分析 ,寻求适宜的高速公路生态恢复技术     

Techno-economic analysis of municipal wastewater land treatment systems in China

This paper analyses the capital costs, power consumption and operation costs of municipal wastewater land treatment systems, including rapid infiltration, slow-rate infiltration, overflow and constructed wetland, by means of series engineering design. The results show that land treatment can save 50-70% of capital costs, 80-90% of power and 75-85% of operation costs when compared with secondary treatment.     

Effects of Grazing Pressure on Succession Process and Productivity of Old Fields on Mediterranean Islands

Poterium spinosum, competitive under conditions of overgrazing and fire, accounted for 70%–85% of the total plant cover in all sites, except Santorini, where participation of spiny species was very low. In the recently abandoned sites, annuals accounted for 50%–60% of the standing biomass, but constituted only a tiny fraction in those abandoned for 30 years or more. This was not paralleled by any remarkable increase of the total plant cover. In fact, the yearly produced green biomass decreased with the years after abandonment. The productivity of old fields abandoned for a long time is insufficient to support the grazing animals present. This shortfall, given the animals' requirements, is most dramatic in Symi. The nonrecovering vegetation in the old fields of these mountainous islands constitutes a severe environmental threat; remedial measures appear imperative.