昆明湖沉积物的组成和理化性质的粒度响应

文章采用扫描电镜、激光粒度仪、X-射线衍射光谱仪,全谱直读ICP发射光谱仪等现代大型仪器鉴定和常规化学分析技术,对不同筛分粒径下昆明湖沉积物颗粒的组成、形貌及物理化学性质进行了综合分析.结果表明,昆明湖沉积物颗粒主要以粉粒和黏粒为主,具有晶体结构,平均粒径为22.37-160.17 μm;呈现不规则的块、片状形貌,表面...     

Effect of activated sludge treatment on the formation of Nnitrosamines under different chloramination conditions

Municipal wastewater discharge is considered as one of the main sources of N-nitrosamine precursors which can impact the qualities of downstream source waters and reclaimed wastewaters for potable reuse. NNitrosamine precursors can be removed to various degrees during biological wastewater treatment (e.g., the activated sludge (AS) process). So far, little is known about the impact of the AS process on N-nitrosamine formation under practical disinfection condition (e.g., uniform formation condition (UFC)). In this study, N-nitrosamine UFC from selected model compounds, sewage components (i.e., blackwaters and greywaters) and sewage samples were comprehensively investigated during batch AS treatment tests. NNitrosodimethylamine (NDMA) formation from the tested precursor compounds (i.e., trimethylamine (TMA) and sumatriptan (SMTR)) under UFC chloramination decreased mostly after 6 or 24 hr treatment with different types of AS (i.e., domestic rural AS, domestic urban AS, and textile AS), and the reductions in NDMA UFC were comparable to their NDMA formation potential (FP) reductions. In urine and feces blackwaters, NDMA UFC increased after 6 or 24 hr treatment with the domestic (i.e., rural and urban) AS, while NDMA FP decreased substantially. The increases in NDMA UFC after AS treatment was presumably attributed to the removal of bulk organic matters (e.g., dissolved organic carbon (DOC)) which favored NDMA formation under UFC. On the other hand, in laundry greywaters having relatively abundant DOC, N-nitrosamine UFC was less affected by DOC removal before or after AS treatment, but decreased to similar degrees with N-nitrosamine FP. In sewage samples collected from wastewater treatment plants, N-nitrosamines UFC tended to increase or remain constant during AS treatment, despite the decreases in their FPs. These results suggest that biological wastewater treatment (e.g., the AS process) may not effectively reduce N-nitrosamine formation (e.g., measured under UFC) partially because the concurrent removal of bulk organic matters (e.g., DOC) favored N-nitrosamine formation in s econdary effluents.     

The shaped blasting experimental study on damage and crack evolution of high stress coal seam

In the deep high stress coal and rock mass, the efficiency of the ordinary blasting method is constantly affected by the high pressure. This study investigates the shaped blasting technology with increased blasting efficiency, develops a mechanical model for coal crack expansion during shaped blasting, and examines the force-energy action of energy-gathering jets during coal splitting. The established model was combined with experiments and simulations to reveal the damage and evolution of cracks in coal and rock masses. Experiments demonstrate that shaped blasting can create an energy-gathering jet that causes a directional fracture in the test block. The peak of compressive strain in the energy-gathering direction is 1.12 times greater than that of ordinary blasting, and the static action period of the explosive gas is prolonged by 1.3 μs according to the stress curve. Moreover, the peak pressure strain increased 3.2 times, and the pull strain peak increased 3.92 times. The damage amount was represented by the resistivity and ultrasonic wave speed, and shaped blasting causes 1.2 and 1.5 times greater damage than ordinary blasting. The research results provide technical methods for safe and rapid penetration blasting in deep high-ground stressed coal mines.     

Improvement of integrity management for pressure vessels based on risk assessment - A natural gas separator case study

The process of oil and gas processing plant is complex, the types of pressure vessels are rich, and the functions are critical. However, the working medium is mostly untreated medium, and the hazard factors are complex, which poses a threat to the safe production of oil and gas processing plant. Based on PDCA cycle, this paper establishes a six-step links of integrity management for sustainable improvement of pressure vessels. The typical failure modes of pressure vessels are determined, and the fishbone diagram of risk factors under each failure mode is compiled. Risk quantification and classification of pressure vessels based on failure modes (RBFM) is innovatively proposed. Avoiding incalculable failure frequency index, the process quantification of failure possibility is formed according to the development of hazard factors. A failure consequence calculation model based on the leakage affected area was established. Combined with the failure probability level and risk level, the hierarchical inspection strategy for pressure vessels under different failure modes is established. Finally, the method is applied to the natural gas separator of H processing plant. The research results show that RBFM proposed in this paper can meet the requirements for rapid and accurate risk assessment of pressure vessels in oil and gas processing plant. This paper establishes a safe production barrier for the pressure vessel and improves the intrinsic safety of the equipment.     

输送、滞留叠加海上回流的长时间沙尘天气影响判断及贡献分析

于2019年10月15日～11月7日对上海大气中颗粒物的质量浓度和PM2.5的化学组分进行了在线连续观测,期间,华东地区遭遇了一次大范围的沙尘过程.根据相关规定,结合沙尘示踪组分和WRF-CMAQ 数值模拟,将观测过程分为4 个阶段:沙尘前、沙尘I(输送和滞留过程)、沙尘Ⅱ(海上回流和清除过程)和沙尘后.基于相关规定、...