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针对红外分光光度法分析过程耗时、耗力、试剂用量大等问题,在保证分析质量的前提下对操作技术进行了一些改进。通过这些改进,对解决石油类测定过程中出现的一些问题,具有很好的应用价值。 相似文献
195.
自"十五"以来,为改善水质,我国许多城市湖泊均先后采取了水环境治理措施.为了解这些措施对富营养化城市湖泊水质改善成效,根据中国科学院太湖湖泊生态系统研究站对蠡湖的长期监测数据和本课题组2017年对蠡湖的两次调查结果进行汇总分析,探讨了无锡蠡湖综合整治前后近30年来水环境质量变化情况.结果表明:①TN、TP、高锰酸盐指数和Chl-a等水质指标的浓度从20世纪90年代初开始呈现快速上升的趋势,1997~2003年间处于最差状态,2003年经过综合整治后呈现逐年递减趋势,但近两年略有反弹;水体透明度整治前后无明显改善.②从季节上看,综合整治之前,水质波动较大;综合整治之后,蠡湖各项指标出现显著差异,冬季水质明显好于夏季.③从区域上来看,蠡湖西部水质明显优于东部湖区.综合其他城市湖泊治理情况,研究表明水环境治理可以改善湖泊水质,但在水质改善后需要恢复草型生态系统,推进以生物调控为主的生态修复,逐步提升物种多样性,真正恢复湖泊生态系统服务功能. 相似文献
196.
温榆河氨氮污染控制措施的效果模拟 总被引:5,自引:2,他引:5
以城市退水为主要补给水源的北京市温榆河呈现以氨氮(18.68 mg·L-1)污染为主的特征.针对温榆河的水质改善需求,本研究以氨氮为目标污染物,采用QUAL2K河流水质模型和情景分析方法,对温榆河污染防治与水质改善措施的效果进行量化评估.模拟结果表明,提高污水厂的处理量和排放标准是改善温榆河水质的关键,可降低温榆河北关闸断面氨氮浓度29.66%;建设旁路离线河流净化器可削减5.57%的氨氮污染,是温榆河水质改善的有效措施.本研究提出的包括改善上游来水水质、干流截污、支流污染控制、污水厂提标改造、建设旁路离线河流净化器和生态河道等措施在内的综合实施方案,可使得温榆河的水质全程达到地表水V类标准. 相似文献
197.
This paper discusses the framework methodology behind the proposed simulation-based HAZOP tool. Simulation-based approach is one of the many ways to support conventional HAZOP by its automation. Compared to knowledge-based and other approaches, a HAZOP software tool based on deviations simulation is able to examine the investigated process more into detail and so find root causes of hazardous consequences. Another advantage is the ability to identify also potential hazards which did not occur in the past and might be overlooked. The presented framework methodology uses a layer of protection analysis (LOPA) concept of independent protection layers (IPLs) testing. Control system integrated into the raw process design represents the first of various protection layers of the LOPA concept. As a case study, a CSTR chemical production with nonlinear behavior under Proportional-Integral-Derivative (PID) actions as the predominant type of classical feedback control strategy is used. The presented tool identifies hazardous regimes under conditions when control loop introduces hazardous consequences or even acts synergically with existing hazardous events. Risk derived from different consequences is ranked by the risk assessment matrix (RAM) as a part of the conventional quantitative HAZOP study. 相似文献
198.
The root cause of most accidents in the process industry has been attributed to process safety issues ranging from poor safety culture, lack of communication, asset integrity issues, lack of management leadership and human factors. These accidents could have been prevented with adequate implementation of a robust process safety management (PSM) system. Therefore, the aim of this research is to develop a comparative framework which could aid in selecting an appropriate and suitable PSM system for specific industry sectors within the process industry. A total of 21 PSM systems are selected for this study and their theoretical frameworks, industry of application and deficiencies are explored. Next, a comparative framework is developed using eleven key factors that are applicable to the process industry such as framework and room for continuous improvement, design specification, industry adaptability and applicability, human factors, scope of application, usability in complex systems, safety culture, primary or secondary mode of application, regulatory enforcement, competency level, as well as inductive or deductive approach. After conducting the comparative analysis using these factors, the Integrated Process Safety Management System (IPSMS) model seems to be the most robust PSM system as it addressed almost every key area regarding process safety. However, inferences drawn from study findings suggest that there is still no one-size-fits-all PSM system for all sectors of the process industry. 相似文献
199.
Like all hazardous installations, inherently safer design (ISD) is one of the key tools in offshore oil and gas projects to minimize risks in offshore facilities. As the life cycle of offshore facilities is relatively short compared with onshore counterparts and there are many projects running every year, the potential is high for raising inherent safety standards and lowering safety risks throughout the offshore industry as old facilities are phased out. This paper gives an overview of offshore facilities and examples of implementation of ISD. Good examples of ISD are numerous. Industry guidance on ISD implementation abound. Yet, the systematic implementation of it in the industry is patchy. There are many reasons for factors which impede the effective, efficient and consistent implementation of ISD in projects. This paper describes some of them and proposes solution to address them. They include (a) the effective integration of ISD into hazard management systems with appropriate language to engage all disciplines in projects, (b) the phasing of resources to enable the project to capture ISD measures which are only available during early phases, (c) application of appropriate ISD goals and ISD performance metrics at various stages and (d) the appropriate use of quantified risk assessment to support ISD. 相似文献
200.
The polymerization reaction can lower the threshold of the required energy by the initiator to improve the efficiency of the overall process reaction. Emerging polymerization initiators are also a major focus of process improvement and technological progress. Azo compounds (azos), which used in dyeing applications, are subsequently used in polymerization reactions due to their highly exothermic reaction characteristics. Although higher heat release can promote polymerization and modify the product, heat generation may also cause process hazards.These thermal hazard parameters were studied by selecting dimethyl 2,2′-azobis(2,4-dimethylvaleronitrile) (ABVN), 2,2′-azobis(2-methyl propionate) (AIBME), 2,2′-azobis(2-methylpropionamide) dihydrochloride (AIBA), and 2,2′-azobis(isobutyronitrile) (AIBN), which are common azo initiators at present. Thermal hazards are closely related to the reaction kinetics of the substance itself. The form of the reaction, the apparent activation energy and the thermodynamic parameters of the exothermic mode were also obtained.Kinetic analysis of the actual process using the experimental data of the isothermal calorimetry model is rarely used in the evaluation of related thermal hazard characteristics. The simulation results revealed the kinetic azo models and were further applied to calculate the runaway situations of azo under specific boundary conditions. 相似文献