氯化亚锡还原光度法测定总磷的方法改进

采用氯化亚锡还原光度法测定总磷时,氯化亚锡深液需要一周后重新配制,以甘油作为氯化亚锡溶液的介质时,其使用时间可以不受限制。此法具有节省试剂、省时等优点。     

模具制造的表面工程技术

针对模具制造和使用过程中的表面质量改性技术原理及应用特点进行了分析与研究 ,采用新的改性工艺 ,有利于提高模具的表面质量及使用寿命。     

厌氧水解-活性污泥法的生命周期能耗分析

运用生命周期分析技术可从全过程的视角识别和比较不同城市污水处理工艺在其生命周期各个阶段的能耗 ,并在此基础上提出改善其能效的措施。本文运用LCA方法对厌氧水解 -活性污泥法处理系统从其原材料开采和加工开始直至污水厂施工建设、处理运行以及废弃拆除的LC全过程能耗进行了识别和量化分析 ,并与普通活性污泥法进行了平行对照。研究结果表明 ,在微孔和穿孔管两种曝气条件下与普通活性污泥法相比 ,厌氧水解法的LC能耗分别节省 14.0 %和 17.6%。由于污泥产量较低 ,厌氧水解法的比能耗大幅度提高 67.7%～ 77.7%。     

城市污水测算统计方法

当今城市生活污水统计以人口与供水量为依据测算 ,难以满足治理和管理工作需要。在城市污水处理场和污水在线监控系统建设快速发展条件下建立以排污口监测统计为基础的城市污水统计系统 ,能够较真实反映生活污水质量和分布 ,满足环境管理工作需要。     

制药行业中污水处理技术及实践

采用物理灭活与生物处理相结合的废水处理技术对药厂污水进行处理,高温灭菌灭活了废水中的病毒、病菌等,生化处理化解污水中大分子的有机物.工程实践表明:两者相结合的处理方法,处理后的水质能够达到国家污水综合排放二级标准.     

螺旋钢管盘制成形的一种新方法

对如何在三辊卷板机上进行盘制螺旋钢管、盘管所用模具及成形工艺作了介绍.     

二苯碳酰二肼分光光度法测定水中六价铬样品预处理方法的改进

本文对二苯碳酰二肼分光光度法测定地表水及工业废水中六价铬的样品预处理方法提出了改进措施。改进方法准、快、简、省,符合环境监测分析要求。用该方法对样品进行预处理后分析,其结果与文献[1]一致。     

铜酞菁生产中的三废综合治理及其资源化探讨

通过某铜酞菁化工生产企业三废治理及其资源化工艺改进的实践，总结出了一套行之有效的利用酸化工艺废酸的资源化新方法，不但从中回收了高价值的铜泥；同时利用废酸吸收生产工艺中的高含氨尾气，生产硫酸铵，达到了以废治废的目的，整个治理工艺符合循环经济的理念。通过该回收工艺的改进，使上述三废不再进入污水处理系统，从而解决了传统铜酞菁生产废水的高酸度、高盐分、高含氨、高难处理的矛盾，使铜酞菁三废处理易于实行。     

关于完善建设项目环保设施竣工验收监测报告的几点思考

结合工作实践，归纳了目前建设项目环保设施竣工验收监测报告中存在的几个突出问题，提出了完善竣工验收监测报告的几点建议。     

Ferrioxalate-mediated photodegradation and mineralization of 4-Chlorophenol

INTENTION, GOAL, SCOPE, BACKGROUND: Advanced oxidation processes are powerful methods which are capable of transforming refractory, nonbiodegradable and/or toxic organic compounds into harmless end products such as carbon dioxide and water. However, one commen problem of all advanced oxidation processes is the high demand of electrical energy for ultraviolet lamps, which causes high operational costs. Minimization of the required irradiation time, and therefore the energy consumption, by optimization of other reaction conditions such as catalyst-oxidant type and concentration, pH, temperature, pollutant/oxidant ratio etc., therefore continues to gain importance. OBJECTIVE: The main objective of this study was the minimization of the required irradiation time through optimization of the use of a newly patented catalyst, ferrioxalate, and also to compare the performance of this catalyst with the performance of other AOPs. METHODS: Oxidation of 4-chlorophenol by photo-Fenton process using potassium ferrioxalate as a mediator was studied in a lab scale photoreactor. The influence of parameters such as hydrogen peroxide and ferrioxalate concentrations, initial pH, power-output, oxalate/iron ratio and different iron sources was evaluated. An upflow photoreactor equipped with a 1000 Watt high-pressure mercury vapour lamp and operating in a recirculation mode was used during photodegradation experiments. The extent of the reduction of 4-chlorophenol, Total Organic Carbon and Chemical Oxygen Demand was used to evaluate the photodegradation reaction. RESULTS AND DISCUSSION: The optimum pH range observed was found to be 2.7-3. The efficiency of 4-chlorophenol oxidation increased with increasing concentrations of hydrogen peroxide and ferrioxalate, reaching a plateau after the addition of 10 and 0.072 mM of those reagents, respectively. Using an Oxalate/iron ratio of 12 was 18% less efficient than using a ratio of 3:1. The efficiency increased with increasing radiation power. However, this increase was not linear. The UV/ferrioxalate/H2O2 process, by which complete mineralization of 100 mg l(-1) 4-chlorophenol was achieved in 20 min of total reaction time, was the most efficient process among the alternatives applied. CONCLUSIONS: The use of ferrioxalate as the catalyst was found to be more efficient than the use of Fe(II) and Fe(III) iron species. It was possible to completely mineralize 4-chlorophenol. RECOMMENDATION AND OUTLOOK: The results of this study demonstrate that the ferrioxalate-mediated degradation of 4-chlorophenol requires less irradiation times than other advanced oxidation processes. There are mainly 19 phenol isomers and other toxic and nonbiodegradable organic compounds. We recommend that similar studies should be performed on many such compounds in order to attain a clear understanding of the performance of this catalyst. Because of its light sensitivity, this catalyst should be used immediately after its preparation. The use of low pressure mercury vapour lamps in this process should also be considered, since low power outputs may be enough for the process.