全文获取类型
收费全文 | 813篇 |
免费 | 37篇 |
国内免费 | 53篇 |
专业分类
安全科学 | 222篇 |
废物处理 | 15篇 |
环保管理 | 128篇 |
综合类 | 346篇 |
基础理论 | 58篇 |
环境理论 | 4篇 |
污染及防治 | 35篇 |
评价与监测 | 29篇 |
社会与环境 | 47篇 |
灾害及防治 | 19篇 |
出版年
2023年 | 11篇 |
2022年 | 23篇 |
2021年 | 50篇 |
2020年 | 52篇 |
2019年 | 28篇 |
2018年 | 17篇 |
2017年 | 30篇 |
2016年 | 35篇 |
2015年 | 50篇 |
2014年 | 56篇 |
2013年 | 50篇 |
2012年 | 39篇 |
2011年 | 62篇 |
2010年 | 24篇 |
2009年 | 46篇 |
2008年 | 42篇 |
2007年 | 41篇 |
2006年 | 47篇 |
2005年 | 45篇 |
2004年 | 26篇 |
2003年 | 28篇 |
2002年 | 17篇 |
2001年 | 15篇 |
2000年 | 15篇 |
1999年 | 12篇 |
1998年 | 9篇 |
1997年 | 6篇 |
1996年 | 9篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1984年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有903条查询结果,搜索用时 15 毫秒
81.
Latex is extensively used in industrial products. However, completing some processes at scale leads to unacceptable levels of risk that need to be quantified and mitigated. Systemic risks must be eliminated wherever possible, and safety takes priority over efficiency and quality. To assess the process risks accurately, four raw materials were examined in this study: polyvinyl acetate (PVA), latex process-initiator-ammonium persulfate (APS) and hydrogen peroxide (H2O2), and vinyl acetate monomer (VAM). The physicochemical composition of the PVA latex process was determined via calorimeters, including differential scanning calorimetry (DSC) and vent sizing package 2 (VSP2). The calorimetry results showed that the protective colloid was a critical component in the polymerisation reaction. In addition, when adding initiators to the system, it is vital to observe the normal ratio of materials and keep the stirring system operating. The scenario system also simulated the effects of shutting down various inhibitory programs, including the build-up of free radicals that could result in a runaway reaction when the initiator was added in excess. On the other hand, the result of the risk matrix displayed as a medium level, indicating that although the probability of an accident is low, the resulting severity is at disaster level. As a result, this study provides process safety engineers with a reliable frame of reference for assessing the potential dangers in the PVA latex manufacturing process. 相似文献
82.
浅析江苏油田井下作业清洁生产工艺技术 总被引:1,自引:0,他引:1
以江苏油田井下作业清洁生产工艺为例,分析了井下作业施工造成对环境污染的因素,介绍了江苏油田在井下作业前期、中期、后期清洁生产的措施及其相关配套新工艺、新技术的应用和取得的效果。 相似文献
83.
84.
Tao Zhang Yaqun He Fangfang Wang Linhan Ge Xiangnan Zhu Hong Li 《Waste management (New York, N.Y.)》2014,34(6):1051-1058
Mineral processing operation is a critical step in any recycling process to realize liberation, separation and concentration of the target parts. Developing effective recycling methods to recover all the valuable parts from spent lithium-ion batteries is in great necessity. The aim of this study is to carefully undertake chemical and process mineralogical characterizations of spent lithium-ion batteries by coupling several analytical techniques to provide basic information for the researches on effective mechanical crushing and separation methods in recycling process. The results show that the grade of Co, Cu and Al is fairly high in spent lithium ion batteries and up to 17.62 wt.%, 7.17 wt.% and 21.60 wt.%. Spent lithium-ion batteries have good selective crushing property, the crushed products could be divided into three parts, they are Al-enriched fraction (+2 mm), Cu and Al-enriched fraction (?2 + 0.25 mm) and Co and graphite-enriched fraction (?0.25 mm). The mineral phase and chemical state analysis reveal the electrode materials recovered from ?0.25 mm size fraction keep the original crystal forms and chemical states in lithium-ion batteries, but the surface of the powders has been coated by a certain kind of hydrocarbon. Based on these results a flowsheet to recycle spent LiBs is proposed. 相似文献
85.
Toxic loads and explosion overpressure loads pose grave threats to the offshore oil and gas industry. Many safety measures are adopted to prevent and mitigate the adverse impacts caused by toxic loads and explosion overpressure loads. As a general safety barrier, the process protection system has been widely used but rarely evaluated. In order to assess the barrier ability, the mitigation performance of the process protection system is concerned in this study. Firstly, several chain accidents of H2S-containing natural gas leakage and explosion are simulated by varying the response time of the process protection system with CFD code FLACS. Qualitative assessment is conducted based on the variation of the dangerous load profiles. Furthermore, the quantitative assessment of the mitigation performance is accomplished by considering its ability in reducing the probability of fatality. Emergency evacuation and no emergency evacuation are considered respectively in the quantitative assessment. The results prove that the process protection system takes effect on mitigating the toxic impact and explosion overpressure impact. The results also demonstrate that although the emergency evacuation may result in a severer explosion load to the operator, the process protection system can mitigate the adverse impacts regardless of whether the emergency evacuation is conducted or not. 相似文献
86.
为检验臭氧预氧化在北方地区的效果,结合东北地区某微污染水源做出了分析和探索,发现臭氧氧化对净水处理效果良好。并全面阐述了微污染水源采用臭氧预氧化技术后带来的效果,可用于脱色除臭、控制氯化消毒副产物、去除藻类和藻毒素、助凝和助滤、初步去除或转化污染物,为相关的工程设计奠定了基础。 相似文献
87.
在国家公园体制改革背景下,“建立以国家公园为主体的自然保护地体系”对我国自然保护地优化整合提出了系列要求。福建省正在进行自然保护地优化整合,泰宁县是全省自然保护地交叉重叠最复杂的区域之一。以泰宁县为例,基于实地调研和专家意见,构建了三个优化整合的情景规划方案:(1)维持现状,不整合;(2)以泰宁国家地质公园为主体的整合;(3)以泰宁国家公园为主体的整合。基于对方案的成本效益比较,结果显示:方案3的存在和使用价值最高,成本持中;方案1的价值保护持中,成本最低;方案2价值最低,成本最高。研究为福建省县市尺度开展自然保护地优化整合提供思路和技术支持,亦为国内外自然保护地的边界优化提供参考。 相似文献
88.
Though dynamic operation of chemical processes has been extensively explored theoretically in contexts such as economic model predictive control or even considering the potential for cyberattacks on control systems creating non-standard operating policies, important practical questions remain regarding dynamic operation. In this work, we look at two of these with particular relevance to process safety: (1) evaluating dynamic operating policies with respect to process equipment fidelity and (2) evaluating procedures for determining the parameters of an advanced control law that can promote both dynamic operation as well as safety if appropriately designed. Regarding the first topic, we utilize computational fluid dynamics and finite element analysis simulations to analyze how cyberattacks on control systems could impact a metric for stress in equipment (maximum Von Mises stress) over time. Subsequently, we develop reduced-order models showing how both a process variable and maximum Von Mises stress vary over time in response to temperature variations at the boundary of the equipment, to use in evaluating how advanced control frameworks might impact and consider the stress. We close by investigating options for obtaining parameters of an economic model predictive control design that would need to meet a variety of theoretical requirements for safety guarantees to hold. This provides insights on practical safety aspects of control theory, and also indicates relationships between control and design from a safety perspective that highlight further relationships between design and control under dynamic operation to deepen perspectives from the computational fluid dynamics and finite element analysis discussions. 相似文献
89.
90.
刘扬 《石油化工环境保护》2002,25(2):14-16
金陵石化炼油厂第二污水处理场改造工程中对原有处理设施进行了工艺调整和优化,采用了均质,二级好氧生物处理及后浮选工艺,工程运行结果表明所采用的技术、设备是合理有效的。 相似文献