宝鸡市街道尘埃磁学特征空间分布及环境意义

对宝鸡市街道尘埃样品进行详细系统环境磁学实验分析并结合扫描电子显微镜研究表明,宝鸡市街道尘埃中磁性矿物含量高,主要的磁性矿物为多畴和假单畴的低矫顽力亚铁磁性矿物,同时含有少量的赤铁矿等高矫顽力的硬磁性矿物.污染来源主要以工业和交通等人为污染为主.街道尘埃的磁学特征表现出一定的空间变化规律揭示出污染的空间分布,划分为6个主要区域:A(创新路到高新八路区域)和B(东风路和马营路区域),磁性物质含量整体很高,揭示污染相对较重,污染源主要为"工业+交通";C区(火炬路到医康区域)磁性物质含量相对较高,是中度污染的区域,污染源主要为"交通";D(经二路与人民路区域)、E(清姜路和姜谭路西部区域)和F(陈仓区虢镇),磁性物质含量相对较低,揭示轻度污染,污染源主要为"交通".     

Minimum ignition energy of mixtures of combustible dusts

Most industrial powder processes handle mixtures of various flammable powders. Consequently, hazard evaluation leads to a reduction of the disaster damage that arises from dust explosions. Determining the minimum ignition energy (MIE) of flammable mixtures is critical for identifying possibility of accidental hazard in industry. The aim of this work is to measure the critical ignition energy of different kinds of pure dusts with various particle sizes as well as mixtures thereof.The results show that even the addition of a modest amount of a highly flammable powder to a less combustible powder has a significant impact on the MIE. The MIE varies considerably when the fraction of the highly flammable powder exceeds 20%. For dust mixtures consisting of combustible dusts, the relationship between the ignition energy of the mixture and the minimum ignition energy of the components follows the so-called harmonic model based upon the volume fraction of the pure dusts in the mixture. This correlation provides results which show satisfactory agreement with the experimental values.     

Risk quantification framework of hydride-based hydrogen storage systems for light-duty vehicles

This study aims to develop a quantitative risk assessment (QRA) framework for on-board hydrogen storage systems in light-duty fuel cell vehicles, with focus on hazards from potential vehicular collision affecting hydride-based hydrogen storage vessels. Sodium aluminum hydride (NaAlH₄) has been selected as a representative reversible hydride for hydrogen storage. Functionality of QRA framework is demonstrated by presenting a case study of a postulated vehicle collision (VC) involving the onboard hydrogen storage system. An event tree (ET) model is developed for VC as the accident initiating event. For illustrative purposes, a detailed FT model is developed for hydride dust cloud explosion as part of the accident progress. Phenomenologically-driven ET branch probabilities are estimated based on an experimental program performed for this purpose. Safety-critical basic events (BE) in the FT model are determined using conventional risk importance measures. The Latin Hypercube sampling (LHS) technique has been employed to propagate the aleatory (i.e., stochastic) and epistemic (i.e., phenomenological) uncertainties associated with the probabilistic ET and FT models. Extrapolation of the proposed QRA framework and its core risk-informed insights to other candidate on-board reversible and off-board regenerable hydrogen storage systems could provide better understanding of risk consequences and mitigation options associated with employing this hydrogen-based technology in the transportation sector.     

Fire accident investigation of an explosion caused by static electricity in a propylene plant

This study investigated a 2010 fire and explosion that occurred at a polypropylene (PP) and copper-clad laminate high-tech plant in Taiwan. Liquid acetone leakage caused the fire and explosion. One person was killed and five were injured; property damage was estimated at US$20 million. In contrast to conventional plants, high-tech plants have sophisticated instrumentation, highly complex pipelines, and confined spaces. In addition, the floor area in a high-tech plant is large and frequently contains a channel through the ground floor to the second or third floor. This channel design enables the fire compartment to be destroyed. Therefore, the system cannot confine the fire to a specific area, thus hindering fire-relief operations. In this study, the original fire outbreak occurred in the PP processing area on the ground floor. The acetone storage tank was located on the third floor. The investigation conducted at the fire site of the situations of the burning (bursting) loss determined that the acetone liquid leaked and dripped from floor cracks and tunnel oven to the PP processing area. Because the PP manufacturing process rapidly generates static electricity, the flammable liquids made contact with the source of ignition, which caused the explosion and fire. Various procedures, such as those involving the operating environment of production, packaging, and processing in a high-tech plant, are likely to produce static electricity in a workplace. Improved electrostatic management can prevent the loss of property and lives, liquid acetone leakage, and loss of equipment caused by static electricity fire.     

金华市街道灰尘磁化率时空变化研究

对不同时空条件下的金华市二环以内的街道灰尘样品的磁化率进行了研究.结果表明,金华市街道灰尘磁化率均值349.67×10-8 m3/kg,冬、春、夏各个季节的平均值:322.55×10-8 m3/kg、358.16×10-8 m3/kg和368.31×10-8 m3/kg,指示了其均具有磁性增强效应,且其值相近;春、夏两个季节街道灰尘磁化率的高值区分布结构相似,模型参数分析表明,区域因素为影响其值的主因;街道灰尘磁化率高值区与城区工业区大体吻合分布,工业区是主要的区域因素。     

Heterogeneous uptake of nitrogen dioxide on Chinese mineral dust

Mineral dust is one of the major aerosols in the atmosphere. To assess its impact on trace atmospheric gases, in this work we present a laboratory study of the effect of temperature on the heterogeneous reaction of NO₂ on the surface of ambient Chinese dust over the temperature range from 258 to 313 K. The results suggest that nitrogen dioxide could mainly be adsorbed on these types of Chinese mineral dust reversibly with little temperature dependence. Similar to a previous study on NO₂ uptake on mineral aerosols, the uptake coefficients are mainly on the order of 10^− 6 for the Chinese dust, when BET areas are taken into account. HONO was observed as a product, and its formation and decomposition on Chinese mineral dust during the uptake processes were also studied. The complete dataset from this study was compiled with previous literature determinations. Atmospheric implications of the heterogeneous reaction between NO₂ and mineral dust are also discussed, in an effort to understand this important heterogeneous process.     

Acid-catalyzed heterogeneous reaction of 3-methyl-2-buten-1-ol with hydrogen peroxide

Acid-catalyzed heterogeneous oxidation with hydrogen peroxide(H2O2) has been suggested to be a potential pathway for secondary organic aerosol(SOA) formation from isoprene and its oxidation products. However, knowledge of the chemical mechanism and kinetics for this process is still incomplete. 3-Methyl-2-buten-1-ol(MBO321), an aliphatic alcohol structurally similar to isoprene, is emitted by pine forests and widely used in the manufacturing industries. Herein the uptake of MBO321 into H2SO4–H2O2mixed solution was investigated using a flow-tube reactor coupled to a mass spectrometer. The reactive uptake coefficients(γ) were acquired for the first time and were found to increase rapidly with increasing acid concentration. Corresponding aqueous-phase reactions were performed to further study the mechanism of this acid-catalyzed reaction. MBO321 could convert to 2-methyl-3-buten-2-ol(MBO232) and yield isoprene in acidic media. Organic hydroperoxides(ROOHs) were found to be generated through the acid-catalyzed route,which could undergo a rearrangement reaction and result in the formation of acetone and acetaldehyde. Organosulfates, which have been proposed to be SOA tracer compounds in the atmosphere, were also produced during the oxidation process. These results suggest that the heterogeneous acid-catalyzed reaction of MBO321 with H2O2 may contribute to SOA mass under certain atmospheric conditions.     

工业烟尘废气中PM2.5的除尘技术概述

本文通过对不同的常规除尘设备的工作原理以及除尘性能进行研究,重点分析了电袋式混合除尘器、静电旋风式混合除尘器以及湿式电除尘器三种混合除尘器的技术特点,指出混合除尘器和凝并器能有效提高除尘器去除PM2.5的效率,对工业发展和保护大气环境具有重要意义.     

苯储罐区火灾爆炸风险分析及对策措施

针对苯储罐区所处的区域位置及火灾爆炸危险性,运用道化学火灾、爆炸危险指数法对苯储罐区的火灾、爆炸风险进行分析评价,得出其安全措施补偿前后的火灾、爆炸指数,确定危险等级,并提出了预防火灾爆炸事故的对策措施。     

环氧氯丙烷工艺中分离罐气相出口的燃爆危险性分析

环氧氯丙烷生产工艺中双氧水分解产生的氧气与含氯丙烯、环氧氯丙烷、甲醇的可燃气体混合存在燃爆危险,为预防燃爆发生,利用5L爆炸极限测试仪测定分离罐气相出口可燃气在不同氧气浓度条件下的爆炸极限,并以此绘制爆炸极限三元图,得到不同工况条件下"可燃气-氧气-氮气"混合体系的燃爆区域。结果表明:随着氧气浓度的升高,可燃气爆炸上限明显提高,但爆炸下限变化不明显;随温度上升,气相出口组分发生变化,LOC值逐渐降低;正常冷却条件下极限氧含量为12%,冷却效果差时为10%,冷却失效时为9.3%;设置氧浓度报警时参考最小LOC值,留出裕度空间,控制体系氧含量小于5%有助于预防燃爆发生。