发酵生物制氢反应器的产氢菌生物强化作用研究

将发酵产氢菌Ethanoligenens sp. B49投加到连续流搅拌槽式反应器（CSTR）的活性污泥中,以糖蜜废水为底物,进行强化活性污泥产氢效能的研究.对生物强化前和生物强化后反应系统的产氢能力、发酵产物组成和pH值进行了对比分析.结果表明,在COD容积负荷为12 kg/(m³·d)条件下,投加产氢菌可显著提高反应系统的产氢能力并改善发酵产物组成.反应系统的比产氢速率从强化前的3.6 mmol/(kg·d)提高到强化后的5.7 mmol/(kg·d),是生物强化前的1.5倍.生物强化前,反应系统液相发酵产物乙醇、乙酸和丙酸的平均浓度分别为6.8、 5.3和4.8　mmol/L,生物强化后乙醇、乙酸和丙酸的平均浓度分别为10.5、 7.5和1.7 mmol/L,其中乙醇型发酵目的产物乙醇和乙酸在总发酵产物中的比例从生物强化前的72.0%提高为强化后的86.8%.生物强化作用使出水pH值从4.5～4.7下降为4.3.产氢菌的生物强化作用有助于反应器在低负荷运行期迅速形成产氢能力较高的乙醇型发酵.     

兰州市CMAQ近地面臭氧模拟结果的订正方法——基于机器学习方法

为能更加准确地模拟出兰州市近地面臭氧浓度,在CMAQ(社区多尺度空气质量建模系统)的基础上,利用机器学习方法中的XGBoost(极限梯度提升)模型及LSTM(长短期记忆)神经网络模型建立近地面臭氧模拟结果的订正模型,并以两种方法为基础,利用误差变权倒数组合方法构建LSTM-XGBoost组合模型,以期进一步提高订正效果.本文选取兰州市4个国控站点(兰炼宾馆,铁路设计院,榆中校区,生物制品所)2019年7、8月环境空气质量监测数据及兰州市气象站同期气象数据,对CMAQ模拟的同时段兰州市近地面臭氧浓度进行订正.结果表明,CMAQ能够模拟出兰州市近地面臭氧浓度的空间及时间分布特征,但整体上对浓度有所低估.利用上述方法构建的订正模型中,LSTM-XGBoost组合模型的订正效果最好,臭氧相关性由CMAQ模拟的0.61～0.76提升至0.89～0.95,臭氧8h平均相关性由0.65～0.79提升至0.81～0.88,臭氧RMSE由44.83～70.17μg/m³提升至15.21～26.53μg/m³,臭氧8h平均RMSE由40.07～67.57μg/m...     

近30年来鄱阳湖环湖区土地利用与景观格局变化研究

以1988—2018年7期Landsat遥感卫星影像为数据源,采用土地利用转移矩阵、景观格局指数等方法探究了鄱阳湖环湖区近30年来土地利用与景观格局变化特征.结果表明：(1)近30年来鄱阳湖环湖区建设用地和林地面积显著增加,耕地、草地、水域和未利用地面积减少.(2)建设用地的转入类型以耕地为主,30年间共侵占耕地面积1243.66 km²,占建设用地面积增加量的71.19%.林地的转入类型主要为耕地和草地,其中,耕地转入占比56.95%.耕地的转出类型以建设用地、草地和林地为主,且1999年以后随着城镇化的发展耕地主要转向建设用地.(3)近30年来鄱阳湖环湖区景观总体破碎程度逐渐增大,景观斑块个数共增加63492个,增幅为11.68%.景观连通性降低,各类型土地呈均衡化趋势分布,景观异质性增加.研究结果可为推动鄱阳湖环湖区土地资源保护、生态环境保护和经济协同发展提供参考依据.     

New parameterization scheme for effective indices for emissions from road transport

The local to regional processes of chemical transformations, washout and dry deposition cannot be directly resolved in global scale models, they rather need to be parameterized. A suitable way to account for the non-linearity, e.g., in chemical transformation processes, is the use of effective emission indices (EEIs). EEI translate the actual (small scale) emissions into input for global scale models, partially accounting for unresolved processes occurring shortly after the release of the emissions.The emissions from the road traffic have some specifics, because of which the concept of deriving EEI from the interaction of an instantaneous plume with the ambient air is perhaps not so convenient. A new parameterization scheme for the EEI from the road transport is suggested in the present paper, based on few simplifying assumptions and introducing the adjoin equations approach, which makes it possible to achieve unified, not depending on the specific emission pattern, procedure for calculating the EEI from road traffic.     

The role of the Alliance of Small Island States (AOSIS) in the negotiation of the United Nations Framework Convention on Climate Change (UNFCCC)

The United Nations Framework Convention on Climate Change (UNFCCC), which was signed by some 153 countries at the Earth Summit in Rio de Janeiro, Brazil in 1992, represented a singular triumph for the geographically dispersed group of island states and low-lying coastal developing countries, located in the Pacific, Atlantic and Indian Oceans, as well as in the Caribbean, South China and Mediterranean Seas, and known as the Alliance of Small Island States (AOSIS). This article focuses on the goals of AOSIS during the negotiations leading up to the adoption of the UNFCCC. For the first time in the history of the United Nations, a group of small states, hitherto relegated to the sidelines, was able to develop a specific negotiating agenda addressing areas which are of overriding concern to them and succeeded in having those concerns incorporated in a legally binding Convention of historic importance. As this article reveals, AOSIS set itself 12 negotiating goals during the negotiating rounds leading up to the UNFCCC, and 10 of these 12 goals were realized. Nevertheless, AOSIS, whose member states are most vulnerable to the possible adverse effects of climate change, was particularly concerned about those provisions of the UNFCCC that were either watered-down significantly, made largely meaningless or excluded altogether. These include: the absence of definite targets or specific timetables for the significant reduction of carbon dioxide by the industrialized countries of the North; the lack of permanent and clear financing arrangements in particular the lack of definitive financial provisions for adaptive response measures to the adverse impacts of climate change such as sea-level rise; and the absence of a specific provision for the implementation of coastal zone management schemes for those countries most vulnerable to sea-level rise. As the UNFCCC moves into the implementation phase, AOSIS should and must build on its past success. To do so, it will need to develop clearly defined initiatives aimed at strengthening the commitments for financing and insurance, and to seek inclusion of a provision to develop and finance coastal zone management schemes for the most vulnerable small states. While the article covers the AOSIS negotiating period up to and including the Earth Summit in June 1992, we nevertheless postulate some possible objectives which the AOSIS group might wish to consider in what is sure to be an intensive post-Earth Summit phase of the UNFCCC, leading up to the first Conference of the Parties of that Convention.     

爆炸性环境用防爆对旋轴流式通风机的研制及应用

论述了新研制的KDZ型防爆对旋压抽式轴流通风机的工作原理、结构特点、主要技术指标及应用效果。     

攀钢烧结机头烟气脱硫技术方案的建议

主要介绍了攀钢烧结机头烟气现状 ,并分析了该烟气中硫元素的主要来源 ;目前国内部分已运用于生产和正处于研究、开发阶段的大烟气量低浓度 SO2 脱硫技术 ;日本新日铁株式会社已运用于生产的利用活性炭吸附的烧结烟气脱硫、脱硝技术。并对攀钢进行烧结烟气脱硫提出了一些建议。     

In silico prediction of Tetrahymena pyriformis toxicity for diverse industrial chemicals with substructure pattern recognition and machine learning methods

There is an increasing need for the rapid safety assessment of chemicals by both industries and regulatory agencies throughout the world. In silico techniques are practical alternatives in the environmental hazard assessment. It is especially true to address the persistence, bioaccumulative and toxicity potentials of organic chemicals. Tetrahymena pyriformis toxicity is often used as a toxic endpoint. In this study, 1571 diverse unique chemicals were collected from the literature and composed of the largest diverse data set for T. pyriformis toxicity. Classification predictive models of T. pyriformis toxicity were developed by substructure pattern recognition and different machine learning methods, including support vector machine (SVM), C4.5 decision tree, k-nearest neighbors and random forest. The results of a 5-fold cross-validation showed that the SVM method performed better than other algorithms. The overall predictive accuracies of the SVM classification model with radial basis functions kernel was 92.2% for the 5-fold cross-validation and 92.6% for the external validation set, respectively. Furthermore, several representative substructure patterns for characterizing T. pyriformis toxicity were also identified via the information gain analysis methods.     

卷式超滤膜在蓝藻收集中的应用

利用微孔滤布-卷式超滤膜组合工艺,构建蓝藻收集中试系统,用于处理高藻期富营养化水体。考察了高藻期该工艺的蓝藻收集效率、膜通量变化及膜污染状况。结果表明,该组合工艺在进水泵频率40 Hz,进水压力0.2 MPa的条件下,定期排蓝藻浓缩液实验和蓝藻连续浓缩实验的蓝藻截留率均能达到95%以上;6 d后定期排蓝藻浓缩液实验最低...     

Relationship of surface changes to metal leaching from tungsten composite shot exposed to three different soil types

Physical changes that occur on the surface of fired shots due to firing and impact with soil may increase the dissolution of muniton metals. Increased metal dissolution could potentially increase metal transport and leaching, affecting metal concentrations in surface and groundwater. This research describes the relationship between the surface changes on fired tungsten-nickel-iron (94% W:2% Ni:4% Fe) composite shots and metals leaching from those shots. Tungsten composite shot was fired into, and aged in, three soil types (Silty Sand, Sandy Clay, and Silt) in mesoscale rainfall lysimeters to simulate live-fire conditions and subsequent interactions between the metals of the composite and soil. Leachate, runoff, and soil samples were collected from the lysimeters and analyzed for metal content. The shots were analyzed using scanning electron microscopy (SEM) to evaluate surface changes. SEM results indicated that a soil’s particle size distribution initially affected the amount of metal that was sheared from the surface of the fired W-composite shots. Shearing was greatest in soils with larger soil particles (sand and gravel); shearing was least in soils composed of small soil particles (fines). Increased metallic shearing from the shot’s surface was associated with increased W dissolution, compared to controls, following a simulated 1 year soil aging.